Rapid Communication in Photoscience

Korean Society of Photoscience (한국광과학회)
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Electron-Beam Mediated Rearrangement and Fragmentation of Bis(diphenylphosphino)alkane Derivatives in Gas Phase

  • Jeon, Yea-Sel (Department of Bio & Chemical Engineering, Hongik University) ;
  • Choi, Jeong Chul (Department of Bio & Chemical Engineering, Hongik University) ;
  • Jeong, Young-Sik (Center for Medicinal Chemistry, Korea Research Institute of Chemical Technology) ;
  • Hwang, Kwang-Jin (Department of Bio & Chemical Engineering, Hongik University)
  • Received : 2013.03.31
  • Accepted : 2013.04.30
  • Published : 2013.03.01
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Abstract

The irradiation of electron-beam onto bis-(diphenylphosphino)methane, ethane, propane and butane initiated phenyl-shift from a phosphine to another phosphine atom and subsequent fragmentation resulted in the formation of triphenylphosphine derivative as key intermediate. The mechanism of those processes is speculated.

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References

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