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Surface Properties of the Dried Coacervate Film Affect Dry Feel of the Shampoo Composed of Cationic Polymer and Anionic/Amphoteric Surfactant

양이온 폴리머와 음이온/양쪽성 계면활성제로 형성된 코아세르베이트 건조 필름 특성이 샴푸 건조 후 사용감에 미치는 영향

  • Received : 2012.03.14
  • Accepted : 2012.06.16
  • Published : 2012.06.30

Abstract

The purpose of this study was to examine the correlation between physical properties of dried coacervate films and dry feel for shampoo composition. Simple shampoo compositions were made of two different cationic charge density polymers in the same surfactant compositions. The simple shampoo compositions were diluted with distilled water to make coacervate. Formed coacervate was collected by centrifuge (3,000 rpm, 30 min). Coacervate was coated on the glass plates and dried in drying oven (for 1 h, $50^{\circ}C$) to make the thin film. We carried out an experiment on measurement of contact angle, moisture loss ratio and SEM image analysis of the dried coacervate film. Dry feelings of the shampoos were evaluated by panel using hair tresses. Results show that the properties of dried coacervate films affect the dry feel of the after shampooing.

본 연구는 건조된 코아세르베이트 필름의 물리적 특성이 샴푸 건조 후 모발 사용감에 미치는 상관관계를 조사하기 위하여 실시하였다. 단순 샴푸 조성물은 동일한 조성의 계면활성제에 양이온 전하 밀도가 서로 다른 두 종류의 양이온 폴리머를 사용하여 제조하였다. 이 단순 조성물을 물에 희석하여 코아세르베이트(Coacervate)를 형성되도록 하였고, 3000 rpm, 30 min 조건으로 원심 분리하여 형성된 코아세르베이트를 얻었다. 얻어진 코아세르베이트를 유리판 위에 균일한 두께로 도포하고 $50^{\circ}C$ 건조기에서 1 h 건조하여 코아세르베이트 필름을 얻었다. 이렇게 얻어진 코아세르베이트 필름의 접촉각과 코아세르베이트의 SEM 이미지 조사를 수행하였고, 코아세르베이트의 수분 보유량과 수분 유지력을 동시에 조사하였다. 샴푸 후 건조된 모발의 부드러움과 보습감은 모발타래를 이용하여 전문 미용 패널이 평가를 수행하였다. 본 실험결과 건조된 코아세르베이트 필름의 특성이 샴푸 후 건조된 모발의 부드러움 및 보습감에 영향을 주는 것으로 확인되었다.

Keywords

References

  1. P. Hossel, R. Dieing, R. Norenberg, A. pfau, and R. Sander, Conditioning polymers in today's shampoo formulations - efficacy, mechanism and test method, International Journal of Cosmetic Science, 22(1), 1 (2000). https://doi.org/10.1046/j.1467-2494.2000.00003.x
  2. G. Clera, New cationic conditioning polymers for hair care, ASIA PACIFIC PERSONAL CARE, September (2005).
  3. R. Y. Lochhead and L. R. Huisinga, Advances in Polymers for Hair Conditioning Shampoos, Cosmetics & Toiletries magazine, 120(5), 69 (2005).
  4. E. D. Goddard, T. S. Phillips, and R. B. Hannan, Water soluble polymer-surfactant interaction part I, J. Soc. Cosmet. Chem., 26(9), 461 (1975).
  5. J. Caelles, F. Comelles, J. SaNCHEZ Leal, J. L. Parra, and S. Anguera, Anionic and cationic compounds in mixed systems, Cosmetics & Toiletries, 106(4), 49 (1991).
  6. E. D. Goddard, P. S. Leung, and K. P. A. Padmanabhan, Novel gelling structures based on polymer/ surfactant systems, J. Soc. Cosmet. Chem., 42, 19 (1991).
  7. S. Zhou, C. g Xu, J. Wang, P. Golas, and J. Batteas, Phase behavior of cationic hydroxyethyl cellulose-sodium dodecyl sulfate mixtures: Effect of molecular weight and ethylene oxide side chain length of polymers, Langmuir, 20(20), 8482 (2004). https://doi.org/10.1021/la049142n
  8. R. Y. Lochhead and L. R. Huisinga, A brief review of polymer/surfactant interaction, Cosmetics & Toiletries magazine, 119(2), 37 (2005).
  9. R. L. Schmitt, B. Brook, E. D. Goddard, and Edison, Investigation into the adsorption of cationic polymers, Cosmetics & Toiletries magazine, 109(12), 83 (1994).
  10. J. A. Faucher, E. D. Goddard, and R. B. Hannan, Sorption and desorption of a cationic polymer by human hair: Effect of salt solutions, Textile Research Journal, 47(9), 616 (1977). https://doi.org/10.1177/004051757704700906
  11. Y. K. Kamath, C. J. Dansizer, and H. D. Weigmann, Surface wettability of human hair. III. Role of surfactants in the surface deposition of cationic polymers, Journal of Applied Polymer Science, 30(3), 937 (1985). https://doi.org/10.1002/app.1985.070300305
  12. E. Terada, Y. Samoshina, T. Nylander, and B. Lindman, Adsorption of cationic cellulose derivatives/ Anionic surfactant complexes onto solid surface. I. Silica Surfaces, Langmuir, 20(5), 1753 (2004). https://doi.org/10.1021/la035626s
  13. E. Terada, Y. Samoshina, T. Nylander, and B. Lindman, Adsorption of cationic cellulose derivatives/ anionic surfactant complexes onto solid surface. II. Hydrophobized Silica Surfaces, Lang- muir, 20(16), 6692 (2004). https://doi.org/10.1021/la049922w
  14. F. E. Antunes, E. F. Marques, R. Gomes, K. Thuresson, B. Lindman, and M. G. Miguel, Network formation of cationic vesicles and oppositely charged polyelectrolytes. Effect of polymer charge density and hydrophobic modification, Langmuir, 20(11), 4647 (2004). https://doi.org/10.1021/la049783i
  15. T. Nylander, Y. Samoshina, and B. Lindman, Formation of polyelectrolyte-surfactant complexes on surfaces, Advances in Colloid and Interface Science, 105, 123 (2006).
  16. S. Chiron, Performance and sensorial benefits of cationic guar in hair care applications, Cosmetics & Toiletries magazine, 119(2), 47 (2004).
  17. L. Wing, G. Clara, A. Jennifer, J. Susan, T. Alan, and C. Davis, Maximising shampoo performance, ASIA PACIFIC PERSONAL CARE, July (2006).
  18. M. Gamez-Garcia, Controlling the deposition of insoluble actives to hair from shampoo systems, ASIA PACIFIC PERSONAL CARE, May (2002).
  19. Y. Hiwatari, K. Yoshida, T. Akutsu, M. Yabu, and S. Iwai, Polyelectrolyte micelle coacervation -Effect of coacervate on the properties of shampoo-, International Journal of Cosmetic Science, 26(6), 316 (2004).
  20. R. Y. Lochhead, L. R. Huisinga, and Tara Waller, Deposition from conditioning shampoo: Optimizing coacervate formation, Cosmetics & Toiletries magazine, 121(3), 75 (2006).