Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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New Application of 2-(4-N-Phenyl-3-thiosemicarbazone)-8-hydroxyquinoline as a Sensor for Relay Recognition of Cu2+ and Sulfide in Aqueous Solution

  • Tang, Lijun (Department of Chemistry, Liaoning Provincial Key Laboratory for the Synthesis and Application of Functional Compounds, Bohai University) ;
  • Zhou, Pei (Department of Chemistry, Liaoning Provincial Key Laboratory for the Synthesis and Application of Functional Compounds, Bohai University) ;
  • Huang, Zhenlong (Department of Chemistry, Liaoning Provincial Key Laboratory for the Synthesis and Application of Functional Compounds, Bohai University) ;
  • Zhao, Jia (Department of Chemistry, Liaoning Provincial Key Laboratory for the Synthesis and Application of Functional Compounds, Bohai University) ;
  • Cai, Mingjun (Department of Chemistry, Liaoning Provincial Key Laboratory for the Synthesis and Application of Functional Compounds, Bohai University)
  • Received : 2013.06.24
  • Accepted : 2013.07.05
  • Published : 2013.10.20
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Abstract

Fluorescent and colorimetric recognition properties of 2-(4-N-phenyl-3-thiosemicarbazone)-8-hydroxyquinoline (1) in buffered aqueous solution (1% DMSO, HEPES 20 mM, pH = 7.4) have been examined. Sensor 1 displays highly selective and sensitive recognition to $Cu^{2+}$ with fluorescence "ON-OFF" performance. The in situ formed 1-$Cu^{2+}$ complex exhibits an excellent selectivity toward sulfide ions with fluorescence "OFF-ON" behavior via $Cu^{2+}$ displacement approach. Thus, relay recognition of $Cu^{2+}$ and sulfide by a known molecule 1 has been achieved.

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References

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