DOI QR코드

DOI QR Code

Detecting gold by voltammetric handhold systems

  • Kim, Nack-Joo (Dept. of Fine Chemistry, Seoul National Univ. of Science & Technology) ;
  • Choi, Dal-Woong (Department of Public Health Sciences, Graduate School, Korea University) ;
  • Yoo, Hai-Soo (Korea Institute Ocean Science Technology) ;
  • Lee, Kyung (Excavation Literature and Ancient Scripts Research Institute, Fudan University) ;
  • Lee, Chang-Hyun (Division of General Education, Pyeongtaek University) ;
  • Ly, Suw-Young (Biosensor Research Institute) ;
  • Kim, Tae-Yun (Biosensor Research Institute)
  • 투고 : 2014.08.22
  • 심사 : 2014.09.25
  • 발행 : 2014.09.30

초록

A voltammetric investigation of Au assay was conducted at a low cost, using Nafion and DNA immobilized on a graphite Pencil working electrode (NDP) with a black lead counter and reference. The following optimal parameters were found: 0.4 V amplitude, 500 Hz frequency, -0.7 V initial potential, and 0.015 V increment potential. These optimal conditions were also applied to sand obtained from the river site. The aforementioned technique is simpler and less costly compared to the common voltammetry and spectrophotometric methods.

키워드

참고문헌

  1. S. M. Rancic; S. D. N. Mandi;, L. M. Mandic; Kinetic spectrophotometric method for gold(III) determination, Analytica Chimica Acta 547. 144-149 (2005) https://doi.org/10.1016/j.aca.2004.11.078
  2. I.L. Garcia; N. Campillo; I.A. Jerez; M. H.Cordoba; Slurry sampling for the determination of silver and gold in soils and sediments using electrothermal atomic absorption spectrometry, Spectrochimica Acta Part B 58, 1715-721 (2003) https://doi.org/10.1016/S0584-8547(03)00135-6
  3. R. A. Merey; Z. Hariri; J. A Hilal; Selective separation of gold from iron ore samples using ion exchange resin, Microchemical Journal 75, 169-77 (2003) https://doi.org/10.1016/S0026-265X(03)00092-4
  4. M. Pumera; M. Aldavert; C. Mills; A. Merkoc; S. Alegret; Direct voltammetric determination of gold nanoparticles using graphite-epoxy composite electrode, Electrochimica Acta 50, 3702-3707 (2005) https://doi.org/10.1016/j.electacta.2005.01.035
  5. C. Wang; H. Zhang; Y. Sun; H.Li; Electrochemical behavior and determination of gold at chemically modified carbon paste electrode by theethylenediamine fixed humic acid preparation, Analytica Chimica Acta 361; 133-139 (1998) https://doi.org/10.1016/S0003-2670(97)00714-9
  6. A.M. Bond; P.J. Mahona; J. Schiewe; V.V. Beckettb; An inexpensive and renewable pencil electrode in field-based stripping voltammetry, Analytica Chimica Acta 345, 67-74 (1997) https://doi.org/10.1016/S0003-2670(97)00102-5
  7. D. Demetriades; A. Economou.; A. Voulgaropoulos; A study of pencil-lead bismuth-film electrodes for the determination of trace metals by anodic stripping voltammetry, Analytica Chimica Acta 519, 167-172 (2004) https://doi.org/10.1016/j.aca.2004.05.008
  8. W. Gao; J. Song; N. Wu; Voltammetric behavior and square-wave voltammetric determination of trepibutone at a pencil graphite electrode, Journal of Electroanalytical Chemistry 576, 1-7 (2005) https://doi.org/10.1016/j.jelechem.2004.09.026
  9. P. Masawat; S. Liawruangrath; Y. Vaneesorn; B. Liawruangrath; Design and fabrication of a low-cost flow-through cell for the determination of acetaminophen in pharmaceutical formulations by flow injection cyclic voltammetry, Talanta 58, 1221--1234 (2002) https://doi.org/10.1016/S0039-9140(02)00424-1
  10. H. Karadeniz; B. Gulmez; F. Sahinci; A. Erdem; G.I. Kaya; N. Unver; B. Kivcak; M. Ozsoz; Disposable electrochemical biosensor for the detection of the interaction between DNA and lycorine based on guanine and adenine signals, Journal of Pharmaceutical and Biomedical Analysis 33, 295-302 (2003) https://doi.org/10.1016/S0731-7085(03)00283-8
  11. M. Ozsoz; A. Erdem; P. Kara; K. Kerman; D. Ozkan; Electrochemical Biosensor for the Detection of Interaction Between Arsenic Trioxide and DNA Based on Guanine Signal, Electroanalysis, 15, 613-619 (2003) https://doi.org/10.1002/elan.200390077
  12. M. Fojta; L. Havran; S. Billova; P. Kostecka; M. Masarik; R. Kizek; Two-Surface Strategy in Electrochemical DNA Hybridization Assays: Detection of Osmium-Labeled Target DNA at Carbon Electrodes, Electroanalysis, 15, 431-440 (2003). https://doi.org/10.1002/elan.200390050