Journal of Korea Technical Association of The Pulp and Paper Industry (펄프종이기술)

Korea Technical Association of the Pulp and Paper Industry (한국펄프종이공학회)
권호 표지
DOI QR코드

DOI QR Code

Effect on Bleaching Efficiency by Chelating Treatment in Sugarcane Bagasse DEDP Bleaching Process

사탕수수 부산물 펄프의 DEDP 표백 시 킬레이트 전처리가 표백 효율에 미치는 영향

  • Lee, Jai-Sung (Department of Wood and Paper Science, Chungbuk National University) ;
  • Song, Woo-Yong (Department of Wood and Paper Science, Chungbuk National University) ;
  • Park, Jong-Moon (Department of Wood and Paper Science, Chungbuk National University) ;
  • Shin, Soo-Jeong (Department of Wood and Paper Science, Chungbuk National University)
  • 이재성 (충북대학교 목재종이과학과) ;
  • 송우용 (충북대학교 목재종이과학과) ;
  • 박종문 (충북대학교 목재종이과학과) ;
  • 신수정 (충북대학교 목재종이과학과)
  • Received : 2015.08.04
  • Accepted : 2015.08.19
  • Published : 2015.08.30
Download PDF
⟨ Previous Next ⟩

Abstract

Soda-AQ pulp made from sugarcane bagasse (SCB) were bleached in element chlorine free (ECF) sequence. To reduce chlorine dioxide use, final peroxide bleaching was introduced. Prior to peroxide bleaching, different chelating chemicals were applied for comparative analysis in ISO brightness and viscosity. When using equal total chlorine dioxide usage (4.5%), bleached SCB pulp using chelate and hydrogen peroxide (DEDQP) was reached 86.8% (DTPA), 86.4% (EDTA) ISO brightness, whereas bleached pulp using only hydrogen peroxide (DEDP) reached at 81.2% ISO brightness. Viscosity of DEDQP bleached pulp was 25.6 cPs (DTPA), 25.2 cPs (EDTA), And DEDP bleached pulp was shown 18.0 cPs viscosity. Decreasing of transition metal by chelate process led to improvements in final brightness along with higher viscosity. Due to EDTA is 5-7 times cheaper than DTPA, EDTA is recommended as chelating chemical prior to peroxide bleaching.

Keywords

References

  1. Abrantes, S., Amaral, E., Costa, P., Shatalov, A., and Duarte, P., Hydrogen peroxide bleaching of Arundo donax L. kraft-anthraquinone pulp - Effect of a chelating stage, Ind. Crops Prod. 25:288-293 (2007). https://doi.org/10.1016/j.indcrop.2006.12.006
  2. Seco, C. L., Neto, P., and Silvestre, D., Strategies to reduce the brightness reversion of industrial ECF bleached Eucalyptus globulus kraft pulp, J. Chem. Technol. Biotechnol. 83:218-226 (2008). https://doi.org/10.1002/jctb.1791
  3. Gustavson, C., Sjostrom, K., and Wafa Al-Dajani, W., The influence of cooking conditions on the bleachability and chemical structures of kraft pulps, Nord. Pulp. Pap. Res. 14:7 (1999).
  4. Liss-Albin, C. I., Oskar, D. S., and Erik, N. S., Bleaching and delignification of partially delignified pulp with a mixture of chlorine and chlorine dioxide, US patent, US3652388 A (1972).
  5. Axegard, P. and Renberg, L., The influence of bleaching chemicals and lignin content on the formation of polychlorinated dioxins and dibenzofurans, Chemosphere 19:661-668 (1989). https://doi.org/10.1016/0045-6535(89)90387-1
  6. Savant, D. V., Abdul-Rahman, R., and Ranade, D. R., Anaerobic degradation of adsorbable organic halides (AOX) from pulp and paper industry wastewater, Bioresour. Technol. 97(9):1092-1104 (2006). https://doi.org/10.1016/j.biortech.2004.12.013
  7. Basta, J., Holtinger, L., and Hook, J., Controlling the profile of metals in the pulp before hydrogen peroxide treatment, 6th International Symposium on Wood and Pulping Chemistry Proceedings, Melbourne, Vol. 1, pp. 237-244 (1991).
  8. Jones, P. W. and Williams, D. R., Chemical speciation simulation used to assess the efficiency of environmnet-friendly EDTA alternatives for use in the pulp and paper industry, Inorg. Chim. Acta 339:41-50 (2002). https://doi.org/10.1016/S0020-1693(02)00924-6
  9. Rreire, C. S. R., Silvestre, A. J. D., Neto, C. P., and Evtuguin, D. V., Effect of oxygen, ozone and hydrogen peroxdie bleaching stages on the contents and composition of extractives of Eucalyptus globulus kraft pulps, Bioresour. Technol. 97:420-428 (2006). https://doi.org/10.1016/j.biortech.2005.03.006
  10. Zhang, X. Z., Francis, R. C., Dutton, D. B., and Hill, R. T., The role of transition metal species in delignification with distilled peracetic acid, J. Wood Chem. Technol. 18(3):253-266 (2008). https://doi.org/10.1080/02773819809349580
  11. Granholm, K., Harju,. L., and Ivaska, A., Desorption of metal ions from kraft pulps. part 1. Chelation of hardwood and softwood kraft pulp with EDTA, BioResoures 5(1):206-226 (2010).
  12. Carvalho, M. G. V. S., Carvalho, N. M. V., and Loureiro, P. E. G., Performance of a final hydrogen peroxide stage in the ECF bleaching of Eucalyptus $D_0E_{0P}D_1$ kraft pulps, Tappi J. 7:8-13 (2008).
  13. Araujo, F. V. F. and Yokoyama, L. Heterogeneous fenton process using the mineral hematite for the discolouration of a reactive dye solution, Braz. J. Chem. Eng. 28(4):605-616 (2011). https://doi.org/10.1590/S0104-66322011000400006