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An Experimental Study on Conversion of Reducing Agent from Aqueous Urea Solutions under Low Reaction Temperature

저온 반응장에서 요소 수용액의 환원제 전환에 관한 실험적 연구

  • 구건우 (경북대학교 기계공학과) ;
  • 홍정구 (경북대학교 기계공학과)
  • Received : 2015.02.17
  • Accepted : 2015.03.20
  • Published : 2015.03.31

Abstract

Urea-SCR which is one of the aftertreatment technologies for reducing the NOx emission is widely used. An experimental study was performed to investigate urea decomposition under various thermo-fluid conditions, with different temperatures and velocities of inflow gas, and urea solution quantities. 40 wt. % aqueous urea solutions were used in this study. The inflow gas conditions were similar to the exhaust conditions of a large marine engine. The spray performance of urea solution injector was identical under all experimental conditions. The conversion efficiency of $NH_3$ was larger than that of HNCO under all experimental conditions, unlike for the theoretical thermolysis reaction.

Keywords

References

  1. C. Ciardelli, I. Nova, E. Tronconi, D. Chatterjee, B. Bandl-Konrad, M. Weibel and B. Krutzsch, "Reactivity of $NO/NO_2-NH_3$ SCR System for Diesel Exhaust Aftertreatment: Identification of the Reaction Network as a Function of Temperature and $NO_2$ Feed Content", Applied Catalysis B, Vol. 70, 2007, pp. 80-90. https://doi.org/10.1016/j.apcatb.2005.10.041
  2. F. Nakajima and I. Hamada, "The State of the Art Technology of NOx Control", Catalysis today, Vol. 29, 1996, pp. 109-115. https://doi.org/10.1016/0920-5861(95)00288-X
  3. A. Bernhard, "Catalytic urea decomposition, side-reactions and urea evaporation in the selective catalytic reduction of $NO_x$", Ph.D. thesis No. 20813, ETH Zurich, Switzerland, 2006.
  4. S. D. Yim, S. J. Kim, J. H. Baik, I. S. Nam, Y. S. Mok, J. H. Lee, B. K. Cho and S. H. Oh, "Decomposition of Urea into NH3 for the SCR Process", Ind. Eng. Chem. Res., Vol. 43(16), 2004, pp. 4856-4863. https://doi.org/10.1021/ie034052j
  5. M. Koebel, M. Elsener and M. Kleemann, "Urea-SCR: a promising technique to reduce NOx emissions from automotive diesel engines", Catalysis Today Vol. 59, 2000, pp. 335-345. https://doi.org/10.1016/S0920-5861(00)00299-6
  6. A. Lundstrom, T. Snelling, P. Morsing, P. Gabrielsson, E. Senar and L. Olsson, "Urea Decomposition and HNCO Hydrolysis Studied over Titanium Dioxide, Fe-Beta and ${\gamma}$-Alumina", Applied Catalysis B, Vol. 106, 2011, pp. 273-279. https://doi.org/10.1016/j.apcatb.2011.05.010
  7. D. Peitz, A. Bernhard, M. Elsener, O. Krocher, "Laboratory test reactor for the investigation of liquid reducing agents in the selective catalytic reduction of NOx", Rev. Sci. Instrum., 82, 084101, 2011. https://doi.org/10.1063/1.3617463
  8. H. L. Fang and H. F. M. DaCosta, "Urea thermolysis and NOx reduction with and without SCR catalysts", Appl. Catal., B 46, 17, 2003. https://doi.org/10.1016/S0926-3373(03)00177-2
  9. M. Eichelbaum, A. B. Siemer, R. J. Farrauto and M. J. Castaldi, "The impact of urea on the performance of metal-exchanged zeolites for the selective catalytic reduction of NOx--Part II. Catalytic, FTIR, and NMR studies", Appl. Catal., B 97, 98, 2010. https://doi.org/10.1016/j.apcatb.2010.03.028
  10. P. A. Schaber, J. Colson, S. Higgins, D. Thielen and B. Anspach, J. Brauer, "Thermal decomposition (pyrolysis) of urea in an open reaction vessel", Thermochim. Acta, 424, 131, 2004. https://doi.org/10.1016/j.tca.2004.05.018
  11. F. Birkhold, U. Meingast, P. Wassermann and O. Deutschmann, "Modeling and simulation of the injection of urea-water-solution for automotive SCR $DeNO_x$-systems", Applied Catalysis B, Vol. 70, 2007, pp. 119-127. https://doi.org/10.1016/j.apcatb.2005.12.035
  12. F. Birkhold, U. Meingast, P. Wassermann and O. Deutschmann, "Analysis of the Injection of Urea-Water-Solution for Automotive SCR DeNOx-Systems: Modeling of Two-Phase Flow and Spray/Wall-Interaction", SAE 2006-01-0643, 2006.
  13. E. Abu-Ramadan, K. Saha, X. Li, Modeling the depleting mechanism of urea-water-solution droplet for automotive selective catalytic reduction systems. AIChE J., 2011; DOI 10.1002/aic.12523.
  14. IMO Resolution MEPC. 176(58), Revised Marpol Annex VI.
  15. Y. Wakatsuki and K. Misawa, NOx Reduction Performances of Marine SCR System, Proc. ISME., 2011, 2011.
  16. N. Nakayama, H. Yamashita, K. Ueshima, Y. Arahori, Y. Okada and T. Tokuoka, On-board Tests using Selective Catalytic Reduction (SCR) Pilot Reactor, J. MESJ., Vol. 33, 1998, pp. 332-339 https://doi.org/10.5988/jime1966.33.332
  17. Y. Niki, K. Hirata, T. Kishi, T. Inaba, M. Takagi, T. Fukuda, T. Nagai and E. Muraoka, SCR System for NOx Reduction of Medium Speed Diesel Engine, CIMAC Congress 2010, 2010, pp. 228.
  18. H. Dong, S. Shuai and J. Wang, "Effect of Urea Thermal Decomposition on Diesel NOx-SCR Aftertreatment Systems", SAETechnical, 2008, Paper 2008-01-1544.
  19. H. Strom, A. Lundstrom and B. Andersson, Choice of urea-spray models in CFD simulations of urea-SCR systems, Chem. Eng. J., Vol. 150, 2009, pp. 69-82. https://doi.org/10.1016/j.cej.2008.12.003
  20. T. Suzuki, A. Saito, T. Fujimatsu and K. Hayashida, "Development of A Simple System of Dropsizing: Part 1: Development Story and Outline of The System [in Japanese]", Journal of the ILASS-Japan, Vol. 16, No. 54, 2007, pp. 34-46.
  21. T. Suzuki, A. Saito, T. Fujimatsu and K. Hayashida, "Development of A Simple System of Dropsizing: Part 2 : Some Examples of Measurements [in Japanese]", Journal of the ILASS-Japan, Vol. 17, No. 58, 2008, pp. 44-51.
  22. A. H. Lefebvre, "Atomization and Sprays", Hemisphere publishing corporation, 1989, pp. 136-140.
  23. F. P. Incropera, D. P. DeWitt, T. L. Bergman and A. S. Lavine, "Fundamentals of heat and mass transfer", John Wiley & Sons, 2005.