Journal of the Korea Institute of Military Science and Technology (한국군사과학기술학회지)

The Korea Institute of Military Science and Technology (한국군사과학기술학회)
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High Pressure Effects on 1,3-Dipolar Cycloaddition of Azides with Alkynes

아자이드와 알킨의 1,3-쌍극자 고리첨가반응에서 고압이 반응속도에 미치는 영향에 대한 연구

  • Kwon, Jinju (The 4th Research and Development Institute, Agency for Defense Development)
  • 권진주 (국방과학연구소 제4기술연구본부)
  • Received : 2015.06.16
  • Accepted : 2015.10.16
  • Published : 2015.12.05
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Abstract

The effect of pressure on 1,3-dipolar cycloaddtion has been studied by means of FT-IR and NMR spectroscopy. Pressure accelerates 1,3-dipolar cycloaddition without solvent or catalyst. This simple and inexpensive method eliminates the need for work-up or purification. The method is expected to be applied to the synthesis of binders for solid rocket propellants.

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References

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