Journal of the Korean Applied Science and Technology (한국응용과학기술학회지)

The Korean Society of Applied Science and Technology (한국응용과학기술학회)
권호 표지
DOI QR코드

DOI QR Code

Synthesis and Properties of Glycidyl Succinate Type Cationic Gemini Surfactant

2-메틸숙신산을 이용한 에스테르계 제미니 양이온 계면활성제의 합성 및 물성

  • Park, Jong-Kwon (Department of Engineering Chemistry, College of Engineering Chungbuk National University Chemistry) ;
  • Kim, Won-Kyun (Department of Engineering Chemistry, College of Engineering Chungbuk National University Chemistry) ;
  • Jeong, Noh-Hee (Department of Engineering Chemistry, College of Engineering Chungbuk National University Chemistry)
  • 박종권 (충북대학교 공과대학 공업화학과) ;
  • 김원균 (충북대학교 공과대학 공업화학과) ;
  • 정노희 (충북대학교 공과대학 공업화학과)
  • Received : 2013.05.24
  • Accepted : 2013.06.25
  • Published : 2013.06.30
Download PDF
⟨ Previous Next ⟩

Abstract

This study is to do with the synthesis of glycidyl succinate cationic gemini surfactant. The gemini surfactant was synthesized with using 2-methyl disodium succinate, epichlorohydrine and N,N-dimethyl dodecyl amine. The target material was confirmed by FT-IR, $^1H$-NMR and was tested their properties. Surface active properties such as surface tension, evaluated cmc, emulsing properties, foaming properties were measured respectively at given conditions. The surface tensions for the aqueous solution of gemini surfactant were 33~34 dyne/cm and their cmc values evaluated by surface tension method were $10^{-4}{\sim}10^{-3}mol/L$. Emulsing properties of gemini surfactant was better in organic solvent and foaming power was confirmed good stability.

이 연구는 글리시딜 숙시네이트 양이온 제미니 계면활성제의 합성에 관한 것이다. 제미니 계면활성제는 2-메틸 디소디움 숙시네이트와 에피클로로히드린, N, N-디메틸 도데실 아민을 사용하여 합성하였다. FT-IR과 $^1H$-NMR을 통해 물성을 확인하였다. 표면장력과 cmc 측정, 유화력 및 기포력을 각각 주어진 조건을 이용하여 측정하였다. 제미니 계면활성제의 표면장력은 33~34 dyne/cm이며 cmc 값은 $10^{-4}{\sim}10^{-3}mol/L$ 였다. 제미니 계면활성제의 유화력은 유기용매에서 더 우수하였고 기포력이 안정한 것을 확인하였다.

Keywords

References

  1. K. D. Nam, N. H. Jeong, "Organic Industrial Chemistry", Bo Sung Gak, (1998).
  2. J. Schick and M. Fowkes, "Cationic Surfact ants", MARCEL DEKKER, New York, (1970).
  3. D. T. Lee, H. Kim and H. S. Cho "Gemini surfactant" J. of Korean Oil Chemist Soc., 11(1), 1, (2010).
  4. F. M. Menger and C. A. Littau, "Gemini surfactants: synthesis and properties", J. Am. Chem. Soc., 113, 1452 (1991).
  5. B. J. Kim, H. G. Kim, J. K. Lee and S. S. Mun, "Stability and Characterization of Triethanolamine Type Cation Surfactants", J. Korean Ind. Eng. Chem., 20 , 140, (2009).
  6. R. G. Alargova, I. I. Kochijashky, M. L. Sierra, K. Kwetkat and R. Zana, "Mixed Micellization of Dimeric (Gemini) Surfactants and Conventional Surfactants", Journal of Colloid and Interface Science, 235, 119, (2001). https://doi.org/10.1006/jcis.2000.7311
  7. T. Zhou, H. Yang, X. Xu, X. Wang, J. Wang and G. Dong, "Synthesis, surface and aggregation properties of nonionic poly(ethylene oxide) gemini surfactants", Colloids and Surfaces A : Physicochemical and Eng. Aspects, 317, 339, (2008). https://doi.org/10.1016/j.colsurfa.2007.11.008
  8. Kimbel, Karen, L. "process for converting multifunctional aliphatic alcohols", Patent Cooperaction Tteaty, (2009).
  9. U. Komorek and K. A. Wilk, "Surface and micellar properties of new nonionic gemini aldonamide-type surfactants", Journal of Colloid and Interface Science, 271, 206, (2004). https://doi.org/10.1016/j.jcis.2003.09.020
  10. C. Qibin, L. Xiaodong, W. Shaolei, X. Shouhong, L. Honglai and H. Ying, "Cationic Gemini surfactnat at the air/water interface", Journal of Colloid and Interface Science, 314, 651, (2007). https://doi.org/10.1016/j.jcis.2007.05.063
  11. C. C. Lai and K. M. Chen, "Preparation and surface activity of polyoxylethylene-ca rboxylated modified Gemini surfactants", Colloids and Surfaces A : Physicochemical and Eng. Aspects, 320, 6, (2008). https://doi.org/10.1016/j.colsurfa.2007.12.056
  12. A. B. Pahi, Z. Kiraly and S. Puskas, "Mass spectrometric characterization of the non-ionic gemini surfactant Surfynol 465 and a microcalorimetric study of its micelle formation in water", Colloids and Surfaces A: Physicochemical and Eng. Aspects, 345, 13, (2009). https://doi.org/10.1016/j.colsurfa.2009.05.009
  13. T. A. Camesano and R. Nagarajan, "Micelle formation and CMC of gemini surfactants: A thermodynamic model", Colloids and Surfaces A: Physicochemical and Eng. Aspects, 167(1-2), 165, (2000). https://doi.org/10.1016/S0927-7757(99)00473-2
  14. R. C. Pasquali, M. P. Taurozzi and C. Bregni, "Consideratons about the Hydrophlic-Lipophlic Balance System", International Journal of Pharmacetics, 356, 44, (2008). https://doi.org/10.1016/j.ijpharm.2007.12.034
  15. H. L. Rosano, D. Jon and J. H. Whittam, "Free energy, enthalpy, and entropy changes during the formation of a n-hexadecane/potassium stearate/water/1- pentanol microemulsion system", J. of American Oil Chemist'Soc., 59, 360, (1982). https://doi.org/10.1007/BF02541020
  16. KSM ISO 696, Surface active agents - Measurement of foaming power - Modified Ross - Miles method, (2008).
  17. W. D. Bancroft, "The Theory of Emulsification, V", Journal of Physical Chemistry, 17, 501, (1913).
  18. S. R. Kim, "Science of detergent and washing", Kyo Mun Sa, 23, (1998).