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Synthesis of Zr-Ti Alloy Powder by Magnesium Reduction

마그네슘환원에 의한 지르코늄-티타늄 합금분말 합성

  • Lee, Dong-Won (Powder Technology Research Group, Korea Institute of Materials Science (KIMS)) ;
  • Park, Geun-Tae (Institute of Research and Industry Cooperration, Pusan National University) ;
  • Lim, Tae-Soo (Powder Technology Research Group, Korea Institute of Materials Science (KIMS)) ;
  • Lee, Hye-Moon (Powder Technology Research Group, Korea Institute of Materials Science (KIMS)) ;
  • Yu, Ji-Hun (Powder Technology Research Group, Korea Institute of Materials Science (KIMS))
  • 이동원 (한국기계연구원 부설 재료연구소) ;
  • 박근태 (부산대학교 산학협력단) ;
  • 임태수 (한국기계연구원 부설 재료연구소) ;
  • 이혜문 (한국기계연구원 부설 재료연구소) ;
  • 유지훈 (한국기계연구원 부설 재료연구소)
  • Received : 2011.06.03
  • Accepted : 2011.07.15
  • Published : 2011.08.28

Abstract

Zr-Ti alloy powders were successfully synthesized by magnesium thermal reduction of metal chlorides. The evaporated and mixed gasses of $ZrCl_4+TiCl_4$ were injected to liquid magnesium and the chloride components were reduced by magnesium leading to the formation of $MgCl_2$. The released Zr and Ti atoms were then condensed to particle forms inside the mixture of liquid magnesium and magnesium chloride, which could be dissolved fully in post process by 1~5% HCl solution at room temperature. By the fraction-control of individually injected $ZrCl_4$ and $TiCl_4$ gasses, the final compositions of produced alloy powders were changed in the ranges of Zr-0 wt.%~20 wt.%Ti and their purity and particle size were about 99.4% and the level of several micrometers, respectively.

Keywords

References

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Cited by

  1. Synthesis of Vanadium Powder by Magnesiothermic Reduction vol.1025-1026, pp.1662-8985, 2014, https://doi.org/10.4028/www.scientific.net/AMR.1025-1026.509