Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
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A Simple Analysis Method to Predict the Large Amplitude Oscillatory Shear (LAOS) Flow Behavior of Viscoelastic Polymer Liquids

점탄성 고분자 액체의 대진폭 전단유동거동 예측을 위한 간단한 해석방법

  • Chang, Gap-Shik (Reliability Assessment Team, FITI Testing & Research Institute) ;
  • Ahn, Hye-Jin (Department of Organic Material Science and Engineering, Pusan National University) ;
  • Song, Ki-Won (Department of Organic Material Science and Engineering, Pusan National University)
  • 장갑식 (FITI시험연구원 신뢰성평가팀) ;
  • 안혜진 (부산대학교 공과대학 유기소재시스템공학과) ;
  • 송기원 (부산대학교 공과대학 유기소재시스템공학과)
  • Received : 2015.04.21
  • Accepted : 2015.05.28
  • Published : 2015.06.30
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Abstract

Using an Advanced Rheometric Expansion System (ARES), the dynamic viscoelastic behavior of aqueous poly(ethylene oxide) (PEO) solutions with various molecular weights and different concentrations has been investigated in large amplitude oscillatory shear (LAOS) flow fields over a wide range of strain amplitudes. In order to predict the nonlinear viscoelastic behavior of polymer liquids in strain-sweep experiments, a new analysis method including a simple empirical model was proposed and then its validity was thoroughly evaluated in this study. The results have shown that the suggested model is significant in 95% confidence level and predicts exactly the nonlinear viscoelastic behavior of polymer liquids over a whole range of strain amplitudes tested. The strain limits of linear viscoelastic response and nonlinear behavior indices were determined using this model to estimate the LAOS flow behavior in strain-sweep experiments. The master curves of strain limits and nonlinear behavior indices can be obtained by representing these data against the product of angular frequency by characteristic time. The LAOS flow behavior of polymer systems with various molecular weights and different concentrations can well be predicted from these master curves.

Keywords

References

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