Analytical Science and Technology (분석과학)

The Korean Society of Analytical Sciences (한국분석과학회)
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Property analysis of polysilane precursors and applications for polysilicon

폴리실란으로부터 생성한 폴리실리콘의 물성 분석과 응용

  • Received : 2012.11.30
  • Accepted : 2012.12.06
  • Published : 2012.12.25
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Abstract

Polysilane black powders were synthesized by sonochemical methods from silicon tetrachloride with sodium metal with 37.0% yield. Those black powder materials were found to have fibrous or irregular shapes with round surface. It was found that thermal behaviors of those polysilane black powders were similar to that of hydropolysilanes which was reported earlier. After thermal treatment, black polysilicon was obtained with 57.1% residue yield, and those fibrous or irregular shapes with round surface were intact but lots of small cavities were formed indicating porous structure, and found to be an amorphous state from XRD analysis.

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References

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