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Estimation of damage area on membrane surface by application of fluorescent particles as a surrogate

형광입자를 이용한 분리막 표면 검측과 손상 면적 추정 오차에 대한 연구

  • 최윤경 (세종대학교 환경에너지융합학과) ;
  • 김초아 (세종대학교 환경에너지융합학과) ;
  • 김희준 (지우이앤이주식회사) ;
  • 조진우 (세종대학교 환경에너지융합학과)
  • Received : 2014.02.11
  • Accepted : 2014.04.10
  • Published : 2014.04.15

Abstract

In this study, a novel method was proposed to test the integrity of water treatment system specifically equipped with membrane filtration process. We applied the silica particles coated with a fluorescent agent (rhodamine B isothiocyanate) as a surrogate to detect a membrane process integrity and evaluate the reliability of effluent quality in the system. Additionally, a series of experiments was conducted to evaluate the sensitivity of the method through the laboratory scale experiment. The laboratory scale experiments showed that the feasibility of application of proposed method to detect a breach or damaged part on the membrane surface. However, the sensitivity on predicting the area of a breach was significantly influenced by the testing conditions such as a concentration of surrogate, filtration flux, and detection time. The lowest error of predicting the area of breach was 3.5% at the testing condition of surrogate concentration of 80 mg/L injected with flux of $20L/m^2/hr$ for 10 minutes of detection time for the breach having the actual area of $7.069mm^2$. However, the error of estimation was increased at the small breach with area less than $0.785mm^2$. A future study will be conducted to estimate a damaged area with more accuracy and precision.

Keywords

References

  1. Adam, S., Gagliardo, P., Smith, D., Ross, D., Gramith, K., Trussell, R. (1998) Monitoring the integrity of reverse osmosis membranes, Desalination, 119, pp. 143-150. https://doi.org/10.1016/S0011-9164(98)00134-9
  2. Choi, S.H., Yang, J.H., Suh, C.W., Cho, J.W. (2011) Use of fluorescent silica particles for checking the integrity of microfiltration membranes, Journal of Membrane Science, 367, pp. 306-313. https://doi.org/10.1016/j.memsci.2010.11.015
  3. Farahbakhs, K., and Smith, D.W. (2004) Estimating air diffusion contribution to pressure decay during membrane integrity tests, Journal of Membrane Science, 237, pp. 203-212. https://doi.org/10.1016/j.memsci.2004.03.015
  4. Giglia, S., and Krishnan, M. (2008) High sensitivity binary gas integrity test for membrane filters, Journal of Membrane Science, 323, pp. 60-66. https://doi.org/10.1016/j.memsci.2008.06.017
  5. Gil F. Crozes Sandeep Sethi, Baoci Mi, Jason Curl, Benito Marinas, (2002). Improving membrane integrity monitoring indirect methods to reduce plant downtime and increase microbial removal credit, Desalination, 149, pp. 493-497. https://doi.org/10.1016/S0011-9164(02)00787-7
  6. Glucina, K., Do-Quang, Z., Laine, J.M. (1997) Assessment of a particle counting method for hollow fiber membrane integrity, Desalination, 113, pp. 183-187. https://doi.org/10.1016/S0011-9164(97)00127-6
  7. Guibert, D., Colling, A. (2011) Direct membrane integrity testing : Impact of parameter selection on log removal value calculations, Desalination, 272, pp. 174-178. https://doi.org/10.1016/j.desal.2011.01.017
  8. Guo, H., Wyart, Y., Perot, J., Nauleau, F., Moulin, P. (2010) Application of magnetic nanoparticles for UF membrane integrity monitoring at low-pressure operation, Journal of Membrane Science, 350, pp. 172-179. https://doi.org/10.1016/j.memsci.2009.12.025
  9. Hur, H.C., Rhee, O.J., Lee, K.J., Kim, K.H., Choi, Y.J., Lee, J.J., Hong, S.K. (2008) Analysis of membrane integrity and removal efficiency considering membrane defect and pore size, Journal of Korean Society on Water Quality, 24(4), pp. 423-429.
  10. Masson, P.L. (1987) Particle counting immunoassay-an overview, Journal of Pharmaceutical & Biomedical Analysis, 5(2), pp. 113-117. https://doi.org/10.1016/0731-7085(87)80013-4
  11. Miller, C.R., Vogel, R., Surawski, P., Jack, K.S., Corrie, S.R., Trau, M. (2005) Functionalized organosilica microspheres via a novel emulsion-based route, Langmuir, 21, pp. 9733-9740. https://doi.org/10.1021/la0514112
  12. Nismith, J. (2005) Membrane integrity - direct turbidity measurement of filtrate from MF membrane modules at an operating potable water treatment plant, Desalination, 179, pp. 25-30. https://doi.org/10.1016/j.desal.2004.11.052
  13. Panglisch, S., Deinert, U., Dautzengerg, W., Keipke, O., Gimbel, R. (1998) Monitoring the integrity of capillary membranes by particle counters, Desalination, 19, pp. 65-72.
  14. Vogel, R., Surawski, P.P.T., Littleton, B.L., Miller, C.R., Lawrie, G.A., Battersby, B.J., Trau, M. (2007) Fluorescent organosilica micro-and nanoparticles with controllable size, Journal of Colloid and Interface Science, 310, pp. 144-150. https://doi.org/10.1016/j.jcis.2007.01.092