Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Liquid-phase Dehydration of 1-Phenylethanol to Styrene over an Acidic Resin Catalyst

  • Khan, Nazmul Abedin (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University) ;
  • Hwang, Jin-Soo (Bio-refinerary Research Center, Korea Research Institute of Chemical Technology) ;
  • Jhung, Sung-Hwa (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University)
  • Received : 2011.01.27
  • Accepted : 2011.03.03
  • Published : 2011.04.20
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Abstract

Dehydration of 1-phenylethanol to produce styrene has been studied in liquid phase with three solid acid catalysts such as H-ZSM-5, H-Y and Amberlyst-15. Amberlyst-15 shows the highest conversion and styrene yield, suggesting the applicability of a resin catalyst in the dehydration. The good performance of the Amberlyst-15 may be due to high acid concentration and ready diffusion of reactants and products. A possible reaction scheme (such as the formation of styrene from diphenylethylether) has also been suggested.

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References

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