Bulletin of the Korean Chemical Society

  • 제33권1호
  • /
  • Pages.60-64
  • /
  • 2012
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Synthesis of Silver Nanoparticles from the Decomposition of Silver(I) [bis(alkylthio)methylene]malonate Complexes

  • Lee, Euy-Jin (Department of Chemistry and GETRC, Kongju National University) ;
  • Piao, Longhai (Department of Chemistry and GETRC, Kongju National University) ;
  • Kim, Jin-Kwon (Department of Chemistry and GETRC, Kongju National University)
  • 투고 : 2011.09.16
  • 심사 : 2011.10.28
  • 발행 : 2012.01.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Silver(I) [bis(alkylthio)methylene]malonates were synthesized from the reaction of silver nitrate and potassium [bis(alkylthio)methylene]malonates. The structures of the Ag complexes were characterized with nuclear magnetic resonance (NMR), inductively coupled plasma atomic emission spectrometry (ICP-AES) and elemental analysis. Ag nanoparticles (NPs) were obtained from the decomposition of the Ag complexes in 1,2-dichlorobenzene at $110^{\circ}C$ without an additional surfactant. The average sizes of the Ag NPs are in the range of 5.1-6.3 nm and could be controlled by varying the length of the alkyl chain. The optical properties, crystalline structure and surface composition of Ag NPs were characterized with ultraviolet-visible (UV-visible) spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), gas chromatography-mass spectrometry (GC-MS), X-ray Photoelectron Spectroscopy (XPS) and thermal gravimetric analysis (TGA).

키워드

참고문헌

  1. Rosi, N. L.; Mirkin, C. A. Chem. Rev. 2005, 105, 1547. https://doi.org/10.1021/cr030067f
  2. Puntes, V. F.; Krishnan, K. M.; Alivisatos, A. P. Science 2001, 291, 2115. https://doi.org/10.1126/science.1057553
  3. Burda, C.; Chen, X. B.; Narayanan, R.; El-Sayed, M. A. Chem. Rev. 2005, 105, 1025. https://doi.org/10.1021/cr030063a
  4. Zhang, W.; Qiao, X. J. Chen, Mater. Sci. Eng. B 2007, 142, 1. https://doi.org/10.1016/j.mseb.2007.06.014
  5. Bronstein, L. M.; Kostylev, M.; Shtykova, E.; Vlahu, T.; Huang, X.; Stein, B. D.; Bykov, A.; Remmes, N. B.; Baxter, D. V.; Svergun, D. I. Langmuir 2008, 24, 12618. https://doi.org/10.1021/la8021276
  6. Brinas, R. P.; Hu, M. H.; Qian, L. P.; Lymar, E. S.; Hainfeld, J. F. J. Am. Chem. Soc. 2008, 130, 975. https://doi.org/10.1021/ja076333e
  7. Shrivastava, S.; Bera, T.; Singh, S. K.; Singh, G.; Ramachandrarao, P.; Dash, D. ACS Nano 2009, 3, 1357. https://doi.org/10.1021/nn900277t
  8. Smetana, A. B.; Klabunde, K. J.; Marchin, G. R.; Sorensen, C. M. Langmuir 2008, 24, 7457. https://doi.org/10.1021/la800091y
  9. Murray, B. J.; Walter, E. C.; Penner, R. M. Nano Lett. 2004, 4, 665. https://doi.org/10.1021/nl049841k
  10. Dearden, A. L.; Smith, P. J.; Shin, D. Y.; Reis, N.; Derby, B.; O'Brien, P. Macromol. Rapid Commun. 2005, 26, 315. https://doi.org/10.1002/marc.200400445
  11. Kamyshny, A.; Ben-Moshe, M.; Aviezer, S.; Magdassi, S. Macromol. Rapid Commun. 2005 , 26, 281. https://doi.org/10.1002/marc.200400522
  12. Rycenga, M.; Cobley, C. M.; Jie, Z.; Weiyang, L.; Christine, H. M.; Qiang, Z.; Dong, Q.; Xia, Y. N. Chem. Rev. 2011, 111, 3669. https://doi.org/10.1021/cr100275d
  13. Yamamoto, M.; Nakamoto, M. J. Mater. Chem. 2003, 13, 2064. https://doi.org/10.1039/b307092a
  14. Kashiwagi, Y.; Yamamoto, M.; Nakamoto, M. J. Colloid Interface Sci. 2006, 300, 169. https://doi.org/10.1016/j.jcis.2006.03.041
  15. Yamamoto, M.; Kashiwagi, Y.; Nakamoto, M. Langmuir 2006, 22, 8581. https://doi.org/10.1021/la0600245
  16. Abe, K.; Hanada, T.; Yoshida, Y.; Tanigaki, N.; Takiguchi, H.; Nagasawa, H.; Nakamoto, M.; Yamaguchi, T.; Yase, K. Thin Solid Films 1998, 327-329, 524. https://doi.org/10.1016/S0040-6090(98)00702-0
  17. Jensen, K. A.; Henriksen, L. Acta Chem. Scand. 1968, 22, 1107. https://doi.org/10.3891/acta.chem.scand.22-1107
  18. Soderback, E. Acta Chem. Scand. 1962, 17, 362. https://doi.org/10.3891/acta.chem.scand.17-0362
  19. Gompper , R.; Topfl, W. Chem. Ber. 1962, 95, 2861. https://doi.org/10.1002/cber.19620951206
  20. Lee, S. J.; Han, S. W.; Choi, H. J.; Kim, K. J. Phys. Chem. B. 2002, 106, 2829. https://doi.org/10.1021/jp013139k
  21. Lee, S. J.; Han, S. W.; Choi, H. J.; Kim, K. J. Phys. Chem. B. 2002, 106, 7439. https://doi.org/10.1021/jp0255841
  22. Kim, J.; Park, C.-H.; Kim, S.-H.; Yoon, S.; Piao, L. Bull. Korean Chem. Soc. 2011, 32, 3267. https://doi.org/10.5012/bkcs.2011.32.9.3267
  23. Piao, L.; Lee, K. H.; Min, B. K.; Kim, W.; Do, Y. R.; Yoon, S. Bull. Korean Chem. Soc. 2011, 32, 117. https://doi.org/10.5012/bkcs.2011.32.1.117
  24. He, S.; Yao, J.; Xie, S.; Gao ,H.; Pang, S. J. Phys. D. 2001, 34, 342.

피인용 문헌

  1. Colorimetric Detection Based on Localised Surface Plasmon Resonance Optical Characteristics for the Detection of Hydrogen Peroxide Using Acacia Gum–Stabilised Silver Nanoparticles vol.12, pp.1177-3901, 2017, https://doi.org/10.1177/1177390116684686
  2. Synthesis of silver nanoparticles using bacterial exopolysaccharide and its application for degradation of azo-dyes vol.15, pp.None, 2012, https://doi.org/10.1016/j.btre.2017.02.006