Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Simple Synthetic Manipulation Allowing for Morphological Diversity of Porphyrin-Based Microcrystals

  • Received : 2010.10.28
  • Accepted : 2010.12.13
  • Published : 2011.02.20
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Abstract

Amphiphilic (porphyrin)Sn$(OH)_2$ molecular building block can directly translate into well-defined solid-state microcrystalline structures. The crystalline diamond plates are obtained from ethanol and crystalline square plates are grown from methanol solution. With a simple synthetic manipulation during the microcrystal growth, the morphologies can be controlled by adopting different molecular packing. Consequently, morphologies of microcrystals have been diversified. Furthermore, the macroscopic crystals were obtained in the presence of cetyltrimethylammonium bromide (CTAB).

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References

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