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A Study on an Operating Conditions for the Direct Ethanol Fuel Cell

직접에탄올 연료전지의 운전조건에 관한 연구

  • Received : 2011.08.24
  • Accepted : 2011.10.10
  • Published : 2011.11.01

Abstract

The goal of this paper is to find an operating conditions of the single direct ethanol fuel cell such as the cell temperature, and flow rates of ethanol and oxygen. To investigate the output characteristics, the electrical current increased from 0[A] with interval of 0.001[A] every 2[s], and the cell voltage was increased until the voltage became 0.05[V]. Related to the effect of the cell temperature, the output characteristics both voltage and power were increased upto 80[$^{\circ}C$] according to the increase of the current density, but those were decreased over that temperature. In addition, the optimal flow rate of ethanol in anode was identified as of 2[mL/min] due to the dependence of generation rate such as the hydrogen ion and electron. And the flow rate of oxygen in cathode was desirable to about 300[sccm/min], it might be affected by the chemical reaction rate of the water formation among hydrogen ion, electron, and oxygen. Consequently, the fundamental conditions were identified in this work, and it will be carried out to find the best conditions of membrane by the effect of the plasma surface treatment, and the effect of other catalysts except for a platinum.

Keywords

References

  1. J. Larminie, A. Dicks, "Fuel Cell Systems Explained", John Wiley & Sons, LTD, England, 2000
  2. J,s. Bett, H.R. Kunz, A.J. Aldykiewicz Jr, J.M. Fenton W.S. Bailey, D.V. McGrath, "Platinum-macrocycle co-catalysts for the electrochemical oxidation of methanol", Electrochimica Acta, Vol. 43, No. 24, 3645-3655, 1998 https://doi.org/10.1016/S0013-4686(98)00122-4
  3. F. Vigier, C. Coutanceau, F. Hahn, E.M. Belgsir, C. Lamy "On the mechanism of ethanol electrooxidation on Pt and PtSn catalysts: electrochemical and in situ IR reflectance spectroscopy studies", J. of Electoanalytical Chem., Vol. 563, No. 1, 81-89, 2004 https://doi.org/10.1016/j.jelechem.2003.08.019
  4. C. Lamy, S. Rousseau, E.M Belgsir, C. Coutanceau, and J.-M. Leger. "Recent progress in the direct ethanol fuel cell: development of new platinum-tin electrocatalysts", Electrochimica Acta, Vol. 49, No. 22-23, 3901-3908, 2004 https://doi.org/10.1016/j.electacta.2004.01.078
  5. C. Lamy, J.-M. Leger, J. Phys. IV, 1994
  6. S. Rousseau, C. Coutanceau, C. Lamy, J.-M. Leger, "Direct ethanol fuel cell (DEFC): Electrical performances and reaction products distribution under operating conditions with different platinum-based anodes", J. of Power Sources, Vol. 158, No. 1, 18-24, 2006 https://doi.org/10.1016/j.jpowsour.2005.08.027
  7. A.S. Arico, S. Srinivasan, V. Antonucci, "Fuel cell" 1, 134, 2001
  8. S. Song, W. Zhou, J. Tian, Rui Cai, G. Sun, Q. Xin, S. Kontou, P. Tsiakaras, "Ethanol crossover phenomena and its influence on the performance of DEFC", J. of Power Sources, Vol. 145, No. 2, 266-271, 2005 https://doi.org/10.1016/j.jpowsour.2004.12.065
  9. S. Song, G. Wang, W. Zhou, X. Zhaa, G. Sun, Q. Xin., S. Kontou, P. Tsiakaras, "The effect of the MEA preparation procedure on both ethanol crossover and DEFC performance", J. of Power Sources, Vol. 140, No. 1, 103-110, 2005 https://doi.org/10.1016/j.jpowsour.2004.08.011
  10. Thangaraj Mathuraiveeran, Kimball Roelofs, Doreen Senftleben, Thomas Schiestel, "Proton conducting composite membranes with low ethanol crossover for DEFC", Desalination, Vol. 200, No. 1-3, 662-663, 2006 https://doi.org/10.1016/j.desal.2006.03.483
  11. Q. Wang, G.Q. Sun, L. Cao, L.H. Jiang, G.X. Wang, S.L. Wang, S.H. Yang, Q. Xin, "High performance direct ethanol fuel cell with double-layered anode catalyst layer" J. of Power Sources, Vol. 177, No. 1, 142-147, 2008 https://doi.org/10.1016/j.jpowsour.2007.11.040