Bulletin of the Korean Chemical Society

  • 제33권6호
  • /
  • Pages.2017-2022
  • /
  • 2012
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Novel Lanthanide Coordination Polymers Prepared by Microwave Heating: [Ln(L)3(H2O)2](H2O)3 (Ln = Eu, Tb, Gd; L = trans-(3-py)-CH=CH-COO)

  • Han, Sun-Hwa (Department of Chemistry (BK21), Sungkyunkwan University, Natural Science Campus) ;
  • Zheng, Zhen Nu (Department of Chemistry (BK21), Sungkyunkwan University, Natural Science Campus) ;
  • Cho, Sung-Il (Department of Chemical Engineering, University of Seoul) ;
  • Lee, Soon-W. (Department of Chemistry (BK21), Sungkyunkwan University, Natural Science Campus)
  • 투고 : 2012.02.28
  • 심사 : 2012.03.22
  • 발행 : 2012.06.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Three isostructural lanthanide coordination polymers, $[Ln(L)_3(H_2O)_2](H_2O)_3$ {Ln = Eu (1), Tb (2), Gd (3); L = $trans$-3-(3-pyridyl)acrylate, (3-py)-CH=CH-COO}, were prepared from HL, lanthanide nitrate, and NaOH in $H_2O$ by microwave heating. In all coordination polymers, the metal is bonded to eight oxygen atoms, and all pyridyl nitrogen atoms do not coordinate to the metals. All polymers have a 1-D loop-connected chain structure. The hydrogen atoms in the aqua ligands and lattice water molecules all participate in the hydrogen bonds of the O-$H{\cdots}O$ or O-$H{\cdots}N$ type. The hydrogen bonds connect the 1-D chains to create a 2-D network. Polymer 1 exhibited red luminescence in the solid state at room temperature.

키워드

참고문헌

  1. Medina, M. E.; Platero-Prats, A. E.; Snejko, N.; Rojas, A.; Monge, A.; Gandara, F.; Gutierrez-Puebla, E.; Camblor, M. A. Adv. Mater. 2011, 23, 5283-5292. https://doi.org/10.1002/adma.201101852
  2. Jiang, H.-L.; Xu, Q. Chem. Commun. 2011, 47, 3351-3370. https://doi.org/10.1039/c0cc05419d
  3. Farha, O. K.; Hupp, J. T. Acc. Chem. Res. 2010, 43, 1166-1175. https://doi.org/10.1021/ar1000617
  4. McKinlay, A. C.; Morris, R. E.; Horcajada, P.; Férey, G.; Gref, R.; Couvreur, P.; Serre, C. Angew. Chem. Int. Ed. 2010, 49, 6260- 6266. https://doi.org/10.1002/anie.201000048
  5. Duren, T.; Bae, Y.-S.; Snurrb, R. Q. Chem. Soc. Rev. 2009, 38, 1237-1247. https://doi.org/10.1039/b803498m
  6. Teoa, P.; Hor, T. S. A. Coord. Chem. Rev. 2011, 255, 273-289. https://doi.org/10.1016/j.ccr.2010.08.014
  7. Hou, K.-L.; Bai, F.-Y.; Xing, Y.-H.; Wanga, J.-L.; Shi, Z. CrystEngComm. 2011, 13, 3884-3894. https://doi.org/10.1039/c0ce00707b
  8. Liu, Y.-H.; Fang, H.-P.; Jhang, P.-C.; Peng, C.-C.; Chien, P.-H.; Yang, H.-C.; Huang, Y.-C.; Lo, Y.-L. CrystEngComm. 2010, 12, 1779-1783. https://doi.org/10.1039/b920419a
  9. Jang, Y. O.; Lee, S. W. Polyhedron 2010, 29, 2731-2738. https://doi.org/10.1016/j.poly.2010.06.019
  10. Sun, Y. G.; Gu, X. F.; Ding, F.; Gao, E. J.; Zhang, W. Z. Russ. J. Coord. Chem. 2009, 35, 916-919. https://doi.org/10.1134/S1070328409120100
  11. Yun, S. Y.; Lee, K. E.; Lee, S. W. J. Mol. Struct. 2009, 935, 75-81. https://doi.org/10.1016/j.molstruc.2009.06.044
  12. Huh, H. S.; Lee, S. W. Bull. Korean Chem. Soc. 2006, 27, 1839- 1843. https://doi.org/10.5012/bkcs.2006.27.11.1839
  13. Yao, J.-C.; Guo, J.-B.; Wang, J.-G.; Wang, Y.-F.; Zhang, L.; Fan, C.-P. Inorg. Chem. Commun. 2010, 13, 1178-1183. https://doi.org/10.1016/j.inoche.2010.06.043
  14. Tang, Y.-Z.; Wen, H.-R.; Cao, Z.; Wang, X.-W.; Huang, S.; Yu, C.- L. Inorg. Chem. Commun. 2010, 13, 924-928. https://doi.org/10.1016/j.inoche.2010.04.027
  15. Liu, G.-X.; Xu, Y.-Y.; Ren, X.-M.; Nishihara, S.; Huang, R.-Y. Inorg. Chim. Acta 2010, 363, 3727-3732. https://doi.org/10.1016/j.ica.2010.05.026
  16. Peng, G.; Ma, L.; Liu, B.; Cai, J.-B.; Deng, H. Inorg. Chem. Commun. 2010, 13, 599-602. https://doi.org/10.1016/j.inoche.2010.02.012
  17. Andruh, M.; Costes, J.-P.; Diaz, C.; Gao, S. Inorg. Chem. 2009, 48, 3342-3359. https://doi.org/10.1021/ic801027q
  18. Gunning, N. S.; Cahill, C. L. Dalton Trans. 2005, 2788-2792.
  19. Kurmoo, M.; Estournès, C.; Oka, Y.; Kumagai, H.; Inoue, K. Inorg. Chem. 2005, 44, 217-224. https://doi.org/10.1021/ic0488536
  20. Ayyappan, P.; Evans, O. R.; Lin, W. Inorg. Chem. 2001, 40, 4627- 4632. https://doi.org/10.1021/ic010343d
  21. Zhang, J.; Xiong, R.-G.; Chen, X.-T.; Che, C.-M.; Xue, Z.; You, X.-Z. Organometallics 2001, 20, 4118-4121. https://doi.org/10.1021/om001033q
  22. Zhang, J.; Xiong, R.-G.; Zuo, J.-L.; Che, C.-M.; You, X.-Z. J. Chem. Soc., Dalton Trans. 2000, 2898-2900.
  23. Zhang, J.; Xiong, R.-G.; Zuo, J.-L.; You, X.-Z. Chem. Commun. 2000, 1495-1496.
  24. Liu, C.-B.; Nie, X.-L.; Ding, L.; Xie, M.-Y.; Wen, H.-L. Acta Cryst. 2006, E62, m2319.
  25. Zheng, Z. N.; Lee, S. W. Bull. Korean Chem. Soc. 2011, 32, 1859- 1864. https://doi.org/10.5012/bkcs.2011.32.6.1859
  26. Prior, T. J.; Yotnoi, B.; Rujiwatra, A. Polyhedron 2011, 30, 259- 268. https://doi.org/10.1016/j.poly.2010.10.010
  27. Patricia, S.; Valente, A. V.; Joao, R.; Filipe, A. A. P. Cryst. Growth Des. 2010, 10, 2025-2028. https://doi.org/10.1021/cg900884d
  28. Lee, J. S.; Halligudi, S. B.; Jang, N. H.; Hwang, D. W.; Chang, J.- S.; Hwang, Y. K. Bull. Korean Chem. Soc. 2010, 31, 1489-1495. https://doi.org/10.5012/bkcs.2010.31.6.1489
  29. Liang, P.-C.; Liu, H. K.; Yeh, C.-T.; Lin, C.-H.; Zima, V. Cryst. Growth Des. 2011, 11, 699-708. https://doi.org/10.1021/cg101114h
  30. Huh, S.; Jung, S.; Kim, S.-J.; Park, S. Dalton Trans. 2010, 39, 1261-1265. https://doi.org/10.1039/b916176g
  31. Phetmun, H.; Wongsawat, S.; Pakawatchai, C.; Harding, D. J. Inorg. Chim. Acta 2009, 362, 2435-2439. https://doi.org/10.1016/j.ica.2008.10.038
  32. Zhuang, G.-L.; Sun, X.-J.; Long, L.-S.; Huang, R.-B.; Zheng, L.- S. Dalton Trans. 2009, 4640-4642.
  33. Sheldrick, G. M. SADABS, Program for Absorption Correction, University of Gottingen, 1996.
  34. Bruker, SHELXTL, Structure Determination Software Programs, Bruker Analytical X-ray Instruments Inc., Madison, Wisconsin, USA, 1997.
  35. Muller, G. DaltonTrans. 2009, 9692-9707.
  36. Chen, M.-S.; Su, Z.; Chen, M.; Chen, S.-S.; Li, Y.-Z.; Sun, W.-Y. CrystEngComm. 2010, 12, 3267-3276. https://doi.org/10.1039/c005207h
  37. Liu, Z.-H.; Qiu, Y.-C.; Li, Y.-H.; Deng, H.; Zeller, M. Polyhedron 2008, 27, 3493-3499. https://doi.org/10.1016/j.poly.2008.07.035

피인용 문헌

  1. (HL = 6-(nicotinamido)-2-naphthoic acid) vol.35, pp.7, 2014, https://doi.org/10.5012/bkcs.2014.35.7.2179
  2. Spectral, Electrochemical, Fluorescence, Kinetic and Anti-microbial Studies of Acyclic Schiff-base Gadolinium(III) Complexes vol.33, pp.11, 2012, https://doi.org/10.5012/bkcs.2012.33.11.3581
  3. A Manganese Coordination Polymer and a Palladium Molecular Compound of 3-Pyridinepropionic acid (HL): [MnL2(H2O)2]∞ and trans-[Pd(HL)2Cl vol.34, pp.10, 2012, https://doi.org/10.5012/bkcs.2013.34.10.2947
  4. Structural Isomers of a Potential Linking Ligand Containing a Pyridyl and a Carboxylate Terminals: (n-py)-CH=N-C6H4-CH2-COOH} (n = 3, 4) vol.35, pp.2, 2012, https://doi.org/10.5012/bkcs.2014.35.2.647