Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
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Selective Metal Ion Sensing of Bipyridine-Bisterpyridine containing Fluorescent Dyes

다중 피리딘 구조를 가지는 형광염료의 금속 이온 반응성에 대한 연구

  • Zo, Hye Jin (Department of Organic Material and Polymer Engineering, Dong-A University) ;
  • Kim, Arong (Department of Organic Material and Polymer Engineering, Dong-A University) ;
  • Jeong, Sooyeon (Nano Carbon Materials Research Center, Korea Electrotechnology Research Institute(KERI)) ;
  • Park, Jong S. (Department of Organic Material and Polymer Engineering, Dong-A University)
  • 조혜진 (동아대학교 유기재료고분자공학과) ;
  • 김아롱 (동아대학교 유기재료고분자공학과) ;
  • 정수연 (한국전기연구원 나노카본소재연구센터) ;
  • 박종승 (동아대학교 유기재료고분자공학과)
  • Received : 2013.11.04
  • Accepted : 2013.12.09
  • Published : 2013.12.27
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Abstract

In this study, we synthesized a new fluorescent polypyridyl dye 2 containing a 2,2'-bipyridine in the center and two 2,2':6',2"-terpyridines at both ends. When exposed to various metal ions, the dye 2 showed selective fluorescence responses. In the presence of $Cu^{2+}$ and $Ni^{2+}$, it exhibited a highly effective fluorescence quenching, leading to large $K_{sv}$ values of up to $10^5$. In response to most other metal ions including $Al^{3+}$, in contrast, its fluorescence changes little, showing a small Ksv value at $10^2$. Meanwhile, the compound 2 revealed a differentiated fluorescence response to $Zn^{2+}$, which is evidenced by a large red shift of > 100 nm. Such a red shift from the ion binding is attributed to the planarization of the bipyridyl unit extending the effective conjugation length in conjunction. A polypyridyl compound will find important usefulness in chemosensor application due to its selective binding to metal ions. Subsequent research concerned with modified derivatives is currently going on, as a way to provide high solubility even after metal-complexing.

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References

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