한국세라믹학회지 (Journal of the Korean Ceramic Society)

  • 제50권3호
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  • Pages.195-200
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  • 2013
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  • 1229-7801(pISSN)
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  • 2234-0491(eISSN)
한국세라믹학회 (The Korean Ceramic Society)
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착체중합법을 이용한 (Ni,Mg)Al2O4 Cyan 나노 무기안료 합성

Synthesis of (Ni,Mg)Al2O4 Ceramic Nano Pigment by a Polymerized Complex Method

  • 손보람 (한국세라믹기술원 이천분원) ;
  • 윤대호 (성균관대학교 공과대학 신소재공학) ;
  • 한규성 (한국세라믹기술원 이천분원) ;
  • 조우석 (한국세라믹기술원 이천분원) ;
  • 황광택 (한국세라믹기술원 이천분원) ;
  • 김진호 (한국세라믹기술원 이천분원)
  • Son, Bo-Ram (Incheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET)) ;
  • Yoon, Dea-Ho (School of Advanced Materials Engineering, Sungkyunkwan University) ;
  • Han, Kyu-Sung (Incheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET)) ;
  • Cho, Woo-Suk (Incheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET)) ;
  • Hwang, Kwang-Taek (Incheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET)) ;
  • Kim, Jin-Ho (Incheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET))
  • 투고 : 2013.03.14
  • 심사 : 2013.04.24
  • 발행 : 2013.05.31
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초록

Here, we report preparation of cyan ceramic nano-pigment for inkjet printing and the Ni substitutional effects on the cyan color. $MgAl_2O_4$ was selected as the crystalline host network for the synthesis of nickel-based cyan ceramic nano-pigments. Various compositions of $Ni_xMg_{1-x}Al_2O_4$ ($0{\leq}x{\leq}1$) powders were prepared using the polymerized complex method. The powder was then preheated at $400^{\circ}C$ for 5 h and finally calcined at $1000^{\circ}C$ for 5 h. XRD patterns of $Ni_xMg_{1-x}Al_2O_4$ showed a single phase of the spinel structure in all the compositions. The particle sizes ranged from 20 to 50 nm in TEM observations. The characteristics of the color tones of $Ni_xMg_{1-x}Al_2O_4$ were analyzed by UV-Visible spectroscopy and CIE $L^*a^*b^*$ measurement. CIE $L^*a^*b^*$ measurement results indicate that the pigment color changes from light cyan to deep cyan due to the decrease of the $a^*$ and $b^*$ values with an increase of an Ni substitutional amount. In addition, the thermal stability and the binding nature of $Ni_xMg_{1-x}Al_2O_4$ are also discussed using TG-DSC and FT-IR results respectively.

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