Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Liquid-phase Dehydration of 1-Phenylethanol to Styrene over an Acidic Resin Catalyst

  • Khan, Nazmul Abedin (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University) ;
  • Hwang, Jin-Soo (Bio-refinerary Research Center, Korea Research Institute of Chemical Technology) ;
  • Jhung, Sung-Hwa (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University)
  • Received : 2011.01.27
  • Accepted : 2011.03.03
  • Published : 2011.04.20
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Abstract

Dehydration of 1-phenylethanol to produce styrene has been studied in liquid phase with three solid acid catalysts such as H-ZSM-5, H-Y and Amberlyst-15. Amberlyst-15 shows the highest conversion and styrene yield, suggesting the applicability of a resin catalyst in the dehydration. The good performance of the Amberlyst-15 may be due to high acid concentration and ready diffusion of reactants and products. A possible reaction scheme (such as the formation of styrene from diphenylethylether) has also been suggested.

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References

  1. Molnar, A.; Bartok, M. Dehydration of Alcohols, In Heterogeneous Catalysis; Sheldon, R. A., van Bekkum, H., Eds.; Wiley-VCH: Weinheim, 2001; pp 295-307.
  2. Lee, K. Y.; Chae, H.-J.; Jeong, S.-Y.; Seo, G. Appl. Catal. A: General 2009, 369, 60-66. https://doi.org/10.1016/j.apcata.2009.08.033
  3. Chen, D.; Moljord, K.; Fuglerud, T.; Holmen, A. Micropor. Mesopor. Mater. 1999, 29, 191-203. https://doi.org/10.1016/S1387-1811(98)00331-X
  4. Lee, Y.-J.; Baek, S.-C.; Jun, K.-W. Appl. Catal. A: General 2007, 329, 130-136. https://doi.org/10.1016/j.apcata.2007.06.034
  5. Jun, K.-W.; Lee, H.-S.; Roh, H.-S.; Park, S.-E. Bull. Kor. Chem. Soc. 2002, 23, 803-806. https://doi.org/10.5012/bkcs.2002.23.6.803
  6. Jiang, S.; Hwang, Y. K.; Jhung, S. H.; Chang, J.-S.; Hwang, J.-S.; Cai, T.; Park, S.-E. Chem. Lett. 2004, 33, 1048-1049. https://doi.org/10.1246/cl.2004.1048
  7. Delsarte, S.; Grange, P. Appl. Catal. A: General 2004, 259, 269-279. https://doi.org/10.1016/j.apcata.2003.09.030
  8. Macias, O.; Largo, J.; Pesquera, C.; Blanco, C.; Gonzalez, F. Appl. Catal. A: General 2006, 314, 23-31. https://doi.org/10.1016/j.apcata.2006.07.027
  9. Medina, E.; Bringué, R.; Tejero, J.; Iborra, M.; Fite, C. Appl. Catal. A: General 2010, 374, 41-47. https://doi.org/10.1016/j.apcata.2009.11.024
  10. Chai, S.-H.; Wang, H.-P.; Liang, Y.; Xu, B.-Q. Green Chem. 2007, 9, 1130-1136. https://doi.org/10.1039/b702200j
  11. Chang, J.-S.; Hong, D.-Y.; Vislovskiy, V. P.; Park, S.-E. Catal. Survey Asia 2007, 11, 59-69. https://doi.org/10.1007/s10563-007-9021-5
  12. Kochloefl, K.; Muhler, M. Dehydrogenation of ethylbenzene, In Handbook of Heterogeneous Catalysis; Ertl, G., Knozinger, H., Schüth, F., Weitkamp, J., Eds.; 2nd ed.; Wiley-VCH: Weinheim, 2008; 7, 3229-3240.
  13. Bertero, N. M.; Apesteguía, C. R.; Marchi, A. J. Catal. Commun. 2009, 10, 1339-1344. https://doi.org/10.1016/j.catcom.2009.02.018
  14. Bertero, N. M.; Apesteguía, C. R.; Marchi, A. J. Catal. Commun. 2008, 10, 261-265. https://doi.org/10.1016/j.catcom.2008.09.002
  15. Lange, J.-P.; Otten, V. Ind. Eng. Chem. Res. 2007, 46, 6899-6903. https://doi.org/10.1021/ie070397g
  16. Lange, J.-P.; Otten, V. J. Catal. 2006, 238, 6-12. https://doi.org/10.1016/j.jcat.2005.11.033
  17. Romanova, R. G.; Lamberov, A. A.; Shmelev, I. G. Kinetics Catal. 2004, 45, 422-428. https://doi.org/10.1023/B:KICA.0000032179.51404.69
  18. Sharma, M. M. Reactive Funct. Polymer 1995, 26, 3-23. https://doi.org/10.1016/1381-5148(95)00029-F
  19. Yoon, J. W.; Chang, J.-S.; Lee, H.-D.; Kim, T.-J.; Jhung, S. H. J. Mol. Catal. A 2006, 260, 181-186. https://doi.org/10.1016/j.molcata.2006.07.026
  20. Yoon, J. W.; Jhung, S. H.; Chang, J.-S. Bull. Kor. Chem. Soc. 2008, 29, 339-341. https://doi.org/10.5012/bkcs.2008.29.2.339
  21. Yoon, J. W.; Jhung, S. H.; Lee, J. S.; Kim, T.-J.; Lee, H.-D.; Chang. J.-S. Bull. Kor. Chem. Soc. 2008, 29, 57-60. https://doi.org/10.5012/bkcs.2008.29.1.057
  22. Yoon, J. W.; Jhung, S. H.; Kim, T.-J.; Lee, H.-D.; Jang, N. H.; Chang, J.-S. Bull. Kor. Chem. Soc. 2007, 28, 2075-2078. https://doi.org/10.5012/bkcs.2007.28.11.2075

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