Rapid Communication in Photoscience

  • 제4권1호
  • /
  • Pages.19-21
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  • 2015
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  • 2234-8182(pISSN)
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  • 2288-4564(eISSN)
한국광과학회 (Korean Society of Photoscience)
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Photocatalytic Epoxidation of Olefins Using Molecular O2 by TiO2 Incorporated in Hydrophobic Y Zeolite

  • Kuwahara, Yasutaka (Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University) ;
  • Magatani, Yasuhiro (Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University) ;
  • Yamashita, Hiromi (Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University)
  • 투고 : 2015.03.10
  • 심사 : 2015.03.19
  • 발행 : 2015.03.01
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초록

Zeolite is an ideal host material for encapsulating nano-size metal catalyst species because of its defined microporous structure, prominent adsorption/condensation properties, high surface area, chemical/thermal stability, and transparency to light. In this study, $TiO_2$ photocatalyst was incorporated in highly hydrophobic Y zeolite and its photocatalytic activity was examined in the photocatalytic oxidation of olefins under UV-light irradiation using molecular oxygen as an oxygen source. $TiO_2$ nanoparticles incorporated in hydrophobic Y zeolite exhibited a markedly enhanced photocatalytic activity compared with bare $TiO_2$ owing to its excellent affinity toward organic moieties, which facilitates the mass transfer of organic substrates and allows them to efficiently access to the neighboring active $TiO_2$ surface.

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피인용 문헌

  1. Single-site and nano-confined photocatalysts designed in porous materials for environmental uses and solar fuels pp.1460-4744, 2018, https://doi.org/10.1039/C8CS00341F