Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Preparation and Characterization of Palladium Nanoparticles Supported on Nickel Hexacyanoferrate for Fuel Cell Application

  • Choi, Kwang-Hyun (School of Chemical and Biological Engineering, World Class University Program of Chemical Convergence for Energy and Environment, Seoul National University) ;
  • Shokouhimehr, Mohammadreza (School of Chemical and Biological Engineering, World Class University Program of Chemical Convergence for Energy and Environment, Seoul National University) ;
  • Kang, Yun Sik (School of Chemical and Biological Engineering, World Class University Program of Chemical Convergence for Energy and Environment, Seoul National University) ;
  • Chung, Dong Young (School of Chemical and Biological Engineering, World Class University Program of Chemical Convergence for Energy and Environment, Seoul National University) ;
  • Chung, Young-Hoon (School of Chemical and Biological Engineering, World Class University Program of Chemical Convergence for Energy and Environment, Seoul National University) ;
  • Ahn, Minjeh (School of Chemical and Biological Engineering, World Class University Program of Chemical Convergence for Energy and Environment, Seoul National University) ;
  • Sung, Yung-Eun (School of Chemical and Biological Engineering, World Class University Program of Chemical Convergence for Energy and Environment, Seoul National University)
  • Received : 2012.11.07
  • Accepted : 2013.01.26
  • Published : 2013.04.20
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Abstract

Nickel hexacyanoferrate supported palladium nanoparticles (Pd-NiHCF NPs) were synthesized and studied for oxygen reduction reactions in direct methanol fuel cell. The NiHCF support was readily synthesized by a comixing of $Ni(OCOCH_3)_2$ and equimolar $K_3[Fe(CN)_6]$ solution into DI water under rigorous stirring. After the preparation of NiHCF support, Pd NPs were loaded on NiHCF via L-ascorbic acid reduction method at $80^{\circ}C$. Pd-NiHCF NPs were electrochemically active for oxygen reduction reaction in 0.1 M $HClO_4$ solution. X-ray absorption near edge structure analysis was conducted to measure the white line intensity of Pd-NiHCF to verify the OH adsorption. As a comparison, carbon supported Pd NPs exhibited same white line intensity. This study provides a general synthetic approach to easily load Pd NPs on porous coordination polymers such as NiHCF and can provide further light to load Pd based alloy NPs on NiHCF framework.

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