Transactions on Electrical and Electronic Materials

  • 제14권5호
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  • Pages.258-262
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  • 2013
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  • 1229-7607(pISSN)
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  • 2092-7592(eISSN)
한국전기전자재료학회 (The Korean Institute of Electrical and Electronic Material Engineers)
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Systematic Approaches for Blue Light-emitting Polymers by Introducing Various Naphthalene Linkages into Carbazole Containing PPV Derivatives

  • Ahn, Taek (Department of Chemistry, Kyungsung University)
  • 투고 : 2013.08.13
  • 심사 : 2013.08.28
  • 발행 : 2013.10.25
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초록

Poly(2,3-naphthalenevinylene-alt-N-ethylhexyl-3,6-carbazolevinylene), 2,3-PNCPV, poly(2,6-naphthalene vinylenealt- N-ethylhexyl-3,6-carbazolevinylene), 2,6-PNCPV, and poly(1,4-naphthalenevinylene-alt-N-ethylhexyl-3,6- carbazolevinylene), 1,4-PNCPV were synthesized through the Wittig polycondensation reaction. The conjugation lengths of the polymers were controlled by differently linked naphthalenes in the polymer main chain. The resulting polymers were completely soluble in common organic solvents, and exhibited good thermal stability at up to $400^{\circ}C$. The synthesized polymers showed UV-visible absorbance and photoluminescence (PL) in the ranges of 357-374 nm and 487-538 nm, respectively. The carbazole and 2,3-linked naphthalene containing 2,3-PNCPV showed a blue PL peak at 487 nm. A single-layer light-emitting diode was fabricated with an ITO/polymer/Al configuration. The electroluminescence (EL) emission of 2,3-PNCPV was shown at 483 nm.

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참고문헌

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피인용 문헌

  1. Thermal and photoluminescence analysis of a methacrylic diester derivative of naphthalene-2,7-diol vol.126, pp.1, 2016, https://doi.org/10.1007/s10973-016-5587-3
  2. Synthesis and study of morphological, optical and electrical properties of new organic semi conducting polymers containing isosorbide pendant group vol.221, 2016, https://doi.org/10.1016/j.synthmet.2016.09.010