Bulletin of the Korean Chemical Society

  • 제32권9호
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  • Pages.3389-3394
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  • 2011
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Isomeric Trimethylbenzyl Radicals Produced by Corona Discharge of 1,2,3,5-Tetramethylbenzene

  • Lee, Gi-Woo (Department of Chemistry, Korea University) ;
  • Yoon, Young-Wook (Department of Chemistry and The Chemistry Institute for Functional Materials, Pusan National University) ;
  • Lee, Sang-Kuk (Department of Chemistry and The Chemistry Institute for Functional Materials, Pusan National University)
  • 투고 : 2011.06.11
  • 심사 : 2011.06.30
  • 발행 : 2011.09.20
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초록

Isomeric trimethylbenzyl radicals were generated and vibronically excited from precursor 1,2,3,5-tetramethylbenzene, isodurene, with a large amount inert carrier gas helium in a corona excited supersonic expansion (CESE) using a pinhole-type glass nozzle. A long-path monochromator was used to record the visible vibronic emission spectra of the jet-cooled benzyl-type radicals in the $D_1{\rightarrow}D_0$ electronic transition. From the analysis of the spectra, we identified the evidence of the presence of three isomeric trimethylbenzyl radicals in the corona discharge, and obtained the electronic energy and a few vibrational mode frequencies in the ground electronic state for each isomer.

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피인용 문헌

  1. Spectroscopic Evidence of Jet-Cooled p-Chloro-α-Methylbenzyl Radical in Corona Excitation vol.33, pp.9, 2012, https://doi.org/10.5012/bkcs.2012.33.9.2943
  2. The electronic spectroscopy of resonance-stabilised hydrocarbon radicals vol.35, pp.2, 2016, https://doi.org/10.1080/0144235X.2016.1166830
  3. Confirmed assignments of isomeric dimethylbenzyl radicals generated by corona discharge vol.135, pp.21, 2011, https://doi.org/10.1063/1.3663962
  4. Vibronic Assignments of Isomeric Trimethylbenzyl Radicals : Revisited vol.35, pp.3, 2011, https://doi.org/10.5012/bkcs.2014.35.3.737
  5. Spectroscopic identification of dichlorobenzyl radicals: Jet-cooled 2,3-dichlorobenzyl radical vol.633, pp.None, 2011, https://doi.org/10.1016/j.cplett.2015.05.026