Journal of the Korean Society of Marine Environment & Safety (해양환경안전학회지)

The Korean Society of Marine Environment and safety (해양환경안전학회)
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Biogeochemistry of Metal and Nonmetal Elements in the Surface Sediment of the Gamak Bay

가막간 표층퇴적물 중의 금속 및 비금속 원소의 생지화확적 분포특성

  • Kim, Pyoung-Joong (Southwest sea Fisheries Research Institute, National Fisheries Research and Development Institute) ;
  • Shon, Sang-Gyu (Southwest sea Fisheries Research Institute, National Fisheries Research and Development Institute) ;
  • Park, Soung-Yun (Southwest sea Fisheries Research Institute, National Fisheries Research and Development Institute) ;
  • Kim, Sang-Soo (Southwest sea Fisheries Research Institute, National Fisheries Research and Development Institute) ;
  • Jang, Su-Jeong (Southwest sea Fisheries Research Institute, National Fisheries Research and Development Institute) ;
  • Jeon, Sang-Baek (Southwest sea Fisheries Research Institute, National Fisheries Research and Development Institute) ;
  • Ju, Jae-Sik (Southwest sea Fisheries Research Institute, National Fisheries Research and Development Institute)
  • 김평중 (국립수산과학원 남서해수산연구소) ;
  • 손상규 (국립수산과학원 남서해수산연구소) ;
  • 박승윤 (국립수산과학원 남서해수산연구소) ;
  • 김상수 (국립수산과학원 남서해수산연구소) ;
  • 장수정 (국립수산과학원 남서해수산연구소) ;
  • 전상백 (국립수산과학원 남서해수산연구소) ;
  • 주재식 (국립수산과학원 남서해수산연구소)
  • Received : 2012.03.12
  • Accepted : 2012.04.23
  • Published : 2012.04.30
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Abstract

In order to evaluate die geochemical characteristics of sediment in a semi-enclosed bay used as shellfish and fish farming area, the concentrations of metallic(V, Cr, Mn, Fe, Co. Ni, Cu, Zn, Ag, Cd, Hg, Ph, As) and non-metallic(P, Se) elements and uranium were measured in the surface sediment samples collected from 19 stations of Gamak Bay in April 2010. Metal contamination status in the sediments were also evaluated using the sediment quality guidelines(SQGs) proposed by the National Oceanic and Atmospheric Administration(NOAA) and the enrichment factor(EF). The concentrations of elements in sediment were mainly controlled by quartz-dilution effect(V, Cr, Fe, Co and Ni), the dilution effect of organic matter(Cd and U), and metal redistribution by the decomposition of organic matter(Mn, Ag, As, and Se). The concentrations of metals, except As and Ni, in sediments from all sampling stations were lower than ERL values of NOAA. Conclusively, the surface sediment of Gamak Bay was slightly polluted with Ni, Ag, Cd, and Cd but was not polluted with other elements on the basis of EF results. Our results suggest that the surface sediment in Gamak Bay is not polluted by metallic elements.

양식활동이 활발한 반폐쇄적인 내만에서 퇴적물의 지화학적 특성을 파악하기 위하여 2010년 4월 가막만 전역의 19개 정점에서 표층 퇴적물을 채취하여 퇴적물 중의 금속(V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ag, Cd, Hg, Pb, As), 비금속(P, Se) 및 악티늄족 중 U원소의 분포특성을 파악하였다. 또한, 퇴적물기준 및 농축계수를 이용하여 금속원소의 오염도를 평가하였다. V, Cr, Fe, Co 및 Ni 등은 석영희석 효과, Cd 및 U은 유기물 희석효과, Mn, Ag, As 및 Se는 만의 북부 및 남부해역 정점들에서 표층퇴적물의 강한 환원환경경하에서 이산화망간 및 황산염이 유기물 분해의 산화제로 이용되면서 화학적 재분배에 의해 농도분포가 결정되어지는 것으로 보여진다. 미국 퇴적물 오염 기준(SQGs)에 의한 오염평가는 As의 경우 만의 중앙부를 제외한 대부분의 정점, Ni은 전 조사정점에서 ERL을 초과하였다. 농축계수(EF)를 이용한 평가는 Ni, Ag, Cd 및 As가 평균 EF가 1을 약간 초과하는 단계를 보였으며, 이외의 성분은 1과 유사하거나 혹은 그 이하 양호한 수준을 나타내었다.

Keywords

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