Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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An off-on Fluorescent Sensor for Detecting a Wide Range of Water Content in Organic Solvents

  • Kim, Kang-Hyeon (School of Applied Chemical Engineering, Chonnam National University) ;
  • Lee, Wan-Jin (School of Applied Chemical Engineering, Chonnam National University) ;
  • Kim, Jae Nyoung (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Kim, Hyung Jin (School of Applied Chemical Engineering, Chonnam National University)
  • Received : 2013.03.13
  • Accepted : 2013.05.02
  • Published : 2013.08.20
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Abstract

This paper describes the synthesis and water sensing properties of a fluorescent photoinduced electron transfer (PET) sensor (5) with an extended operating sensing range. The 1,8-naphthalimide derivative (5) attached with a piperazine group and a carboxylic group was synthesized and applied as a fluorescent water sensor in water-miscible organic solvents. The fluorescence intensity of the dye 5 increased with increasing water content up to 80% (v/v) and the fluorescence intensities were enhanced 45-, 67- and 122-fold in aqueous EtOH, DMF and DMSO solutions, respectively. In aqueous acetone solution, the enhancement of the fluorescence intensities was somewhat lower (30-fold) but the response range was wider (0-90%, v/v).

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