Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Brønsted Acidic Ionic Liquids as Efficient Catalysts for Clean Synthesis of Carbamatoalkyl Naphthols

  • Tavakoli-Hoseini, Niloofar (Department of Chemistry, Faculty of Sciences, Mashhad Branch, Islamic Azad University) ;
  • Heravi, Majid M. (Department of Chemistry, School of Sciences, Alzahra University) ;
  • Bamoharram, Fatemeh F. (Department of Chemistry, Faculty of Sciences, Mashhad Branch, Islamic Azad University) ;
  • Davoodnia, Abolghasem (Department of Chemistry, Faculty of Sciences, Mashhad Branch, Islamic Azad University)
  • Received : 2010.10.30
  • Accepted : 2010.12.23
  • Published : 2011.03.20
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Abstract

Under mild conditions and without any additional organic solvent, synthesis of carbamatoalkyl naphthols could be carried out in the present of two halogen-free Br${\phi}$nsted acidic ionic liquids, 3-methyl-1-(4-sulfonic acid)butylimidazolium hydrogen sulfate and N-(4-sulfonic acid)butylpyridinium hydrogen sulfate. A wide range of aromatic aldehydes easily undergo condensation with $\beta$-naphthol and methyl or benzyl carbamate to afford the desired products of good purity in excellent yields. The present methodology offers several advantages such as a simple procedure with an easy work-up, short reaction times, and excellent yields. The catalysts could be recycled and reused for several times without substantial reduction in their catalytic activities.

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References

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