Bulletin of the Korean Chemical Society

  • 제33권4호
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  • Pages.1225-1230
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  • 2012
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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A New Unsymmetrical Zinc Phthalocyanine as Photosensitizers for Dye-sensitized Solar Cells

  • Zhang, Dan (Department of Chemistry, College of Science, North University of China) ;
  • Zhang, Xue-Jun (Department of Chemistry, College of Science, North University of China) ;
  • Zhang, Lei (Department of Chemistry, College of Science, North University of China) ;
  • Mao, Li-Jun (Department of Chemistry, College of Science, North University of China)
  • 투고 : 2011.07.07
  • 심사 : 2012.01.05
  • 발행 : 2012.04.20
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초록

A new unsymmetrical zinc phthalocyanine has been designed and synthesized based on the 'push-pull' and extended ${\pi}$-conjugation concept for the dye-sensitized solar cells. Three tert-butoxy groups, which act as electron releasing ('push'), enhance the solubility of phthalocyanine in common organic solvents and reduce the aggregation. Hydroxy substituted 9,10-anthraquinones act as electron acceptors ('pull') for the study of photoinduced electron transfer processes as well as grafting onto nanocrystalline $TiO_2$. The new unsymmetrical zinc phthalocyanine was fully characterized by FTIR, UV-vis, $^1H$ NMR, cyclic voltammetry and differential pulse voltammetry. The new sensitizer was tested in dye-sensitized solar cells, and gave a better performance.

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참고문헌

  1. Regan, B. O'.; Gratzel, M. Nature 1991, 353, 737. https://doi.org/10.1038/353737a0
  2. Ko, Y. S.; Kim, M. H.; Kwon, Y. U. Bull. Korean Chem. Soc. 2008, 29, 463. https://doi.org/10.5012/bkcs.2008.29.2.463
  3. Hwang, K. J.; Yoo, S. J.; Jung, S. H.; Park, D. W.; Kim, S. I.; Lee, J. W. Bull. Korean Chem. Soc. 2009, 30, 172. https://doi.org/10.5012/bkcs.2009.30.1.172
  4. Nazeeruddin, M. K.; Pechy, P.; Renouard, T.; Zakeeruddin, S. M.; Humphry-Baker, R.; Comte, P.; Liska, P.; Cevey, L.; Costa, E.; Shklover, V.; Spiccia, L.; Deacon, G. B.; Bignozzi, C. A.; Grätzel, M. J. Am. Chem. Soc. 2001, 123, 1613. https://doi.org/10.1021/ja003299u
  5. He, J.; Benko, G.; Korodi, F.; Polivka, T.; Lomoth, R.; Akermark, B.; Sun, L.; Hagfeldt, A.; Sundstrom, V. J. Am. Chem. Soc. 2002, 124, 4922. https://doi.org/10.1021/ja0178012
  6. Leznoff, C. C., Lever, A. B. P., Eds.; Phthalocyanines: Properties and Applications; VCH: New York, 1993; Vol. 1, 1993; Vol. 2, 1993; Vol. 3, 1996; Vol. 4.
  7. Masakazu, N.; Hiroaki, H.; Atsuya, M.; Yoshinobu, N.; Hiroshi, H.; Tatsuo, A. J. Porphyrins Phthalocyanines 2011, 15, 47. https://doi.org/10.1142/S1088424611003008
  8. Nazeeruddin, M. K.; Humphry-Baker, R.; Gratzel, M.; Wohrle, D.; Schnurpfeil, G.; Schneider, G.; Hirth, A.; Trombach, N. J. Porphyrins Phthalocyanines 1999, 3, 230. https://doi.org/10.1002/(SICI)1099-1409(199903)3:3<230::AID-JPP127>3.0.CO;2-L
  9. Deng, H. H.; Mao, H. F.; Zhang, H.; Lu, Z. H.; Xu, H. J. J. Porphyrins Phthalocyanines 1998, 2, 171. https://doi.org/10.1002/(SICI)1099-1409(199803/04)2:2<171::AID-JPP59>3.0.CO;2-8
  10. An, M. S.; Kim, S.; Hong, J. D. Bull. Korean Chem. Soc. 2010, 31, 3272. https://doi.org/10.5012/bkcs.2010.31.11.3272
  11. Giribabu, L.; Vijay Kumar, C. H.; Yella Reddy, P.; Yum, J. H.; Gratzel, M.; Nazeeruddin, M. K, J. Chem. Sci. 2009, 121, 75. https://doi.org/10.1007/s12039-009-0008-9
  12. Giribabu, L.; Kumar, Ch. V.; Reddy, V. G.; Reddy, P. Y.; Rao, Ch. S.; Jang, S.-R.; Yum, J.-H.; Nazeeruddin, M. K.; Gratzel, M. Solar Energy Material & Sola Cells 2007, 91, 1611. https://doi.org/10.1016/j.solmat.2007.05.004
  13. Zhou, W. P.; Zhao, B.; Shen, P.; Jiang, S. H.; Huang, H. D.; Deng, L. J.; Tan, S. T. Dyes and Pigments 2011, 91, 404. https://doi.org/10.1016/j.dyepig.2011.05.017
  14. Liao, M. S.; Scheiner, S. J. Chem. Phys. 2002, 117, 205. https://doi.org/10.1063/1.1480872
  15. Li, C. Y.; Yang, X. C.; Chen, R. K.; Pan, J. X.; Tian, H. N.; Zhu, H. J.; Wang, X. N.; Hagfeldt, A.; Sun, L. C. Solar Energy Materials & Sollar Cells 2007, 91, 1863. https://doi.org/10.1016/j.solmat.2007.07.002
  16. Fang, J.; Su, L.; Wu, J.; Shen, Y.; Lu, Z. New Journal of Chemistry 1997, 21, 1303.
  17. He, J.; Hagfeldt, A.; Lindquist, S. Langmuir 2001, 17, 2743. https://doi.org/10.1021/la001651b
  18. Barbe, C. J.; Arendse, F.; Comte, P.; Jirousek, M.; Lenzmann, F.; Shklover, V.; Gratzel, M. J. Am. Chem. Soc. 1997, 80, 3157.
  19. Wang, P.; Zakeeruddin, S. M.; Comte, P.; Charvet, R,; Humphry- Baker, R.; Gratzel, M. J. Phys. Chem. 1996, 100, 16502. https://doi.org/10.1021/jp960976r
  20. Nazeeruddin, M. K.; De Angelis, F.; Fantacci, S.; Selloni, A.; Viscardi, G.; Liska, P.; Ito, S.; Bessho, T.; Gratzel, M. J. Am. Chem. Soc. 2005, 127, 16835. https://doi.org/10.1021/ja052467l
  21. Zharnikova, N.; Usol'tseva, N.; Kudrik, E.; Thelakkat, M. J. Mater. Chem. 2009, 19, 3161. https://doi.org/10.1039/b821306b
  22. Yenilmez, H. Y.; Ozcesmeci, .; Okur, A. .; Gul, A. Polyhedron 2004, 23, 787. https://doi.org/10.1016/j.poly.2003.12.003
  23. Nazeeruddin, M. K.; Splivallo, R.; Liska, P.; Comte, P.; Gratzel, M. Chem. Commun. 2003, 1456.
  24. Wang, Z. S.; Hara, K.; Dan-oh, Y.; Kasada, C.; Shinpo, A.; Suga, S.; Arakawa, H.; Sugihara, H. J. Phys. Chem. B 2005, 109, 3907. https://doi.org/10.1021/jp044851v
  25. Li, G.; Jiang, K. J.; Bao, P.; Li, Y. F.; Li, S. L.; Yang, L. M. New J. Chem. 2009, 33, 868. https://doi.org/10.1039/b815649b
  26. Kandaz, M.; Yarasir Meryem, N. U.; Koca, A.; Bekaroglu, O. Polyhedron 2002, 21, 255. https://doi.org/10.1016/S0277-5387(01)00982-2
  27. Hagfeldt, A.; Gratzel, M. Chem. Rev. 1995, 95, 49. https://doi.org/10.1021/cr00033a003
  28. Nazeeruddin, M. K.; Humphry-Baker, R.; Grätzel, M.; Murrer, B. A. Chem. Commun. 1998, 719.
  29. Aranyos, V.; Hjelm, J.; Hagfeldt, A.; Grennberg, H. J. Porphyrins Phthalocyanines 2001, 5, 609. https://doi.org/10.1002/jpp.371
  30. Gratzel, M. J. Photochem. Photobiol. C: Photochem. Rev. 2003, 4, 145. https://doi.org/10.1016/S1389-5567(03)00026-1
  31. Garcia-Iglesias, M.; Yum, J. H.; Humphry-Baker, R.; Zakeeruddin, S. M.; Pechy, P.; Vazquez, P.; Palomares, E.; Gratzel, M.; Nazeeruddin, M. K. Chem. Sci. 2011, 2, 1145. https://doi.org/10.1039/c0sc00602e
  32. Kong, F. T.; Dai, S. Y. Progress in Chemistry 2006, 11, 1409.

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  2. Novel planar binuclear zinc phthalocyanine sensitizer for dye-sensitized solar cells: Synthesis and spectral, electrochemical, and photovoltaic properties vol.1079, pp.None, 2012, https://doi.org/10.1016/j.molstruc.2014.09.037