DOI QR코드

DOI QR Code

Biomass-burning에서 배출되는 미세입자 (PM2.5)의 배출원 구성물질 성분비 개발에 관한 연구

A Study on the Source Profile Development for Fine Particles (PM2.5) Emitted from Biomass Burning

  • 강병욱 (한국교통대학교 환경공학과) ;
  • 이학성 (서원대학교 환경건설정보학과)
  • Kang, Byung-Wook (Department of Environmental Engineering, Korea National University of Transportation) ;
  • Lee, Hak-Sung (Department of Environmental, Civil and Information System, Seowon University)
  • 투고 : 2012.03.07
  • 심사 : 2012.06.07
  • 발행 : 2012.08.31

초록

This study was performed to develop the source profiles for fine particles ($PM_{2.5}$) emitted from the biomass burning. The multi-method research strategy included a usage of combustion devices such as field burning, fireplace, and residential wood burning to burn rice straw, fallen leaves, pine tree, and oak tree. The data were collected from multiple sources and measured water-soluble ions, elements, elemental carbon (EC), and organic carbon (OC). From this study, it turned out that OC (34~67%) and EC (1.2~39%) are the major components emitted from biomass burning. In the case of burning rice straw at field burning, OC (66.6%) was the most abundant species, followed by EC (4.3%), $Cl^-$ (3.6%), Cl (2.1%), and $SO^{2-}_4$(1.9%). Burning rice straw, fallen leaves, pine tree, and oak tree at fireplace, the amount of OC was 58.5%, 52.7%, 52.5%, and 61.2%, and that of EC was 1.2%, 18.4%, 36.5%, and 2.7%, respectively. The ratio of OC for the burning of pine tree and oak tree from the residential wood burning device was 56.9% and 34.3%, and that of EC was 25% and 38.6%, respectively. Applying the measured data with respect to the proportion of components emitted from biomass burning to reference model, it turned out that self-diagnosed result was appropriate level, and the result based on the model is in highly corresponding to actual timing of biomass burning.

키워드

참고문헌

  1. Abas, M.R.B., D.R. Oros, and B.R.T. Simoneit (2004) Biomass burning as the main source of organic aerosol particulate matter in Malaysia during haze episodes, Chemosphere, 55(8), 1089-1095. https://doi.org/10.1016/j.chemosphere.2004.02.002
  2. Allen, A.G. and A.H. Miguel (1995) Biomass burning in theamazon- characterization of the ionic component of aerosols generated from flaming and smoldering rain-forest and savanna, Environ. Sci. Technol., 29(2), 486-493. https://doi.org/10.1021/es00002a026
  3. Cahoon, D.R., B.J. Stock, J.S. Levine, W.R. Cofer III, and C.C. Chung (1992) Evaluation of a technique for satellite-derived estimation of biomass burning, J. of Geophysical Research, 97(D4), 3805-3814. https://doi.org/10.1029/91JD03080
  4. Chow, J.C. (1995) Measurement methods to determine compliance with ambient air quality standards for suspended particles, J. Air & Waste Manage. Assoc., 45, 320-382. https://doi.org/10.1080/10473289.1995.10467369
  5. Chowdhury, Z., M. Zheng, J.J. Schauer, R.J. Sheesley, L.G. Salmon, G.R. Cass, and A.G. Russell (2007) Speciation of ambient fire organic carbon particles and source apportionment of PM2.5 in Indian cities, J. Geophys. Res., 112, D15303, doi:10.1029/2007JD008386.
  6. Dennis, A., M. Fraser, S. Anderson, and D. Allen (2002) Air pollutant emissions associated with forest, grassland, and agricultural burning in Texas, Atmos. Environ., 36(23), 3779-3792. https://doi.org/10.1016/S1352-2310(02)00219-4
  7. Dibb, J.E., R.W. Talbot, S.I. Whitlow, M.C. Shipham, J. Winterle, J. McConnell, and R. Bales (1996) Biomass burning signatures in the atmosphere and snow at Summit, Greenland: An event on 5 August 1994, Atmos. Environ., 30(4), 553-561. https://doi.org/10.1016/1352-2310(95)00328-2
  8. Fine, P.M., G.R. Cass, and B.R.T. Simoneit (2001) Chemical characterization of fine particle emissions from fireplace combustion of woods grown in the Northeastern United States, Environ. Sci. Technol., 35, 2665-2675. https://doi.org/10.1021/es001466k
  9. Fine, P.M., G.R. Cass, and B.R.T. Simoneit (2004) Chemical characterization of fine particle emissions from the wood stove combustion of prevalent United States tree species, Environ. Eng. Sci., 21(6), 705-724. https://doi.org/10.1089/ees.2004.21.705
  10. Formenti, P., W. Elbert, W. Maenhaut, J. Haywood, S. Osborne, and M.O. Andreae (2003) Inorganic and carbonaceous aerosols during the Southern African Regional Science Initiative (SAFARI 2000) experiment: Chemical characteristics, physical properties, and emission data for smoke from African biomass burning, J. Geophys. Res-Atmos., SAF24, 1-16.
  11. Gill, M. and P.H.R. Moore (2005) Fire situation in Australia, March 2005, http://www.fao.org/docrep.
  12. Gustafsson, O., M. Krusa, Z. Zencak, R.J. Sheesley, L. Granat, E. Engstrom, P.S. Praveen, P.S.P. Rao, C. Leck, and H. Rodhe (2009) Brown clouds over south Asia: biomass or fossil fuel combustion?, Science, 323, 495-498. https://doi.org/10.1126/science.1164857
  13. Hedberg, E., A. Kristensson, M. Ohlsson, C. Johansson, P.-A. Johansson, E. Swietlicki, V. Vesely, U. Wideqvist, and R. Westerholm (2002) Chemical and physical characterization of emissions from birch wood combustion in a wood syove, Atmos. Environ., 36, 4823-4837. https://doi.org/10.1016/S1352-2310(02)00417-X
  14. Hegg, D.A., S.G. Warren, T.C. Grenfell, S.J. Doherty, and A.D. Clarke (2010) Sources of light-absorbing aerosol in arctic snow and their seasonal variation, Atmos. Chem. Phys., 10, 10923-10938. https://doi.org/10.5194/acp-10-10923-2010
  15. Hu, Y., M.T. Odman, M.E. Chang, W. Jackson, S. Lee, E.S. Edgerton, K. Baumann, and A.G. Russell (2008) Simulation of air quality impacts from prescribed fires on an urban area, Environ. Sci. Technol., 42, 3676-3682. https://doi.org/10.1021/es071703k
  16. Huang, X., I. Olmez, N.K. Aras, and G.E. Gorden (1994) Emissions of trace elements from motor vehicles: potential marker elements and source composition profile, Atmos. Environ., 28(8), 1385-1391. https://doi.org/10.1016/1352-2310(94)90201-1
  17. Kang, B.-W., H.S. Lee, and H.-K. Kim (2000) Source identification of fine particle ($PM_{2.5}$) in Chongju using a chemical mass balance model, J. KOSAE, 16(5), 477-485. (in Korean with English abstract)
  18. Kang, C.-M., B.-W. Kang, and H. S. Lee (2006) Source identification and trends in concentrations of gaseous and fine particulate principal species in Seoul, South Korea, J. Air & Waste Manage. Assoc., 56, 911-921. https://doi.org/10.1080/10473289.2006.10464506
  19. Lee, H.S., C.-M. Kang, B.-W. Kang, and S.-K. Lee (2005) A study on the $PM_{2.5}$ source characteristics affecting the Seoul area using a chemical mass balance receptor model, J. KOSAE, 21(3), 329-341. (in Korean with English abstract)
  20. Nichol, J. (1997) Bioclimatic impacts of the 1994 smoke haze event in southeast Asia, Atmos. Environ., 31(8), 1209-1219. https://doi.org/10.1016/S1352-2310(96)00260-9
  21. Park, S.S. (2001) A combined methodology for estimating atmospheric aerosol sources using PM2.5 particles and PAH compounds, Doctoral dissertation, Kwangju Institute of Science and Technology, 115.
  22. Ramanathan, V., M.V. Ramana, G. Roberts, D. Kim, C. Corrigan, C. Chung, and D. Winker (2007) Warming trends in Asia amplified by brown cloud solar absorption, Nature, 448, 575-578. https://doi.org/10.1038/nature06019
  23. Schauer, J.J., M.P. Fraser, G.R. Cass, and B.R.T. Simoneit (2002) Source reconciliation of atmospheric gasphase and particle-phase pollutants during a severe photochemical smog episode, Environ. Sci. Technol., 36, 3806-3814. https://doi.org/10.1021/es011458j
  24. Schmidl, C., I.L. Marr, A. Caseiro, P. Kotianova, A. Berner, H. Bauer, A. Kasper-Giebl, and H. Puxbaum (2008) Chemical characterisation of fine particle emissions from wood stove combustion of common woods growing in mid-European alpine regions, Atmos. Environ., 42, 126-141. https://doi.org/10.1016/j.atmosenv.2007.09.028
  25. Sheesley, R.J., J.J. Schauer, M. Zheng, and B. Wang (2007) Sensitivity of molecular marker-based CMB models to biomass burning source profiles, Atmos. Environ., 41, 9050-9063. https://doi.org/10.1016/j.atmosenv.2007.08.011
  26. Sheesley, R.J., J.J. Schauer, Z. Chowdhury, G.R. Cass, and B.R.T. Simoneit (2003) Characterization of organic aerosols emitted from the combustion of biomass indigenous to South Asia, J. Geophys. Res. 108(D9), 4285, doi:10.1029/2002JD002981.
  27. Streets, D.G., K.F. Yarber, J.-H. Woo, and G.R. Carmichael (2003) Biomass burning in Asia: Annual and seasonal estimates and atmospheric emissions, Global Biogeochemical Cycles, 17(4), 1099, doi:10.1029/2003GB002040.
  28. Stone, E.A., D.C. Snyder, R.J. Sheesley, A.P. Sullivan, R.J. Weber, and J.J. Schauer (2008) Source apportionment of fineorganic aerosol in Mexico city during the MILARGO experiment 2006, Atmos. Chem. Phys. 8, 1249-1259. https://doi.org/10.5194/acp-8-1249-2008
  29. Stone, E.A., J.J. Schauer, B.B. Pradhan, P.M. Dangol, G. Habib, C. Venkataraman, and V. Ramanathan (2010) Characterization of emissions from south Asian biofuels and application to source apportionment of carbonaceous aerosol in the Himalayas, J. of Geophysical Research, 115, doi:10.1029/2009JD011881.
  30. Swap, R., M. Garstang, S.A. Macko, P.D. Tyson, W. Maenhaut, P. Artaxo, P. Kallberg, and R. Talbot (1996) The long-range transport of southern African aerosols the tropical South Atlantic, J. Geophys. Res-Atmos., 101(D19), 23777-23791. https://doi.org/10.1029/95JD01049
  31. Uherek, E. (2004) (Vegetation fire), Max Planck Institute for chemistry, Mainz, Accessed Mei 2004, http://www.atmosphere.mpg.de/enid/238.html.
  32. U.S. EPA (2006) SPECIATE 4.0 speciation database development documentation.
  33. WHO (2000) Vegetation fires, http://www.who.int/mediacentre/factsheets/fs254/en/print.html.
  34. Yamaseo, M.A., P. Artaxo, A.H. Miguel, and A.G. Allen (2000) Chemical composition of aerosol particles from direct emissions of vegetation fires in the Amazon basin: water-soluble species and trace elements, Atmos. Environ., 34(10), 1641-1653. https://doi.org/10.1016/S1352-2310(99)00329-5

피인용 문헌

  1. The Characterization of Incomplete Combustion Products in Open Burning vol.30, pp.1, 2014, https://doi.org/10.5572/KOSAE.2014.30.1.048
  2. Streamflow Modeling in Data-scarce Estuary Reservoir Watershed Using HSPF vol.56, pp.6, 2014, https://doi.org/10.5389/KSAE.2014.56.6.129