Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Rational Design of Coordination Polymers with Flexible Oxyethylene Side Chains

  • Choi, Eun-Young (Department of Molecular Science and Technology, Ajou University) ;
  • Gao, Chun-Ji (Department of Molecular Science and Technology, Ajou University) ;
  • Lee, Suck-Hyun (Department of Molecular Science and Technology, Ajou University) ;
  • Kwon, O-Pil (Department of Molecular Science and Technology, Ajou University)
  • Received : 2011.11.22
  • Accepted : 2012.01.13
  • Published : 2012.04.20
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Abstract

We rationally designed and synthesized metallopolymers with organic 1,4-benzenedicarboxylic acid (BDC) linkers with different lengths of oxyethylene side chains in order to examine the influence of side chains on the coordination characteristics. While in a previous report the BDC linkers with alkyl side chains were found to form three-dimensional (3D) isoreticular metal-organic framework (IRMOF) structures or one-dimensional (1D) coordination polymeric structures with short $-O(CH_2)_6CH_3$ or long $-O(CH_2)_9CH_3$ side chains, respectively, new BDC linkers with oxyethylene side chains of the same lengths, $-(OCH_2CH_2)_2CH_3$ and $-(OCH_2CH_2)_3CH_3$, form only 3D IRMOF structures. This result is attributed to the higher flexibility and smaller volume of oxyethylene side chains compared to alkyl side chains.

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