한국섬유공학회지 (Textile Science and Engineering)

  • 제51권2호
  • /
  • Pages.84-88
  • /
  • 2014
  • /
  • 1225-1089(pISSN)
  • /
  • 2288-6419(eISSN)
한국섬유공학회 (The Korean Fiber Society)
권호 표지
DOI QR코드

DOI QR Code

반응성 상용화제를 사용한 Poly(ethylene terephthalate)/Polyamide 6 블렌드로 부터 알로이 섬유의 제조와 구조 및 성능분석(I) -반응성 상용화제가 블렌드의 모폴로지 및 열적 특성에 미치는 영향-

Preparation and Properties of Alloy Fibers Obtained from Poly(ethylene terephthalate)/Polyamide 6 Blends by Using a Reactive Compatibilizer(I) -Effect of Reactive Compatibilizer on Morphology, and Thermal and Rheological Properties-

  • 조징 (금오공과대학교 소재디자인공학과) ;
  • 민병길 (금오공과대학교 소재디자인공학과)
  • Zhou, Jing (Department of Materials Design Engineering, Kumoh National Institute of Technology) ;
  • Min, Byung Gil (Department of Materials Design Engineering, Kumoh National Institute of Technology)
  • 투고 : 2014.02.21
  • 심사 : 2014.04.05
  • 발행 : 2014.04.30
⟨ 이전 논문 다음 논문 ⟩

초록

The effect of a reactive compatibilizer on the morphology, and thermal and rheological properties of alloy fibers obtained from poly(ethylene terephthalate) (PET)/polyamide 6 (PA6) blends was investigated. An epoxy of bisphenol-A type was selected as the reactive compatibilizer for preparing the polymer alloy fibers by enhancing the compatibility of immiscible blends of PA6 and PET. The PET/PA6/epoxy alloy is expected to be used for preparing practically useful alloy fibers with various advantages such as low cost and high moisture absorption. The PA6/PET/epoxy alloy was successfully prepared via melt compounding by using a twin-screw extruder. The domain size of the poor component decreased enough to result in alloy fibers with reasonable mechanical properties. Further, it was found that the cold crystallization temperature of PA6 in the alloy decreased with increasing epoxy amount, but that of PET increased owing to the significant difference between the crystallization rates of PET and PA6. The $T_g$ values for both polymers in the alloy showed a shift along the direction between them. All the results implied that chemical reactions occurred between epoxy and end groups of PA6 and PET, resulting in improved compatibilization.

키워드

참고문헌

  1. K. C. Park and Y. H. Kim, "Preparation and Characterization of Polypropylene/Poly(L-lactic acid) Blend Fibers", Text Sci Eng, 2013, 50, 75-82. https://doi.org/10.12772/TSE.2013.50.075
  2. G. H. Bae, M. J. Ham, and Y. H. Kim, "Effects of Compatibilizers on PPS/PET and PPS/PA66 Blends", Text Sci Eng, 2012, 49, 56-65. https://doi.org/10.12772/TSE.2012.49.1.056
  3. K. Kubo and J. Masamoto, "Dispersion of Poly(phenylene ether) in a Poly(phenylene sufide)/Poly(phenylene ether) Alloy", Macromol Mater Eng, 2001, 286, 555-559. https://doi.org/10.1002/1439-2054(20010901)286:9<555::AID-MAME555>3.0.CO;2-W
  4. W. Tang, X. Hu, J. Tang, and R. Jin, "Toughening and Compatibilization of Polyphenylene Sulfide/Nylon 66 Blends with SEBS and Maleic Anhydride Grafted SEBS Triblock Copolymers", J Appl Polym Sci, 2007, 106, 2648-2655. https://doi.org/10.1002/app.26832
  5. G. H. Bae, M. J. Ham, and Y. H. Kim, "Preparation and Characterization of Poly(phenylene sulfide)/Poly(ethylene terephthalate) Blends", Text Sci Eng, 2010, 47, 352-360.
  6. T. Hisamatsu, S. Nakano, T. Adachi, M. Ishikawa, and K. Iwakura, "The Effect of Compatibility on Toughness of PPS/SEBS Polymer Alloy", Polymer, 2000, 41, 4803-4809. https://doi.org/10.1016/S0032-3861(99)00489-9
  7. S. Fakirov, M. Evstatiev, and S. Petrovich, "Microfibrillar Reinforced Composites from Binary and Ternary Blends of Polyesters and Nylon 6", Macromolecules, 1993, 26, 5219-5226. https://doi.org/10.1021/ma00071a038
  8. C. K. Samios and N. K. Kalfoglou, "Compatibilization of Poly(ethylene terephthalate)/polyamide 6 alloys: Mechanical, Thermal and Morphological Characterization", Polymer, 1999, 40, 4811-4819. https://doi.org/10.1016/S0032-3861(98)00709-5
  9. J. Zhou and B. G. Min, "Interfacial Localization of Multiwalled Carbon Nanotubes in Immiscible Blend of Poly(ethylene terephthalate)/polyamide 6", Fiber Polym, 14(4), 518-524. https://doi.org/10.1007/s12221-013-0518-4
  10. J. Zhou and B. G. Min, "Compatibilizing Effect of Epoxy Resin on the Phase Separation and Properties of Polyamide 6/poly(ethylene terephthalate) Blends", Text Sci Eng, 2014, 51, 21-26. https://doi.org/10.12772/TSE.2014.51.021

피인용 문헌

  1. Preparation and Properties of Poly(ethylene terephthalate)/Nylon 6 Alloy Fibers Using Epoxy as a Reactive Compatibilizer(II) -Preparation and Properties of Alloy Fibers- vol.51, pp.5, 2014, https://doi.org/10.12772/TSE.2014.51.252
  2. Influence of different compatibilizers on the morphology and properties of PA6/PET/glass fiber composites vol.135, pp.26, 2018, https://doi.org/10.1002/app.46429