Bulletin of the Korean Chemical Society

  • 제32권10호
  • /
  • Pages.3592-3596
  • /
  • 2011
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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A Novel Iron(III) Selective Membrane Electrode Containing a Tripodal Polycatacholamine as Sensor

  • Bera, Rati Kanta (Department of Chemistry, Sant Longowal Institute of Engineering & Technology) ;
  • Sahoo, Suban K (Department of Applied Chemistry, SV National Institute of Technology) ;
  • Baral, Minati (Department of Chemistry, National Institute of Technology) ;
  • Kanungo, B.K. (Department of Chemistry, Sant Longowal Institute of Engineering & Technology)
  • 투고 : 2011.06.24
  • 심사 : 2011.08.06
  • 발행 : 2011.10.20
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초록

A novel poly(vinylchloride)-based membrane sensor using $N^1$,$N^3$,$N^5$-tris(2-(2,3-dihydroxybenzylamino)-ethyl)cyclohexane-1,3,5-tricarboxamide (CYCOENCAT, L) as ionophore has been prepared and explored as $Fe^{3+}$ selective electrode. The membrane electrode composed of ionophore, poly(vinylchloride) and o-nitropheyloctyl ether in the optimum ratio 4:33:63 gave excellent potentiometric response characteristics, and displayed a linear log[$Fe^{3+}$] versus EMF response over a wide concentration range of $1.0{\times}10^{-5}-1.0{\times}10^{-1}$ M with super nernstian slope of 28.0 mV/decade and the detection limit of $8.0{\times}10^{-6}$ M. The proposed ion selective electrode showed fast response time (< 15 s), wide pH range (3.0-7.0), high non-aqueous tolerance (up to 20%) and adequate long life time (120 days). It also exhibited very good selectivity for $Fe^{3+}$ relative to a wide variety of alkali, alkaline earth, transition and heavy metal ions. Further, the analytical applicability of the sensor was tested as an indicator electrode in the potentiometric titration of $Fe^{3+}$ with EDTA.

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