The Effects of Surface Morphology of Poly(ethylene terephthalate) Film on Detergency of Particulate Soil (II) -The Adsorption of Surfactant and Interfacial Electrical Phenomena-

PET 필름의 표면 모폴로지가 고형오구의 세척성에 미치는 영향(II) -계면활성제 흡착 및 계면전기적 현상-

  • Kang, In-Sook (Department of Clothing & Textiles, Changwon National University)
  • 강인숙 (창원대학교 자연과학대학 의류학과)
  • Received : 2011.07.29
  • Accepted : 2011.09.20
  • Published : 2011.10.28

Abstract

This study is the preliminary part in investigating the influence of surface characteristics of substrates on detergency of particulate soil. The surface of PET film was modified with NaOH and DMF for different time. Generally, the adsorption of surfactants of the film treated with NaOH and DMF was relatively higher and lower than those of non-treated film, respectively. And the adsorption of surfactant was increased with an increasing concentration of the surfactant regardless of its treated condition. But the effect of ionic strength on the adsorption of surfactant varied with the treated condition. The ${\zeta}$-potential of film and the interaction energy between ${\alpha}-Fe_2O_3$particle and a PET film treated with NaOH was largely higher than the original film, but those treated with DMF was lower. The adsorption of surfactants to the film and the ${\zeta}$-potential of film were related more with contact angle and surface energies than with the surface roughness and surface area. A coefficient of the correlation between adsorption of surfactant to substrate and the ${\zeta}$-potential of film was over 0.9.

Keywords

Acknowledgement

Supported by : 한국학술진흥재단

References

  1. D. J. Shaw, "Introduction to Colloid and Surface Chemistry", Butter-Worths, London, 1970, pp.161-183.
  2. T. Imamura and F. Tokiwa, "The Comparison of Interfacial Electrical Effects on the Detergency Calculated from the DLVO Theory with Those from Hetero Coagulation Theory", Nippon Kagaku Kaishi, 1976, 6, 869-881.
  3. D. V. Robert and J. V. Marjorie, "Colloid Interface Chemistry", Addison-Wesley, London, 1983, pp.164-167.
  4. I. Krznaric and N. Kally, "Stability of Ag/I Colloid in the Presence of Ionic Surface Active Agents and Electrolytes in Aqueous Medium". Tenside Surf Det, 1979, 16, 252-261.
  5. I. S. Kang and S. Y. Jung, "Effect of Steric Stability by Adsorption of Surfactant on Detergency of Particulate Soil in Anionic /nonionic Surfactant Mixed Solution (Part 2) -Adsorption of Surfactant to the Fabric and Adhesion of Particle to Fabric-". Text Sci Eng, 2005, 42, 174-181.
  6. I. S. Kang, "Influence of Characteristics of Textile Materials Finished with Hydrophilic and Hydrophobic Chemicals on Detergency of Particulate Soil-the Adsorption of Surfactant to Fabric and $\zeta$ Potential of Substrate", Text Sci Eng, 2006, 43, 344-352.
  7. I. S. Kang, M. H. Mun, and J. J. Rha, "The Surface Morphology and Characteristics of Poly(ethylene Terephthalate) Film", J Kor Soc Clothing and Text, 2010, 34, 1880-1188. https://doi.org/10.5850/JKSCT.2010.34.11.1880
  8. E. Matijevic and P. Scheiner, "Ferric Hydrous Oxide Sols", J Colloid Interface Sci, 1978, 63, 509. https://doi.org/10.1016/S0021-9797(78)80011-3
  9. D. C. Abbott, "The Colorimetric Determination of Anionic Surface-active Materials in Water", Analyst, 1962, 87, 286- 293. https://doi.org/10.1039/an9628700286
  10. T. Imamura and F. Tokiwa, "Consideration of Interfacial Electrical Conditions of Soil-deposition onto Fabrics". Nippon Kagaku Kaishi, 1974, 3, 406-414.
  11. I. S. Kang and B. J. Kim, "Effect of Electrolyte on Adhesion of Particulate Soil to Fabric in the Surfactant Solution", J Kor Soc Clothing and Text, 2002, 25, 1465-1474.
  12. R. Hogg, T. W. Healy, and D. W. Ferstenau, "Mutual Coagulation of Colloidal Dispersion", Trans Faraday Soc, 1966, 62, 1638-1642. https://doi.org/10.1039/tf9666201638