한국염색가공학회지 (Textile Coloration and Finishing)

  • 제24권3호
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  • Pages.158-164
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  • 2012
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  • 1229-0033(pISSN)
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  • 2234-036X(eISSN)
한국염색가공학회 (The Korean Society of Dyers and Finishers)
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Rhodamine 6G Based New Fluorophore Chemosensor Toward Hg2+

  • Son, Young-A (Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University) ;
  • Park, June-Min (Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University)
  • 투고 : 2012.08.23
  • 심사 : 2012.09.22
  • 발행 : 2012.09.27
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초록

Rhodamine dyes belong to xanthene family has excellent photostability and photophysical properties. In rhodamine dyes, Rhodamine 6G and its precursors also have xanthene chromophore and it shows high fluorescent quantum yield. Rhodamine 6G derivates are simple to synthesis and its high sensitivity and water solubility are suitable as good chemosensor. In this regard, Rhodamine 6G derivates which have selectivity to specific metal cation can used to detect various heavy metal ions. In this study, rhodamine 6G derivatives were synthesized by reaction of rhodamine 6G hydrazide and glyoxal and 4-phenyl thiosemicarbazide and it showed colorimetric and fluorescence sensing toward $Hg^{2+}$ ion. This novel chemosensor was analyzed and measured on UV-Vis and fluorescence spectrophotometer. HOMO/LUMO values were also calculated by computational calculation.

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  2. “Turn-on” fluorescent and colorimetric determination of Cu2+ ions in aqueous media based on a Rhodamine-N-phenyl Semicarbazide derivative vol.16, pp.5, 2015, https://doi.org/10.1007/s12221-015-0953-5
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  6. Detection of Zinc(II) by a Fluorescence Chemosensor Based on Benzofuran in Aqueous Media and Live Cells pp.12295949, 2018, https://doi.org/10.1002/bkcs.11608