Journal of the Korean Applied Science and Technology (한국응용과학기술학회지)

The Korean Society of Applied Science and Technology (한국응용과학기술학회)
권호 표지
DOI QR코드

DOI QR Code

Voltammetric Assay of Silver Ions in Frog's Tissue

  • Ly, Suw-Young (Biosensor Research Institute, Seoul National University of science & Technology) ;
  • Lee, Jin-Hui (Dept. of Chemical Engineering, Seoul National University of Science and Technology) ;
  • Lee, Chang-Hyun (Division of General Education, Pyeongtaek University)
  • Received : 2013.02.25
  • Accepted : 2013.03.22
  • Published : 2013.03.30
Download PDF
⟨ Previous Next ⟩

Abstract

The electrochemical analysis of silver ion was performed using cyclic voltammetry (CV) and square-wave (SW) stripping voltammetry, and electrode cell systems were fabricated with graphite pencil electrode (GE) of working, reference and counter electrodes. Also electrolyte was the use of sea water as electrolyte solutions instead of ionic controlled solutions. The optimum analytical conditions for the cyclic and stripping parameters were determined using GE. The results approached the microgram working ranges of SW(ug/L) and CV(ug/L) Ag, and the optimum conditions were applied to frog's tissue and the food samples.

Keywords

References

  1. A.M. Bond; P.J. Mahon; and J. Schiewe; Victoria Vicente-Beckett, An inexpensive and renewable pencil electrode for use in field-based stripping voltammetry. Anal. Chim. Acta. 345, 67-74 (1997). https://doi.org/10.1016/S0003-2670(97)00102-5
  2. W. Gao, J. Song; and N. Wu; Voltammetric behavior and square-wave voltammetric determination of trepibutone at a pencil graphite electrode. J. Electroanal. Chem. 576, 1-7 (2005). https://doi.org/10.1016/j.jelechem.2004.09.026
  3. D. Demetriades; A. Economou; and A. Voulgaropoulos; A study of pencil-lead bismuth-film electrodes for the determination of trace metals by anodic stripping voltammetry. Anal. Chim. Acta. 519, 167-172 (2004). https://doi.org/10.1016/j.aca.2004.05.008
  4. S. X. Guo; and S.B. Khoo; Highly Selective and Sensitive Determination of Silver(I) at a Poly(8-mercaptoquinoline) Film Modi(R)ed Glassy Carbon Electrode. Electroanal. 11(12), 891-898 (1999). https://doi.org/10.1002/(SICI)1521-4109(199908)11:12<891::AID-ELAN891>3.0.CO;2-9
  5. J.J.Meeuse; A.K.L.Reyners; and A.N.M. Wymenga; Topical Lidocaine in SilverSulfadiazine Cream on Painful,Cancer, or Treatment-Related Skin Lesions. J. Pain. Symptom. Manag. 34(3), 223-225 (2007). https://doi.org/10.1016/j.jpainsymman.2007.05.002
  6. B. Thati, A. Noble; B.S. Creaven; M. Walsh; M. McCann; K. Kavanagh; M. Devereux; and D.A.Egan; In vitro anti-tumour and cyto-selective effects of coumarin-3-carboxylic acid and three of its hydroxylated derivatives, along with their silver-based complexes, using human epithelial carcinoma cell lines. Cancer. Lett. 248, 321-331 (2007). https://doi.org/10.1016/j.canlet.2006.08.009
  7. S. Iwasaki; A. Yoshimura; T. Ideura; S. Koshikawa; and M.sudo; Elimination study of silver in a hemodialyzed burn patient treated with silver sulfadiazine cream. Am. J. Kidney. Dis. 30(2), 298-290 (1997).
  8. A.J.Dole; T.J. Cardwell; R.W. Cattrall; R.D.Giacomo; C.G. Rodrigues; and G.R.Scollary; The Determination of Silver in Photographic Emulsions by Discontinuous Flow Analysis. Electroanal. 10, 21-25 (1998). https://doi.org/10.1002/(SICI)1521-4109(199801)10:1<21::AID-ELAN21>3.0.CO;2-9
  9. J.SSramkova; S. Kotrly; and P. Jakoubkova; Precision attainable in the determination of silver by flame atomic absorption spectrometry Analysis of thermoelectric silver-doped tellurides. Anal. Chim. Acta. 408, 183-190 (2000). https://doi.org/10.1016/S0003-2670(99)00810-7
  10. A.T. Haj-Hussein; Indirect ultraviolet determination of silver with nickelocyanide ion by flow injection analysis. Talanta. 42, 2053-2057 (1995). https://doi.org/10.1016/0039-9140(95)01697-X
  11. H. Ibrahim; Carbon paste electrode modified with silver thimerosal for the potentiometric flow injection analysis of silver(I). Anal. Chim. Acta. 545, 158-165 (2005). https://doi.org/10.1016/j.aca.2005.04.083
  12. E. Masetti; J.Bulir; S. Gagliardia; V. Janicki; A. Krasilnikova; G.D. Santo; and C. Coluzza; Ellipsometric and XPS analysis of the interface between silver and $SiO_{2}$, $TiO_{2}$and SiNx thin films. Thin. Solid. Films. 468-472 . (2004).
  13. S. Bera; P. Gangopadhyay; K.G.M. Nair; B.K. Panigrahib; and S.V. Narasimhan; Electron spectroscopic analysis of silver nanoparticles in a soda-glass matrix. J. Electron Spectrosc. 152, 91-95 (2006). https://doi.org/10.1016/j.elspec.2006.03.008
  14. H. Itabashi; M. Takahata; H. Kawamoto; and H. Akaiwa; Catalytic determination of silver(I) by extractive flow injection analysis. Talanta. 45, 549-555 (1998). https://doi.org/10.1016/S0039-9140(97)00130-6
  15. M.F. SuaArez; A. Mills; R.G. Egdell; and R.G. Compton; Anodic Stripping Voltammetry with Photochemical Preconcentration at Nanocrystalline $TiO_{2}$Films: Detection of Ag. and Hg2. Electroanal. 12, 413-419 (2000). https://doi.org/10.1002/(SICI)1521-4109(20000401)12:6<413::AID-ELAN413>3.0.CO;2-I
  16. K.H. Lubert; L.Beyer; J. Casabo; and C. Perez-Jimenez; Voltammetric Behavior of Silver Ions at a Carbon Paste Electrode in the Presence of 2,5,8-Trithia[9]-mcyclophane. Electroanal. 10, 860-862 (1998). https://doi.org/10.1002/(SICI)1521-4109(199809)10:12<860::AID-ELAN860>3.0.CO;2-S
  17. A.J. Saterlay; F. Marken; J.S. Foord; and R.G. Compton; Sonoelectrochemical investigation of silver analysis at a highly boron-doped diamond electrode. Talanta. 53, 403-415 (2000). https://doi.org/10.1016/S0039-9140(00)00505-1
  18. G. Cepria; O. Abadias. J; Perez- Arantegui, and J.R. Castillo; Electrochmical Behavoir of silver-copper Alloys in Voltammetry of Microparticles: A simple Method for screening purposes. Electroanal. 13(6), 477-483 (2001). https://doi.org/10.1002/1521-4109(200104)13:6<477::AID-ELAN477>3.0.CO;2-E