Journal of Korea Technical Association of The Pulp and Paper Industry (펄프종이기술)

Korea Technical Association of the Pulp and Paper Industry (한국펄프종이공학회)
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Conversion of Fructose to 5-HMF(5-hydroxymethylfurfural) in DMSO(dimethylsulfoxide) solvent

DMSO(dimethylsulfoxide) 용매에서 과당의 5-HMF(5-hydroxymethylfurfural) 전환

  • Sung, Yong Joo (Dept. of Biobased Materials, College of Agriculture and Life Science, Chungnam Nat'l Univ.) ;
  • Park, Chong-Jin (Samyang Genex Corp. Samyang Group Food R&D Center) ;
  • Kim, Byung-Ro (Department of Wood and Paper Science, Chungbuk National University) ;
  • Shin, Soo-Jeong (Department of Wood and Paper Science, Chungbuk National University)
  • 성용주 (충남대학교 농업생명과학대학 환경소재공학과) ;
  • 박종진 ((주) 삼양제넥스 식품연구소 소재개발프로그램) ;
  • 김병로 (충북대학교 목재종이과학과) ;
  • 신수정 (충북대학교 목재종이과학과)
  • Received : 2013.02.20
  • Accepted : 2013.03.20
  • Published : 2013.04.30
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Abstract

Conversion of fructose to 5-hydroxymethylfurfural (5-HMF) was investigated in dimethylsulfoxide (DMSO) solvent with increasing reaction temperatures and impact of residual water from dehydration reaction byproduct. To convert fructose to 5-HMF, increasing reaction temperature led more conversion to 5-HMF than lower temperature at the range of $120-150^{\circ}C$ in DMSO solvent. DMSO engaged in the acid-catalyzed dehydration and rearrangement reaction as acid and solvent. Increasing temperature led to more furanose structure than pyranose at the range of $30-80^{\circ}C$. Formed 5-HMF could be degraded to levulinic and formic acid at the presence of acid and water. Removal of water in reaction medium could prevent 5-HMF degradation.

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References

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