An Accelerated Degradation Test of Electric Double-Layer Capacitors

전기이중층커패시터의 가속열화시험

  • Jung, Jae-Han (Reliability Technology Center, Korea Testing Laboratory) ;
  • Kim, Myung-Soo (Dept. of Industrial Information Engineering, The Univ. of Suwon)
  • 정재한 (한국산업기술시험원 신뢰성기술센터) ;
  • 김명수 (수원대학교 산업정보공학과)
  • Received : 2012.04.18
  • Accepted : 2012.06.01
  • Published : 2012.06.25

Abstract

An electric double-layer capacitor(EDLC) is an electrochemical capacitor with relatively high energy density, typically hundreds of times greater than conventional electrolytic capacitors. EDLCs are widely used for energy storage rather than as general-purpose circuit components. They have a variety of commercial applications, notably in energy smoothing and momentary-load devices, and energy-storage and kinetic energy recovery system devices used in vehicles, etc. This paper presents an accelerated degradation test of an EDLC with rated voltage 2.7V, capacitance 100F, and usage temperature $-40^{\circ}C{\sim}65^{\circ}C$. The EDLCs are tested at $50^{\circ}C$, $60^{\circ}C$, and $70^{\circ}C$, respectively for 1,750hours, and their capacitances are measured at predetermined times by constant current discharge method. The failure times are predicted from their capacitance deterioration patterns, where the failure is defined as 30% capacitance decrease from the initial one. It is assumed that the lifetime distribution of EDLC follows Weibull and Arrhenius life-stress relationship holds. The life-stress relationship, acceleration factor, and $B_{10}$ life at design condition are estimated by analyzing the accelerated life test data.

Keywords

References

  1. 수원대학교 신뢰성혁신센터(2004), 가속수명시험 Guideline-1부: 가속수명시험의 개요.
  2. 수원대학교 신뢰성혁신센터(2004), 가속수명시험 Guideline-3부: 가속수명시험 데이터분석.
  3. 윤중락, 이경민(2011), "스마트 그리드 시스템에서 전력안정화 및 에너지저장용으로 적용되는 초고용량 커패시터 기술 동향", 전기전자재료 제24권 제3호, 45-51.
  4. 전자부품연구원(2003), 초고용량 커패시터.
  5. 한국과학기술정보연구원(2007), 슈퍼커패시터.
  6. Hwang, D.H, Park, J.W., Jung, J.H.(2011), "A Study on the Lifetime Comparison for Electric Double Layer Capacitors using Accelerated Degradation Test," International Conference on Quality, Reliability, Risk, Maintenance, and Safety Engineering (ICQR2MSE), 302-307.
  7. IEC 60068-2-2(1993), Basic environmental testing procedures Part 2: Tests, Tests B: Dry heat.
  8. Kobayashi, Y.(1992), "Acceleration coefficient of the molded electric double layer capacitor," Proceedings of 42nd Electronic Components and Technology Conference, 617-623.
  9. Kotz, R., Ruch, P.W., and Cericola, D.(2010), "Aging and failure mode of electrochemical double layer capacitors during accelerated constant load tests," Journal of Power Sources, Volume 195, Issue 3, 923-928. https://doi.org/10.1016/j.jpowsour.2009.08.045
  10. RS-KTL-2010-0007(2010, 전기이중층커패시터, 기술표준원.
  11. Umemura, T., Mizutani, Y., Okamoto, T., Taguchi, T., Nakajima, K., and Tanaka, K.T.(2003), "Life Expectancy and Degradation behavior of Electric double layer Capacitor Part I," Proceedings of the 7th International Conference on Properties and Applications of Dielectric Materials, 944-948.
  12. 矢田 静邦(2006), 리튬이온전지, 커패시터의 실천평가기술, 기술정보협회.
  13. 高向 芳典, 井澤 武紀, 渡邊 郁(2003), "전기 이중층커패시터의 개발동향", 월간전기기술, 54-57.