Membrane and Water Treatment

Techno-Press (테크노프레스)
권호 표지
DOI QR코드

DOI QR Code

Pervaporation separation of ethanol via adsorbent-filled silicon rubber membranes

  • Ji, Ling-Yun (Department of Chemistry, College of Science, Northeast Forestry University) ;
  • Shi, Bao-Li (Department of Chemistry, College of Science, Northeast Forestry University) ;
  • Wang, Qing-Wen (Key Laboratory of Bio-Based Material Science and Technology of Ministry of Education, Northeast Forestry University)
  • Received : 2014.05.20
  • Accepted : 2014.10.16
  • Published : 2014.10.25
⟨ Previous Next ⟩

Abstract

Pervaporation is the most promising technique for the recovery of ethanol from the fermentation system. To date, extensive research has been conducted on the exploration of membrane materials with favorable properties. In this paper, we primarily review the performance of adsorbent-filled rubbery membranes. In addition, the fundamental mechanisms of ethanol and water molecules transportation through composite membranes are demonstrated, particularly from the perspective of cluster formation. Finally, future prospects are also analyzed to develop the guidelines for the future development of excellent membrane materials for ethanol concentration. This paper is not meant to be an exhaustive overview, rather a specialized summary that allows readers to select the information appropriated to their topics.

Keywords

Acknowledgement

Supported by : National Natural Science Foundation of China

References

  1. Abdehagh, N., Tezel, F.H. and Thibault, J. (2014), "Separation techniques in butanol production: challenges and developments", Biomass Bioenergy, 60, 222-246. https://doi.org/10.1016/j.biombioe.2013.10.003
  2. Adnadjevic, B., Jovanovic, J. and Gajinov, S. (1997), "Effect of different physicochemical properties of hydrophobic zeolites on the pervaporation properties of PDMS-membranes", J. Membr. Sci., 136(1-2), 173-179. https://doi.org/10.1016/S0376-7388(97)00161-0
  3. Aroon, M.A., Ismail, A.F., Matsuura, T. and Montazer-Rahmati, M.M. (2010), "Performance studies of mixed matrix membranes for gas separation: A review", Sep. Puri. Technol., 75(3), 229-242. https://doi.org/10.1016/j.seppur.2010.08.023
  4. Baker, R.W., Wijmans, J.G. and Huang, Y. (2010), "Permeability, performance and selectivity: A preferred way of reporting pervaporation performance date", J. Membr. Sci., 348(1-2), 346-352. https://doi.org/10.1016/j.memsci.2009.11.022
  5. Beaumelle, D., Marin, M. and Gilbert, H. (1993), "Pervaporation with organophilic membranes: State of the art", Food Bioprod. Process., 71(c2), 77-89.
  6. Bennett, M., Brisdon, B.J., England, R. and Field, R.W. (1997), "Performance of PDMS and organofunctionalised PDMS membranes for the pervaporative recovery of organics from aqueous streams", J. Membr. Sci., 137(1-2), 63-88. https://doi.org/10.1016/S0376-7388(97)00183-X
  7. Bowen, T.C., Li, S., Noble, R.D. and Falconer, J.L. (2003), "Driving force for pervaporation through zeolite membranes", J. Membr. Sci., 225(1-2), 165-176. https://doi.org/10.1016/j.memsci.2003.07.016
  8. Bowen, T.C., Nobel, R.D. and Falconer, J.L. (2004), "Fundamentals and application of pervaporation through zeolite membranes", J. Membr. Sci., 245(1-2), 1-33. https://doi.org/10.1016/j.memsci.2004.06.059
  9. Bowen, T.C., Meier, R.G. and Vane, L.M. (2007), "Stability of MFI zeolite-filled PDMS membranes during pervaporative ethanol recovery from aqueous mixtures containing acetic acid", J. Membr. Sci., 298(1-2), 117-125. https://doi.org/10.1016/j.memsci.2007.04.007
  10. Bueso, L., Osorio-Galindo, M., Alcaina-Miranda, I. and Ribes-Greus, A. (2000), "Swelling behavior of pervaporation membranes in ethanol-water mixtures", J. Appl. Polym. Sci., 75(11), 1424-1433. https://doi.org/10.1002/(SICI)1097-4628(20000314)75:11<1424::AID-APP15>3.0.CO;2-T
  11. Chang, K.S. Chung, Y.C. Yang, T.H. Lue, S.J. Tung, K.L. and Lin, Y.F. (2012), "Free-volume and alcohol transport properties of PDMS membranes: Insights of nano-structure and interfacial affinity from molecular modeling", J. Membr. Sci., 417-418, 119-130. https://doi.org/10.1016/j.memsci.2012.06.019
  12. Chapman, P.D., Oliveira, T., Livingston, A.G. and Li, K. (2008), "Membranes for the dehydration of solvents by pervaporation", J. Membr. Sci., 318(1-2), 5-37. https://doi.org/10.1016/j.memsci.2008.02.061
  13. Chen, H.Z. and Qiu, W.H. (2010), "Key technologies for bioethanol production from lignocellulose", Biotechnol. Advances, 28(5), 556-562. https://doi.org/10.1016/j.biotechadv.2010.05.005
  14. Chen, X., Ping, Z.H. and Long, Y.C. (1998), "Separation properties of alcohol-water mixtures through silicalite-1-filled silicone rubber membranes by pervaporation", J. Appl. Polym. Sci., 67(4), 629-636. https://doi.org/10.1002/(SICI)1097-4628(19980124)67:4<629::AID-APP5>3.0.CO;2-4
  15. Chung, T.S., Jiang, L.Y., Li, Y. and Kulprathipanja, S. (2007), "Mixed matrix membranes (MMMs) comprising organic polymers with dispersed inorganic fillers for gas separation", Prog. Polym. Sci., 32(4), 483-507. https://doi.org/10.1016/j.progpolymsci.2007.01.008
  16. Cleas, S., Vandezande, P., Mullens, S., Leysen, R., De Sitter, K., Andersson, A., Maurer, F.H.J., Van den Rul, H., Peeters, R. and Van Bael, M.K. (2010), "High flux composite PTMSP-silica nanohybrid membranes for the pervaporation of ethanol/water mixtures", J. Membr. Sci., 351(1-2), 160-167. https://doi.org/10.1016/j.memsci.2010.01.043
  17. Claes, S., Vandezande, P., Mullens, S., De Sitter, K., Peeters, R. and Van Beal, M.K. (2012), "Preparation and benchmarking of thin film supported PTMSP-silica pervaporation membranes", J. Membr. Sci., 389, 265-271. https://doi.org/10.1016/j.memsci.2011.10.035
  18. De Smet, K., Pleysier, A., Vankelecom, I.F.J. and Jacobs, P.A. (2003), "Recycling of homogeneous hydrogenation catalyst by dialysis", Chem. Eur. J., 9(1), 334-338. https://doi.org/10.1002/chem.200390028
  19. Dobrak, A., Figoli, A., Chovau, S., Galiano, F., Simone, S., Vankelecom, I.F.J., Drioli, E. and Van der Bruggen, B. (2010), "Performance of PDMS membranes in pervaporation: Effect of silicalite fillers and comparison with SBS membranes", J. Colloid. Interf. Sci., 346(1), 254-264. https://doi.org/10.1016/j.jcis.2010.02.023
  20. Favre, E., Schaetzal, P., Nguyen, Q.T., Clement, R. and Neel, J. (1994), "Sorption, diffusion and vapour permeation of various penetrants through dense poly (dimethylsiloxane) membranes: A transport analysis", J. Membr. Sci., 92(2), 169-184. https://doi.org/10.1016/0376-7388(94)00060-3
  21. Flanigen, E.M., Bennet, J.M., Grose, R.M., Cohen, J.P., Patton, R.L., Kirchner, R.M. and Smith, J.V. (1978), "Silicalite, a new hydrophobic crystalline silica molecular sieve", Nature, 271(5645), 512-516. https://doi.org/10.1038/271512a0
  22. Fritz, L. and Hofmann, D. (1997), "Molecular dynamics of permeation of the transport of water-ethanol mixtures through polydimethylsiloxane membranes", Polymer, 38, 1035-1045. https://doi.org/10.1016/S0032-3861(96)00600-3
  23. Gee, R.H., Maxwell, R.S. and Balazs, B. (2004), "Molecular dynamics studies on the effects of water speciation on interfacial structure and dynamic in silica-filled PDMS composites", Polymer, 45(11), 3885-3891. https://doi.org/10.1016/j.polymer.2004.01.078
  24. Ghofar, A. and Kokugan, T. (2004), "The pervaporation mechanism of dilute ethanol solution by hydrophobic porous membranes", Biochem. Eng. J., 18(3), 235-238. https://doi.org/10.1016/j.bej.2003.09.002
  25. Gonzalez-Velasco, J.R., Gonzalez-Marcos, J.A. and Lopez-Dehesa, C. (2002), "Pervaporation of ethanolwater mixtures through poly (1-trimethylsilyl-1-propyne) (PTMSP) membranes", Desalination, 149(1-3), 61-65. https://doi.org/10.1016/S0011-9164(02)00692-6
  26. Grun, M., Lauer, I. and Unger, K.K. (1997), "The synthesis of micrometer-and submicrometer-size spheres of ordered mesoporous oxide MCM-41", Adv. Mater., 9(3), 254-257. https://doi.org/10.1002/adma.19970090317
  27. Guo, J.X., Zhang, G.J., Wu, W. Ji, S.L., Qin, Z.P. and Liu, Z.Z. (2010), "Dynamically formed inner skin hollow-fiber polydimethylsiloxane/polysulfone composite membrane for alcohol permselective pervaporation", Chem. Eng. J., 158(3), 558-565. https://doi.org/10.1016/j.cej.2010.01.053
  28. Heintz, A. and Stephan, W. (1994), "A generalized solution-diffusion model of the pervaporation process through composite membranes Part II. Concentration polarization, coupled diffusion and the influence of the porous support layer", J. Membr. Sci., 89(1-2), 153-169. https://doi.org/10.1016/0376-7388(93)E0223-7
  29. Hoffman, D., Fritz, L. and Paul, D. (1998), "Molecular modeling of pervaporation separation of binary mixtures with polymeric membranes", J. Membr. Sci., 144(1-2), 145-159. https://doi.org/10.1016/S0376-7388(98)00048-9
  30. Huang, J. and Meagher, M.M. (2001), "Pervaporation recovery of n-butanol from aqueous solutions and ABE fermentation broth using thin-film silicalite-filled-silicone composite membranes", J. Membr. Sci., 192(1-2), 231-242. https://doi.org/10.1016/S0376-7388(01)00507-5
  31. Jia, M.D. Pleinemann, K.V. and Behling, R.D. (1992), "Preparation and characterization of thin-film zeolite-PDMS composite membranes", J. Membr. Sci., 73(2-3), 119-128. https://doi.org/10.1016/0376-7388(92)80122-Z
  32. Jiang, L.Y., Chung, T.S. and Rajagopalan, R. (2007), "Matrimid/MgO mixed membranes for iso-propanol dehydration by pervaporation", AIChE J., 53(7), 1745-1757. https://doi.org/10.1002/aic.11198
  33. Kariduraganavar, M.Y., Varghese, J.G., Choudhari, S.K. and Olley, R.H. (2009), "Organic-inorganic hybrid membranes: Solving the trade-off phenomenon between permeation flux and selectivity in pervaporation", Ind. Eng. Chem. Res., 48(8), 4002-4013. https://doi.org/10.1021/ie8016626
  34. Khajavi, S., Jansen, J.C. and Kapteijn, F. (2009), "Application of hydroxy sodalite films as novel water selective membranes", J. Membr. Sci., 326(1), 153-160. https://doi.org/10.1016/j.memsci.2008.09.046
  35. Kokugan, T., Kaseno, Yoshimoto, E. and Kikukawa, H. (1998), "A consideration of pervaporation by porous hydrophobic membranes for dilute ethanol solution", J. Chem. Eng. Jpn., 31(1), 153-156. https://doi.org/10.1252/jcej.31.153
  36. Kujawski, W., Staniszewski, M. and Nguyen, T.Q. (2007), "Transport parameters of alcohol vapors through ion-exchange membranes", Sep. Purif. Technol., 57(3), 476-482. https://doi.org/10.1016/j.seppur.2006.08.027
  37. Lee, J.J., Cho, E.J., Kim, Y.G., Choi, I.S. and Bae, H.J. (2012), "Pervaporation separation of bioethanol using a polydimethylsiloxane/polyetherimide composite hollow-fiber membrane", Bioresour. Technol., 109, 110-115. https://doi.org/10.1016/j.biortech.2012.01.060
  38. Li, L., Xiao, Z., Tan, S., Pu, L. and Zhang, Z. (2004), "Composite PDMS membrane with high flux for the separation of organics from water by pervaporation", J. Membr. Sci., 243(1-2), 177-187. https://doi.org/10.1016/j.memsci.2004.06.015
  39. Li, S.Y., Srivastava, R. and Parnas, R.S. (2010), "Separation of 1-butanol by pervaporation using a novel tri-layer PDMS composite membrane", J. Membr. Sci., 363(1-2), 287-294. https://doi.org/10.1016/j.memsci.2010.07.042
  40. Lin, X., Kita, K. and Okamoto, K. (2001), "Silicate membrane preparation, characterization, and separation performance", Ind. Eng. Chem. Res., 40(19), 4069-4078. https://doi.org/10.1021/ie0101947
  41. Lin, D.J., Chang, C.L., Shaw, H.Y., Jeng, Y.S. and Cheng, L.P. (2004), "Formation of multilayer poly(acrylic acid)/poly(vinylidene fluoride) composite membranes for pervaporation", J. Appl. Polym. Sci., 93(5), 2266-2274. https://doi.org/10.1002/app.20775
  42. Lipnizki, F. (2010), "Membrane process opportunities and challenges in the bioethanol industry", Desalination, 250(3), 1067-1069. https://doi.org/10.1016/j.desal.2009.09.109
  43. Liu, G.P., Wei, W., Jin, W.Q. and Xu, N.P. (2012), "Polymer/ceramic composite membranes and their application in pervaporation process", Chinese J. Chem. Eng., 20(1), 62-70. https://doi.org/10.1016/S1004-9541(12)60364-4
  44. Long, Y.C., Chen, X., Ping, Z.H., Fu, S.K. and Sun, Y.J. (1994), "MFI-type zeolite filled silicone rubber membranes: preparation, composition, and performance", Stud. Surf. Sci. Catal., 84, 1083-1090. https://doi.org/10.1016/S0167-2991(08)63645-9
  45. Lonsdale, H.K. (1982), "The growth of membrane and technology", J. Membr. Sci., 10(2-3), 81-181. https://doi.org/10.1016/S0376-7388(00)81408-8
  46. Lue, S.J., Yang, T.H., Chang, K.S. and Tung, K.L. (2012), "Water diffusion suppression and ethanol-over-water diffusion selectivity enhancement for ethanol/water mixtures in polydimethylsiloxanezeolite membranes", J. Membr. Sci., 415-416, 635-643. https://doi.org/10.1016/j.memsci.2012.05.044
  47. Mahajan, R., Burns, R., Schaeffer, M. and Koros, W.J. (2002), "Challenge in forming successful mixed matrix membranes with rigid polymeric materials", J. Appl. Polym. Sci., 86(4), 881-890. https://doi.org/10.1002/app.10998
  48. Miyagi, A., Nabetani, H. and Nakajima, M. (2012), "Analysis of transport mechanism of binary organic solvent system through a PDMS-based dense membrane using a regular solution model combined with a solution-diffusion model", Sep. Purif. Technol., 88, 216-226. https://doi.org/10.1016/j.seppur.2011.12.005
  49. Miyata, T., Higuchi, J., Okuno, H. and Uragami, T. (1996), "Preparation of polydimethylsiloxane/ polystyrene interpenetrating polymer network membranes and permeation of aqueous ethanol solutions through the membranes by pervaporation", J. Membr. Sci., 61(8), 1315-1324.
  50. Moermans, B., Beuckelaer, W.D., Vankelecom, I.F.J., Ravishankar, R., Martens, J. and Jacobs, P. (2000), "Incorporation of nano-sized zeolites in membranes", Chem. Commun., (24), 2467-2468.
  51. Muller-Plathe, F. (1991), "Diffusion of penetrants in amorphous polymers: a molecular dynamics study", J. Chem. Phys., 94, 3192-3199. https://doi.org/10.1063/1.459788
  52. Nagy, E. (2004), "Nonlinear, coupled mass transfer through a dense membrane", Desalination, 163(1-3), 345-354. https://doi.org/10.1016/S0011-9164(04)90207-X
  53. Nakamoto, H. and Takahashi, H. (1982), "Hydrophobic natures of zeolite ZSM-5", Zeolites, 2(2), 67-68. https://doi.org/10.1016/S0144-2449(82)80002-X
  54. Nasiri, H. and Aroujalian, A. (2010), "A novel model based on cluster formation for pervaporation separation of polar components from aqueous solutions", Sep. Purif. Technol., 72(1), 13-21. https://doi.org/10.1016/j.seppur.2009.12.020
  55. Nitsche, V., Ohlrogge, K. and Sturken, K. (1998), "Separation of organic vapors by means of membranes", Chem. Eng. Technol., 21(12), 925-935. https://doi.org/10.1002/(SICI)1521-4125(199812)21:12<925::AID-CEAT925>3.0.CO;2-0
  56. Nobel, R.D. (2011), "Perspectives on mixed matrix membranes", J. Membr. Sci., 378(1-2), 393-397. https://doi.org/10.1016/j.memsci.2011.05.031
  57. O'Brien, D.J., Roth, L.H. and MaAloon, A.J. (2000), "Ethanol production by continuous fermentationpervaporation: a preliminary economic analysis", J. Membr. Sci., 166(1), 105-111. https://doi.org/10.1016/S0376-7388(99)00255-0
  58. Offeman, R.D. and Ludvik, C.N. (2011), "A novel method to fabricate high permeance, high selectivity thin-film membranes", J. Membr. Sci., 380(1-2), 163-170. https://doi.org/10.1016/j.memsci.2011.07.005
  59. Olson, D.H., Haag, W.O. and Lago, R.M. (1980), "Chemical and physical properties of the ZSM-5 substitutional series", J. Catal., 61(2), 390-396. https://doi.org/10.1016/0021-9517(80)90386-3
  60. Osorio-Galindo, M., Iborra-Clar, A., Alcaina-Miranda, I. and Ribes-Greus, A. (2001), "Characterization of poly(dimethylsiloxane)-poly(methyl hydrogen siloxane) composite membranes for organic water pervaporation separation", J. Appl. Polym. Sci., 81(3), 546-556. https://doi.org/10.1002/app.1469
  61. Peng, P., Shi, B.L. and Lan, Y.Q. (2011a), "A review of membrane materials for ethanol recovery by pervaporation", Sep. Sci. Technol., 46(2), 234-246.
  62. Peng, P., Shi, B.L. and Lan, Y.Q. (2011b), "Preparation of PDMS-silica nanocomposite membranes with silane coupling for recovering ethanol by pervaporation", Sep. Sci. Technol., 46(3), 420-427. https://doi.org/10.1080/01496395.2010.527896
  63. Pouget, E., Tonnar, J., Lucas, P., Lacroix-Desmazes, P., Ganachaud, F. and Boutevin, B. (2010), "Wellarchitectured poly (dimethylsiloxane)-containing copolymers obtained radical chemistry", Chem. Rev., 110(3), 1233-1277. https://doi.org/10.1021/cr8001998
  64. Qiao, X.Y. and Chung, T.S. (2005), "Fundamental characteristics of sorption, swelling, and permeation of P84 co-polymide membranes for pervaporation dehydration of alcohols", Ind. Eng. Chem. Res., 44(23), 8938-8943. https://doi.org/10.1021/ie050836g
  65. Radovanovic, P., Thiel, S.W. and Hwang, S. (1990), "Transport of ethanol-water dimers in pervaporation through a silicon rubber membrane", J. Membr. Sci., 48(1), 55-65. https://doi.org/10.1016/S0376-7388(00)80795-4
  66. Raina, G., Kulkarni, G.U. and Rao, C.R. (2001), "Mass spectrometric determination of the surface composition of ethanol-water mixtures", Int. J. Mass Spectrom., 212(1-3), 267-271. https://doi.org/10.1016/S1387-3806(01)00461-4
  67. Rautenabach, R., Klatt, S. and Vier, J. (1992), "State of the art of pervaporation: 10 years of industrial PV", Processings of the 6th International Conference on Pervaporation Process in Chemical Industry, Eaglewood, NJ, USA, September.
  68. Shao, P. and Huang, R.Y.M. (2007), "Polymeric membrane pervaporation", J. Membr. Sci., 287(2), 162-179. https://doi.org/10.1016/j.memsci.2006.10.043
  69. Smitha, B., Suhanya, D., Sridhar, S. and Ramakrishna, M. (2004), "Separation of organic-organic mixtures by pervaporation-A review", J. Membr. Sci., 241(1), 1-21. https://doi.org/10.1016/j.memsci.2004.03.042
  70. Sommer, S. and Melin, T. (2005), "Influence of operation parameters on the separation mixtures by pervaporation and vapor permeation with inorganic membranes. Part 1: Dehydration of solvents", Chem. Eng. Sci., 60(16), 4509-4523. https://doi.org/10.1016/j.ces.2005.02.059
  71. Sun, D., Li, B.B. and Xu, Z.L. (2013), "Pervaporation of ethanol/water mixture by organophilic nano-silica filled PDMS composite membranes", Desalination, 322, 159-166. https://doi.org/10.1016/j.desal.2013.05.008
  72. Tang, X.Y., Wang, R., Xiao, Z.Y., Shi, E. and Yang, J. (2007), "Preparation and pervaporation performances of fumed-silica-filled polydimethylsiloxane-polyamide (PA) composite membranes", J. Appl. Polym. Sci., 105(5), 3132-3137. https://doi.org/10.1002/app.26471
  73. Tanmai, Y., Tanaka, H. and Nakanishi, K. (1994), "Molecular simulation of permeation of small penetrants through membranes. 1. Diffusion coefficients", Macromolecules, 27(16), 4498-4508. https://doi.org/10.1021/ma00094a011
  74. Te Hennepe, H.J.C., Bargeman, D., Mulder, M.H.V. and Smolders, C.A. (1987), "Zeolite-filled silicon rubber membranes Part 1. Membrane preparation and pervaporation results", J. Membr. Sci., 35(1), 39-54. https://doi.org/10.1016/S0376-7388(00)80921-7
  75. Tin, P.S., Lin, H.Y., Ong, R.C. and Chung, T.S. (2011), "Carbon molecular sieve membranes for biofuel separation", Carbon, 49(2), 369-375. https://doi.org/10.1016/j.carbon.2010.09.031
  76. Tsuchiya, M., Shida, Y., Kobayashi, K., Taniguchi, O. and Okouchi, S. (2004), "Cluster composition distribution at the liquid surface of surface of alcohol-water mixtures and evaporation processes studied by liquid ionization mass spectrometry", Int. J. Mass Spectrom., 235(3), 229-241. https://doi.org/10.1016/j.ijms.2004.03.014
  77. Van der Bruggen, B. and Luis, P. (2014), "Pervaporation as a tool in chemical engineering: A new era?", Current Opinion in Chemical Enigineering, 4, 47-53. https://doi.org/10.1016/j.coche.2014.01.005
  78. Vandezande, P., Gevers, L.E.M. and Vankelecom, I.F.J. (2008), "Solvent resistant nanofiltration: Separating on a molecular level", Chem. Soc. Rev., 37(2), 365-405. https://doi.org/10.1039/B610848M
  79. Vane, L.M. (2005), "A review of pervaporation for product recovery from biomass fermentation processes", J. Chem. Technol. Biotechnol., 80(6), 603-629. https://doi.org/10.1002/jctb.1265
  80. Vane, L.M., Namboodiri, V.V. and Bowen, T.C. (2008), "Hydrophobic zeolite-silicone rubber mixed matrix membranes for ethanol-water separation: Effect of zeolite and silicone component selection on pervaporation performance", J. Membr. Sci., 308(1-2), 230-241. https://doi.org/10.1016/j.memsci.2007.10.003
  81. Vankelecom, I.F.J., Scheppers, E., Heus, R. and Uytterhoeven, J.B. (1994), "Parameters influencing zeolite incorporation in PDMS membranes", J. Phys. Chem., 98(47), 12390-12396. https://doi.org/10.1021/j100098a038
  82. Vankelecom, I.F.J., Depre, D., Beulkelaer, S.D. and Uytterhoeven, J.B. (1995), "Influence of zeolites in PDMS membranes: Pervaporation of water/alcohol mixtures", J. Phys. Chem., 99(35), 13193-13197. https://doi.org/10.1021/j100035a024
  83. Vankelecom, I.F.J., Beukelaer, S.D. and Uytterhoeven, J.B. (1997a), "Sorption and pervaporation of aroma compounds using zeolite filled PDMS membranes", J. Phys. Chem., 101(26), 5186-5190. https://doi.org/10.1021/jp962273f
  84. Vankelecom, I.F.J., Kinderen, J.D., Dewitte, B.M. and Uytterhoeven, J.B. (1997b), "Incorporation of hydrophobic porous fillers in PDMS membranes for use in pervaporation", J. Phys. Chem., 101(26), 5182-5185. https://doi.org/10.1021/jp962272n
  85. Vu, D.Q., Koros, W.J. and Miller, S.J. (2003a), "Mixed matrix membranes using carbon molecular sieve, I. Preparation and experiment results", J. Membr. Sci., 211(2), 311-334. https://doi.org/10.1016/S0376-7388(02)00429-5
  86. Vu, D.Q., Koros, W.J. and Miller, S.J. (2003b), "Mixed matrix membranes using carbon molecular sieve, II. Modeling permeation behavior", J. Membr. Sci., 211(2), 335-348. https://doi.org/10.1016/S0376-7388(02)00425-8
  87. Wakisaka, A. and Matsuura, K. (2006), "Microheterogeneity of ethanol-water binary mixtures observed at the cluster level", J. Mol. Liq., 129(1-2), 25-32. https://doi.org/10.1016/j.molliq.2006.08.010
  88. Wang, L.X., Li, X.G. and Yang, Y.L. (2001), "Preparation, properties and applications of polypyrroles", React. Funct. Polym., 47(2), 125-139. https://doi.org/10.1016/S1381-5148(00)00079-1
  89. Wang, L., Han, X.L., Li, J.D., Qin, L. and Zheng, D.J. (2012), "Preparation of modified mesoporous MCM-41 silica spheres and its application in pervaporation", Powder. Technol., 231, 63-69. https://doi.org/10.1016/j.powtec.2012.07.044
  90. Watson, J.M. and Baron, M.G. (1996), "The behavior of water in poly (dimethylsiloxane)", J. Membr. Sci., 110(1), 47-57. https://doi.org/10.1016/0376-7388(95)00229-4
  91. Wei, W., Xia, S.S., Liu, G.P., Gu, X.H., Jin, W.Q. and Xu, N.P. (2010), "Interfacial adhesion between polymer separation layer and ceramic support for composite membrane" AIChE J., 56(6), 1584-1592. https://doi.org/10.1002/aic.12086
  92. Wei, P., Cheng, L.H., Zhang, L., Xu, X.H., Chen, H.L. and Gao, C.J. (2014), "A review of membrane technology for bioethanol production", Renew. Sus. Energ. Rev., 30, 388-400. https://doi.org/10.1016/j.rser.2013.10.017
  93. Wijmans, J.G. and Baker, R.W. (1995), "The solution-diffusion model: A review", J. Membr. Sci., 107(1-2), 1-21. https://doi.org/10.1016/0376-7388(95)00102-I
  94. Wu, P., Field, R.W., England, R. and Brisdon, B.J. (2001), "A fundamental study of organofunctionalised PDMS membranes for the pervaporation recovery of phenolic compounds from aqueous streams", J. Membr. Sci., 190(2), 147-151. https://doi.org/10.1016/S0376-7388(01)00408-2
  95. Xiangli, F.J., Chen, Y.W., Jin, W.Q. and Xu, N.P. (2007), "Polydimethylsiloxane (PDMS)/ceramic composite membrane with high flux for pervaporation of ethanol-water mixtures", Ind. Eng. Chem. Res., 46(7), 2224-2230. https://doi.org/10.1021/ie0610290
  96. Xiangli, F.J., Wei, W., Chen, Y.W., Jin, W.Q. and Xu, N.P. (2008), "Optimization of preparation conditions for polydimethylsiloxane (PDMS)/ceramic composite membranes using response surface methodology", J. Membr. Sci., 311(1-2), 23-33. https://doi.org/10.1016/j.memsci.2007.11.054
  97. Ye, H., Du, Z.J., Zhang, C. and Li, H.Q. (2005), "A novel carbon black filled alcohol-permselective PDMS composite membrane", Polym. Mater. Sci. Eng., 21, 156-158.
  98. Yi, S.L., Su, Y. and Wan, Y.H. (2010), "Preparation and characterization of vinytriethoxysilane (VTES) modified silicalite-1/PDMS hybrid pervaporation membranes and its application in ethanol separation from dilute aqueous solution", J. Membr. Sci., 360(1-2), 341-351. https://doi.org/10.1016/j.memsci.2010.05.028
  99. Yuan, W., Lin, Y.S. and Yang, W. (2004), "Molecular sieving MFI-Type zeolite membranes for pervaporation separation of xylene isomers", J. Am. Chem. Soc., 126(15), 4776-4777. https://doi.org/10.1021/ja031653t
  100. Zhan, X., Li, J.D., Fan, C. and Han, X.L. (2010), "Pervaporation separation of ethanol/water mixtures with chlorosilane modified silicaite-1/PDMS hybrid membranes", Chin. J. Polym. Sci., 28(4), 625-635. https://doi.org/10.1007/s10118-010-9136-4
  101. Zhan, X., Lu, J., Feng, X.D., Ye. H., Tan, T.T. and Li, J.D. (2012), "Mixed matrix membranes with HF acid etched ZSM-5 for ethanol/water separation: Preparation and pervaporation performance", Appl. Surf. Sci., 259, 547-556. https://doi.org/10.1016/j.apsusc.2012.05.167

Cited by

  1. Mathematical Model for Numerical Simulation of Organic Compound Recovery Using Membrane Separation vol.41, pp.2, 2018, https://doi.org/10.1002/ceat.201700445
  2. Removal of acetic acid from wastewater by esterification in the membrane reactor vol.7, pp.2, 2016, https://doi.org/10.12989/mwt.2016.7.2.143
  3. Investigation on Three-Dimensional Solubility Parameters for Explanation and Prediction of Swelling Degree of Polydimethylsiloxane Pervaporation Membranes vol.54, pp.10, 2015, https://doi.org/10.1080/00222348.2015.1085272
  4. Simulation of Nonporous Polymeric Membranes Using CFD for Bioethanol Purification vol.27, pp.3, 2018, https://doi.org/10.1002/mats.201700084
  5. Drinking tastes of Chinese rice wine under different heating temperatures analyzed by gas chromatography-mass spectrometry and tribology tests vol.52, pp.1, 2021, https://doi.org/10.1111/jtxs.12571