DOI QR코드

DOI QR Code

Studies on the Aging Characteristics in Different Parts of Beeswax-treated Duplicates during Humidified Artificial Aging

습식 인공열화 시 밀랍본 복제품의 제책 부위별 열화특성

  • Choi, Kyoung-Hwa (Research Division of Restoration Technology, National Research Institute of Cultural Heritage) ;
  • Cho, Jung Hye (Research Division of Restoration Technology, National Research Institute of Cultural Heritage) ;
  • Kang, Yeong Seok (Research Division of Restoration Technology, National Research Institute of Cultural Heritage) ;
  • Yang, Eun Jung (Research Division of Restoration Technology, National Research Institute of Cultural Heritage) ;
  • Jeong, Hye Young (Research Division of Restoration Technology, National Research Institute of Cultural Heritage)
  • 최경화 (국립문화재연구소 복원기술연구실) ;
  • 조정혜 (국립문화재연구소 복원기술연구실) ;
  • 강영석 (국립문화재연구소 복원기술연구실) ;
  • 양은정 (국립문화재연구소 복원기술연구실) ;
  • 정혜영 (국립문화재연구소 복원기술연구실)
  • Received : 2012.10.08
  • Accepted : 2012.10.20
  • Published : 2012.10.30

Abstract

In this study, to understand the aging factor and mechanism in different partitions of the beeswax-treated volumes, the duplicated beeswax-treated volume was artificially aged at $80^{\circ}C$ of temperature and 65% of relative humidity and then a physical and optical properties of an aged volumes was analyzed. Also, the degraded components of the beeswax samples isolated from different partitions of aged volumes was measured using a gas chromatography/mass spectroscopy (GC/MS). In results, the surface of beeswax-treated volume which is primarily affected by a main aging factors such as light, oxygen, moisture was more deteriorated than the inside of that volume. However, unlike inside of the book volume which was made from paper, the inside of beeswax-treated volume wax was also considerably deteriorated. The inside of the beeswax-treated volume is largely unaffected by the oxygen and humidity during aging due to the water repellency and the air permeation resistance of beeswax. Therefore, it is confirmed that aging factors and mechanisms in the inside of the volume are different from thats of the outside of the volume. This fact was also verified by the results of GC/MS analysis of an beeswax samples which was sampled from different partitions of aged volumes. As result as GC/MS analysis of the beeswax extracted from the outside of the aged volume, the low molecular compounds with a carbon length of $C_9-C_{20}$ (fatty acid, etc) were increased and the compounds with a carbon length of above $C_{34}$ (ester, etc) were also increased. But the compounds with a chain length of $C_{21}-C_{36}$ (hydrocarbon, alcohol, etc) were decreased. In case of the aged beeswax of inside, the low molecular compounds with a carbon length of $C_9-C_{20}$ (fatty acid, etc) and the compounds with a chain length of $C_{21}-C_{36}$ (hydrocarbon, alcohol, etc) were increased. While, the compounds with a carbon length of above $C_{34}$ (ester, etc) were decreased.

Keywords

References

  1. 송기중, 신병주, 박지선, 이인성, 조선왕조실록 보존을 위한 기초조사연구 (1): 13, 서울대학교출판부, 서울 (2005).
  2. 정소영, 이혜윤, 정용재, 홍정기, 엄두성, 조선왕조실록 밀납본의 보존상태 조사, 보존과학연구 25: 119-132 (2004).
  3. 국립문화재연구소, 조선왕조실록 밀랍본 복원기술 연구 결과보고서 (2006).
  4. 국립문화재연구소, 조선왕조실록 밀랍본 복원기술 연구 결과보고서 (2007).
  5. A. P. Tulloch, Beeswax: Structure of the esters and their component hydroxy acids and diols, Chemistry and Physics of. Lipids 6: 235-265 (1971). https://doi.org/10.1016/0009-3084(71)90063-6
  6. I. Bonaduce, M. P. Colombini, Characterisation of beeswax in works of art by gas chromatography mass spectrometry and pyrolysis gas chromatography mass spectrometry procedures, Journal of Charomatogrphy A 1028(2): 297-306 (2004). https://doi.org/10.1016/j.chroma.2003.11.086

Cited by

  1. 열화 밀랍지의 탈랍 및 강도보강 처리 안정성 평가 vol.45, pp.6, 2012, https://doi.org/10.7584/ktappi.2013.45.6.010
  2. 열화율이 상이한 밀랍지의 초임계유체추출 탈랍처리효과 비교분석 vol.46, pp.6, 2012, https://doi.org/10.7584/ktappi.2014.46.6.056