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Study on the Electrolyte for Zn-Br Redox Flow Battery

Zn-Br 레독스 흐름 전지용 전해액에 관한 연구

  • 최호상 (경일대학교 화학공학과) ;
  • 오용환 (호서대학교 일반대학원 그린에너지공학과) ;
  • 유철휘 (호서대학교 일반대학원 그린에너지공학과) ;
  • 황갑진 (호서대학교 일반대학원 그린에너지공학과)
  • Received : 2013.07.29
  • Accepted : 2013.08.31
  • Published : 2013.08.31

Abstract

Four types of electrolyte were tested for the application as an electrolyte in the Zn-Br redox flow battery. Electrolyte was consist of $ZnBr_2$ (electrolyte number 1), $ZnBr_2+KCl$ (electrolyte number 2), $ZnBr_2+KCl+NH_4Br$ (electrolyte number 3) and $ZnBr_2+KCl+EMPBr(C_7H_{16}BF_4N)$ (electrolyte number 4). The each electrolyte property was measured by CV (cyclic voltammetry) method. The different between the potential of anodic and cathodic maximum current density in a CV experiment (${\Delta}E_P$) was 0.89V, 0.89V, 1.06V and 0.61V for the electrolyte number 1, 2, 3 and 4, respectively. The electrolyte involved KCl increased conductivity which was appeared by anodic and cathodic maximum current density in a CV experiment. It was estimated that the electrolyte of number 3 ($ZnBr_2+KCl+NH_4Br$) and number 4 ($ZnBr_2+KCl+EMPBr$) could be suitable as an electrolyte in the Zn-Br redox flow battery with non-appeared bubble, non-Br formation and high anodic-cathodic maximum current density.

Keywords

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  1. Characteristics of the Zn-Br Redox Flow Battery using the Different Electrolyte and Membrane vol.27, pp.4, 2016, https://doi.org/10.7316/KHNES.2016.27.4.365
  2. Supporting Material for Highly Reversible Zinc-Bromine Electrolytes vol.37, pp.3, 2016, https://doi.org/10.1002/bkcs.10669