Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Nano Structured Potentiometric Sensors Based on Polyaniline Conducting Polymer for Determination of Cr (VI)

  • Received : 2011.11.16
  • Accepted : 2012.01.09
  • Published : 2012.04.20
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Abstract

In this paper, a potentiometric sensor based on polyaniline conducting polymer for potentiometric determination of Cr (VI) ions is reported. Polyaniline was synthesized electrochemically (cyclic voltammetry method) onto a micro pencil graphite electrode (0.7 mm diameter) in the presence of HCl and diphenylcarbazide (termed as (PGE/PAni/DPC). Some initial experiments were performed in order to find out the optimized conditions for preparation of the introduced Cr (VI) sensor electrode. The plot of E vs. log [Cr (VI)], showed a linear response in the range from $1.0{\times}10^{-6}$ to $1.0{\times}10^{-1}$ M. High repeatability with the detection limit of $8.0{\times}10^{-7}$ M was obtained.

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