Transactions on Electrical and Electronic Materials

  • 제14권3호
  • /
  • Pages.125-129
  • /
  • 2013
  • /
  • 1229-7607(pISSN)
  • /
  • 2092-7592(eISSN)
한국전기전자재료학회 (The Korean Institute of Electrical and Electronic Material Engineers)
권호 표지
DOI QR코드

DOI QR Code

Electrochemical Oxidations of Alcohols on Platinum/Carbon Nanotube Composites

  • Kim, Jungsoo (Dongnam Regional Division, Korea Institute of Industrial Technology) ;
  • Nam, Dae-Geun (Dongnam Regional Division, Korea Institute of Industrial Technology) ;
  • Oh, Weontae (Department of Materials & Components Engineering, Dong-Eui University)
  • 투고 : 2013.02.15
  • 심사 : 2013.03.02
  • 발행 : 2013.06.25
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Composites of platinum and multiwalled carbon nanotubes (MWNTs) were prepared in various reduction conditions and characterized using cyclic voltammetry. The MWNTs were functionalized with carboxylic acid and/or hydroxyl groups in acidic solutions prior to the formation of MWNT-Pt composites. Platinum nanoparticles were deposited onto the chemically-oxidized MWNTs in 1-propanol and 1,3-propanediol. The reduction of Pt precursors in other solutions could induce differences in their morphologies in composite thin films. The morphologies of MWNTs with Pt deposited were dependent on the reduction solutions, and the electrocatalytic activities on alcohols changed accordingly. The electrochemical activities of the as-prepared MWNT-Pt thin films on common alcohols such as methanol and ethanol were investigated.

키워드

참고문헌

  1. S. Mukerjee, S. Srinivasan, M. Soriaga, and P. McBreen, J. Electrochem. Soc. 142, 1409 (1995) [DOI: http://dx.doi.org/10.1149/1.2049993].
  2. S. Mukerjee, and S. Srinivasan, J. Electroanal. Chem. 357, 201 (1993) [DOI: http://dx.doi.org/10.1016/0022-0728(93)80380-Z].
  3. G. A. Capuano, and G. Thamizhmani, J. Electrochem. Soc. 141, 968 (1994) [DOI: http://dx.doi.org/10.1149/1.2054866].
  4. K. Y. Chan, J. Ding, J. W. Ren, S .A. Cheng, and K. Y. Tsang, J. Mater. Chem. 14, 505 (2008) [DOI: http://dx.doi.org/10.1039/B314224H].
  5. R. Parsons, and T. VandefNoot, J. Electroanal. Chem. 257, 9 (1988) [DOI: http://dx.doi.org/10.1016/0022-0728(88)87028-1].
  6. X. Xia, T. Iwasita, F. Fe, and W. Vielstich, Electrochim. Acta 41, 711 (1996) [DOI: http://dx.doi.org/10.1016/0013-4686(95)00360-6].
  7. Z. Liu, X.Y. Ling, X. Su, J.Y. Lee, and L.M. Gan, J. Power Sources 149, 1 (2005) [DOI: http://dx.doi.org/10.1016/j.jpowsour.2005.02.009].
  8. K. H. An, W. S. Kim, Y. S. Park, J. M. Moon, D. J. Bae, S. C. Lim, Y. S. Lee, and Y. H. Lee, Adv. Funct. Mater. 11, 387 (2001) [DOI: http://dx.doi.org/10.1002/1616-3028(200110)11:5<387::AIDADFM387>3.0.CO;2-G].
  9. L. M. Ang, T. S. A. Hor, G. Q. Xu, C. H. Tung, S. P. Zhao, and J. L. S. Wang, Carbon 38, 363 (2000) [DOI: http://dx.doi.org/10.1016/S0008-6223(99)00112-8].
  10. X. H. Chen, J. T. Xia, J. C. Peng, W. Z. Li, and S. S. Xie, Compos. Sci. Technol. 60, 301 (2000) [DOI: http://dx.doi.org/10.1016/S0266-3538(99)00127-X].
  11. F. Z. Kong, X. B. Zhang, W. Q. Xiong, E. Liu, W. Z. Huang, Y. L. Sun, J. P. Tu, and X. W. Chen, Surf. Coating Technol. 155, 33 (2002) [DOI: http://dx.doi.org/10.1016/S0257-8972(02)00032-4].
  12. B. Yoon, and C. M. Wai, J. Am. Chem. Soc. 127, 17174 (2005) [DOI: http://dx.doi.org/10.1021/ja055530f].
  13. X. Hu, T. Wang, X. Qu, and S. Dong, J. Phys. Chem. B 110, 853 (2006) [DOI: http://dx.doi.org/10.1021/jp055834o].
  14. G. G. Wildgoose, C. E. Banks, and R. G. Compton, Small 2, 182 (2006) [DOI: http://dx.doi.org/10.1002/smll.200500324].
  15. Z. He, J. Chen, D. Liu, H. Zhou, and Y. Kuang, Diamond Relat. Mater. 13, 1764 (2004) [DOI: http://dx.doi.org/10.1016/j.diamond.2004.03.004].
  16. G. Wu, Y. S. Chen, and B. Q. Xu, Electrochem. Commun. 7, 1237 (2005) [DOI: http://dx.doi.org/10.1016/j.elecom.2005.07.015].
  17. H. K. Kim, and R. Y. Lee, Kor. J. Mater. Res. 19, 192 (2009) [DOI:http://dx.doi.org/10.3740/MRSK.2009.19.4.192].
  18. C. A. Morris, M. L. Anderson, R. M. Stroud, C. I. Merzbacher, and D. R. Rolison, Science 284, 622 (1999) [DOI: http://dx.doi.org/10.1126/science.284.5414.622].
  19. Y. Y. Tong, C. Rice, A. Wieckowski, and E. Oldfield, J. Am. Chem. Soc. 122, 1123 (2000) [DOI: http://dx.doi.org/10.1021/ja9922274].
  20. P. Serp, M. Corrias, and P. Kalck, Appl. Catal. A: Gen. 253, 337 (2003) [DOI: http://dx.doi.org/10.1016/S0926-860X(03)00549-0].
  21. H. T. Gomes, P. V. Samant, P. Serp, P. Kalck, J. L. Figueiredo, and J. L. Faria, Appl. Catal. B: Environ. 54, 175 (2004) [DOI: http://dx.doi.org/10.1016/j.apcatb.2004.06.009].
  22. J. Garcia, H. T. Gomes, P. Serp, P. Kalck, J. L. Figueiredo, and J. L. Faria, Catal. Today 102-103, 101 (2005) [DOI: http://dx.doi.org/10.1016/j.cattod.2005.02.013].
  23. H. Vu, F. Goncalves, R. Philippe, E. Lamouroux, M. Corrias, Y. Kiln, D. Plee, P. Kalck, and P. Serp, J. Catal. 240, 18 (2006) [DOI:http://dx.doi.org/10.1016/j.jcat.2006.03.003].
  24. D. Menard, X. Py, and N. Mazet, Chem. Eng. Process. 46, 565 (2007) [DOI: http://dx.doi.org/10.1016/j.cep.2006.07.013].
  25. Z. Qi, M.C. Lefebvre, and P. G. Pickup, J. Electroanal. Chem. 459, 9 (1998) [DOI: http://dx.doi.org/10.1016/S0022-0728(98)00241-1].
  26. S. D. Tompson, L. R. Jordan, and M. Forsyth, Electrochim. Acta 46, 1657 (2001) [DOI: http://dx.doi.org/10.1016/S0013-4686(00)00767-2].
  27. Z. Liu, X. Lin, J. Y. Lee, W. Zhang, M. Han, and L. M. Gan, Langmuir 18, 4054 (2002) [DOI: http://dx.doi.org/10.1021/la0116903].
  28. C. Wang, M. Waje, X. Wang, J. M. Tang, R. C. Haddon, and Y. Yan, Nano Lett. 4, 345 (2004) [DOI: http://dx.doi.org/10.1021/nl034952p].
  29. M. Koo, J.-S. Bae, H.-C. Kim, D.-G. Nam, C. H. Ko, J.H. Yeum, and W. Oh, Bull. Mater. Sci. 35, 545 (2012) [DOI: http://dx.doi.org/10.1007/s12034-012-0335-1].
  30. V. Selvaraj, M. Vinoba, and M. Alagar, J. Colloid Interf. Sci. 322, 537 (2008) [DOI: http://dx.doi.org/10.1016/j.jcis.2008.02.069].
  31. G. -W. Lee, J. Kim, J. Yoon, J. -S. Bae, B. C. Shin, I.S. Kim, W. Oh, and M. Ree, Thin Solid Films 516, 5781 (2008) [DOI: http://dx.doi.org/10.1016/j.tsf.2007.10.071].
  32. Y.-P. Sun, K. Fu, Y. Lin, and W. Huang, Acc. Chem. Res. 35, 1096 (2002) [DOI: http://dx.doi.org/10.1021/ar010160v].
  33. S. Niyogi, M. A. Hamon, H. Hu, B. Zhao, P. Bhowmik, R. Sen, M. E. Itkis, and R. C. Haddon, Acc. Chem. Res. 35, 1105 (2002) [DOI:http://dx.doi.org/10.1021/ar010155r].
  34. A. Hirsch, Angew. Chem. Int. Ed. 41, 1853 (2002) [DOI: http://dx.doi.org/10.1002/1521-377(2002060341:11<1853::AIDANIE1853>3.0.CO;2-N].
  35. D. Tasis, N. Tagmatarchis, V. Georgakilas, and M. Prato, Chem. Eur. J. 9, 4000 (2003) [DOI: http://dx.doi.org/10.1002/chem.200304800].
  36. G. Gao, G. Yang, M. Xu, C. Wang, C. Xu, and H. Li, J. Power Sources 173, 178 (2007) [DOI: http://dx.doi.org/10.1016/j.jpowsour.2007.06.160]
  37. H. Hitmi, E. M. Belgsir, J. M. Leger, C. Lamy, and R. O. Lezna, Electrochim. Acta 39, 407 (1994) [DOI: 10.1016/0013-4686(94)80080-4].
  38. N. Fujiwara, K. A. Friedrich, and U. Stimming, J. Electroanal. Chem. 472, 120 (1999) [DOI: http://dx.doi.org/10.1016/S0022-0728(99)00282-X]
  39. M. Chatterjee, A. Chatterjee, S. Ghosh, and I. Basumallick, Electrochim. Acta 54, 7299 (2009) [DOI: http://dx.doi.org/10.1016/j.electacta.2009.07.054].

피인용 문헌

  1. High Aspect Ratio Carbon Nanotube Membranes Decorated with Pt Nanoparticle Urchins for Micro Underwater Vehicle Propulsion via H2O2 Decomposition vol.9, pp.8, 2015, https://doi.org/10.1021/acsnano.5b02124