청정기술 (Clean Technology)

  • 제17권1호
  • /
  • Pages.56-61
  • /
  • 2011
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  • 1598-9712(pISSN)
  • /
  • 2288-0690(eISSN)
한국청정기술학회 (The Korean Society of Clean Technology)
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감압잔사유 수첨분해반응의 생성물 분석방법 비교

Comparison of Analytical Methods of Products in Hydrocracking of Vacuum Residue

  • 권혁민 (울산대학교생명화학공학부) ;
  • 김한나 (울산대학교생명화학공학부) ;
  • 웬후이친 (울산대학교생명화학공학부) ;
  • 김도경 (촉매 Lab, SK에너지기술원) ;
  • 김도완 (촉매 Lab, SK에너지기술원) ;
  • 오승훈 (촉매 Lab, SK에너지기술원) ;
  • 신은우 (울산대학교생명화학공학부)
  • Kweon, Hyuk-Min (School of Chemical Engineering and Bioengineering, University of Ulsan) ;
  • Kim, Han-Na (School of Chemical Engineering and Bioengineering, University of Ulsan) ;
  • Huy, Chinh Nguyen (School of Chemical Engineering and Bioengineering, University of Ulsan) ;
  • Kim, Do-Kyong (Catalyst Lab, SK Energy Institute of Technology) ;
  • Kim, Do-Woan (Catalyst Lab, SK Energy Institute of Technology) ;
  • Oh, Seung-Hoon (Catalyst Lab, SK Energy Institute of Technology) ;
  • Shin, Eun-Woo (School of Chemical Engineering and Bioengineering, University of Ulsan)
  • 투고 : 2010.11.15
  • 심사 : 2011.02.23
  • 발행 : 2011.03.31
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초록

감압잔사유를 고압 회분식 반응기에 넣고, 상용 Ni-Mo/$Al_2O_3$ 촉매를 이용하여 $450^{\circ}C$, $500^{\circ}C$에서 수첨분해하였다. 그리고 반응 생성물을 단증류 혹은 GC-SIMDIS 방법으로 각각 분석하였다. 먼저 수첨분해반응에서는 두 온도 조건 모두 촉매 반응뿐만 아니라 열분해 반응도 같이 일어나고 있음을 확인하였고, 온도가 증가할수록 전환율이 증가하고, 생성물 중 가솔린 및 납사 비율이 높아졌다. 생성물 분석 결과, $500^{\circ}C$ 반응에서는 단증류와 GC-SIMDIS 분석 결과의 차이가 없었지만, $450^{\circ}C$ 반응에서는 단증류에서는 디젤이, GC-SIMDIS에서는 vacuum gas oil이 주 생성물로 드러났다. 이는 $450^{\circ}C$ 반응에서의 단증류 분석은 단증류에 의한 열분해 반응으로 인해 생성물의 선택도가 정확하지 않음을 알려준다.

In this study, hydrocarcking of vacuum residue was carried out in an autoclave reactor at $450^{\circ}C$ and $500^{\circ}C$ with a commercial catalyst (HDM) and the quantitative product distributions were analyzed by GC-SIMDIS method or simple distillation. During catalytic hydrocracking, thermal cracking also occurred together with catalytic cracking and the higher conversion and selectivity of gasoline and naphtha were obtained at high reaction temperature. GC-SIMDIS and simple distillation revealed different results for the analysis of products produced at different hydrocracking temperatures; almost same results were obtained for the product produced at $500^{\circ}C$ but different ones for the product produced at $450^{\circ}C$. In the analysis of product produced at $450^{\circ}C$, the GC-SIMDIS showed that a main product was VGO while a main product in the simple distillation was diesel, which implies that the simple distillation for the $450^{\circ}C$ reaction was not accurate due to thermal cracking of the product by the simple distillation.

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참고문헌

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