Journal of the Korea Organic Resources Recycling Association (유기물자원화)

Korea Organic Resources Recycling Association (유기성자원학회)
권호 표지
DOI QR코드

DOI QR Code

Novel Techniques for Remediation of Contaminated Soil with Heavy Metals Using Magnetic Substances

자성체를 사용하는 중금속 오염토양의 새로운 복원기술

  • Jeon, Choong (Department of BioChemical Engineering, Gangneung-Wonju National University)
  • 전충 (강릉원주대학교 생명화학공학과)
  • Received : 2011.08.29
  • Accepted : 2011.12.13
  • Published : 2011.12.31
Download PDF
⟨ Previous Next ⟩

Abstract

In order to remediate contaminated soils with heavy metals, many techniques have been developed and proposed. However, weakness for the various techniques has been making application for actual process difficult. They have been led to the necessity for novel techniques. Therefore, in this study, novel techniques which are developing and commercializing recently in domestic/foreign country will be introduced, especially it will be focused on remediation technique for contaminated soil with heavy metals using magnetic material.

중금속으로 오염된 토양을 복원시키기 위한 여러 가지 기술들이 개발되어지고 제안되어져 왔다. 그러나 다양한 기술들에 대한 단점은 실제공정에 대한 적용을 어렵게 했으며 새로운 기술들에 대한 필요성이 대두되어지고 있다. 그래서 본 본문에서는 최근에 새롭게 개발되어지거나 실용화되어지고 있는 국/내외 기술들에 대하여 소개하고자 하며 특히, 자성체를 이용한 중금속 오염토양 복원기술에 대해 중점적으로 고찰하고자 한다.

Keywords

References

  1. Bank, M., "Basiswissen Umwelttechnik Wasser", Luft, Abfall, Lrm, Umweltrecht. 2., bearb. Aufl., Vogel Wrzburg, 757 S. (1994).
  2. Schuster, M., Sandor, K. and Mller, J., "Umweltchem. Entfernung von Schwermetallen aus einem Boden mit hohem Schluffanteil", kotox., 10(2), pp. 99-106. (1998).
  3. Huang, J. W., Chen, J., Berti, W. R. and Cunningham, S. D., "Phytoremediation of lead-contaminated soils: Role of synthetic chelates in lead phytoextraction", Environ. Sci. Technol., 31(3), pp. 800-805. (1997). https://doi.org/10.1021/es9604828
  4. Wu, J., Hsu, F. C. and Cunningham, S. D., "Chelate-assisted Pb phytoextraction: Pb availability, uptake, and translocation constants", Environ. Sci. Technol., 33(11), pp. 1898-1904. (1999). https://doi.org/10.1021/es9809253
  5. Blaylock, M. J., Salt, D. E., Dushenkov, S., Zakharova, O., Gussman, C., Bolto, B. A. and Pawlowski L., : in Wastewater treatment by Ion-exchange (1th ed.) great britain, new York, U.S.A., pp. 209-253. (1987).
  6. Vassil, A. D., Kapulnik, Y., Raskin, I. and Salt, D. E., "The role of EDTA in lead transport and accumulation by Indian Mustard", Plant Physiol., 117, pp. 447-453. (1998). https://doi.org/10.1104/pp.117.2.447
  7. Roll, J., : Entsorgungstechnik. VCH Verlag Weinheim, S. 117-157. (1996).
  8. Langen, M., : Untersuchungen zu Grundlagen der namechanischen Bodenwsche unter besonderer Bercksichtigung der Abtrennung von Schwermetalltrgerstoffen durch Dichtesortierung und Magnetisierung. Dissertation an der RWTH Aachen, S. pp. 1-19. (1995).
  9. Steele, M. C. and Pichtel, J., "Ex-situ remediation of metal-contaminated superfund soil using selective extractants", J. Environ. Engineering, 7, pp. 639-645. (1998).
  10. Hiroshi, H., Masanori, Abe. and Kohki, Noda., "Biomedical and environmental applications of functionalized magnetic beads", (2005).
  11. Lorenz, J., : Remobilisierung von Schwermetallen aus ruhenden Gewssersedimenten durch EDTA und NTA bei aerober und anaerober Wasserphase. Dissertation an der TH Karlsruhe, S. 1-4. (1997).
  12. Hairston, D. W., "Ring up the chelates", Chem. Engineering, 1, pp. 57-60. (1997).
  13. Chen, S.-Y., Liou, C.-N. and Lin, J.-G., "The influence of nitrilotriacetic acid (NTA) on metal mobilization from a contaminated river sediment", Wat. Sci. Tech., 37(6-7), pp. 47-54. (1998). https://doi.org/10.1016/S0273-1223(98)00181-4
  14. Hong, P. K. A., Li, C., Banerji, S. K. and Regmi, T., "Extraction, recovery, and biostability of EDTA for remediation of heavy metal-contaminated soil", J. Soil Contamination, 8(1), pp. 81-103. (1999). https://doi.org/10.1080/10588339991339243
  15. So, H, "Einsatz von Magnetite-immobilisierten Chelatoren zur Extraktion von Schwermetallen aus Boden und Wasser", Dissertation an der RWTH Aachen, S. 21-23. (2003).
  16. Bolto, B. A., "Magnetic particle technology for wastewater treatment", Waste Management, 10, pp. 11-21. (1990). https://doi.org/10.1016/0956-053X(90)90065-S
  17. Mueller-Schulte, D., Fssl, F. and De Cuyper, M., "Novel magnetic microcarriers on the basis of poly(vinylalcohol) for biomedical analysis", In: Scientific and Clinical Applications of magnetic carriers, Haefeli et al. (eds.), Plenum Press New York, S. pp. 93-107. (1997).
  18. Ozaki, H., Liu, Z. and Terashima, Y., 1991 "Utilization of microorganisms immobilized with magnetic particles for sewage and wastewater treatment", (1991).
  19. Mueller-Schulte, D. and Brunner, H., "Novel magnetic microspheres on the basis of poly(vinylalcohol) as affinity medium for quantitative detection of glycated haemoglobin", J. Chromatography A, 711, pp. 53-60. (1995). https://doi.org/10.1016/0021-9673(95)00114-3
  20. Bergemann, C., Mueller-Schulte, D., Oster, J., Brassard, L. and Lbbe, A. S., "Magnetic ion-exchange nano- and microparticles for medical, biochemical and molecular biological application", J. Magnetism and Magnetic Mat., 194, pp. 45-52. (1999). https://doi.org/10.1016/S0304-8853(98)00554-X
  21. Parikh, I. and Cuatrecasas, P., "Affinity Chromatography. In: Molecular Interactions in Bioseparations, Ngo,T.N. (eds.)", Plenum Press New York, S. 3-13. (1993).
  22. Dresco, P. A., Zaitsev, V. S., Gambino, R. J. and Chu, B., "Preparation and properties of magnetite and polymer magnetite nanoparticles", Langmuir, 15, pp. 1945-1951. (1999). https://doi.org/10.1021/la980971g
  23. Zaitsev, V. S., Filimonov, D. S., Presnyakov, I. A., Gambino, R. J. and Chu, B., "Physical and chemical properties of magnetite and magnetite-polymer nanoparticles and their colloidal dispersions", J. Colloid and Interface Sci., 212, pp. 49-57. (1999). https://doi.org/10.1006/jcis.1998.5993
  24. Lasch, J. and Koelsch, R., "Enzyme linkage and multipoint attachment of agarose bound enzyme preparation", Eur. J. Biochem., 82, pp. 181-186. (1978). https://doi.org/10.1111/j.1432-1033.1978.tb12010.x
  25. Nilsson, K. and Mosbach, K., "Immobilization of enzymes and affinity ligands to various hydroxyl group carring supports using reactive sulfonyl chlorides", Biochem. and Biophysical Res. Communications, 102(1), pp. 449-457. (1981). https://doi.org/10.1016/0006-291X(81)91541-2
  26. Hearn, M. T. W., 1986: "Application of 1,1-carbonyldiimidazole-activated matrices for the purification of proteins", J. Chromatogr., 376, pp. 245-257. (1986). https://doi.org/10.1016/S0378-4347(00)80841-5
  27. Bethell, G. S., Ayers, J. S., Hearn, T. W. and Hancock, W. S., "Investigation of the activation of cross-linked agarose with carbonylating reagents and the preparation of matrices for affinity chromatography purifications", J. Chromatogr., 219, pp. 353-359. (1981).
  28. Porath, J. and Axen, R., "Immobilization of enzymesto agar, agarose and Sephadex supports", Methods Enzymol., 44, pp. 19-45. (1976).
  29. Morgan, P. E., Thomas, O. R., Dunnil, P., Sheppard, A. J. and Slater, N. K., "Poly(vinylalcohol)-coated perfluorocarbon supports for metal chelating affinity separation of a monoclonal antibody", J. Mol. Recognition, 9(5-6), pp. 394-400. (1996). https://doi.org/10.1002/(SICI)1099-1352(199634/12)9:5/6<394::AID-JMR273>3.0.CO;2-B
  30. Narinesingh, D. and Ngo, T. T., "Activation of supports containing hydroxyl groups using bis(4-nitrophenyl)carbonate", Analytical Letters, 29(4), pp. 547-564. (1996). https://doi.org/10.1080/00032719608000420
  31. Monthiller, S., Heck, M.-P., Mioskowski, C., Lafargue, P., Lellouche, J.-P. and Masella, M., "An efficient activation of the hydroxyl funktion by (diethylamino)sulfur trifluoride (DAST): preparation of chiral polyoxygenated tetrahydrofurans by stereoselective benzyloxy group participation", Bull. Soc. Chim. Fr., 134, pp. 145-151. (1997).
  32. Ngo, T. T., "Procedure for activating polymers with primary and/or secondary hydroxyl groups", Makromol. Chem., Makromol. Symp., 17, pp. 229-239. (1988). https://doi.org/10.1002/masy.19880170116
  33. Mueller-Schulte, D., "Synergistic-radiation grafting: A novel modification technique for the preparation of biomaterials", Radiat. Phys. Chem., 42, pp. 891-896. (1993). https://doi.org/10.1016/0969-806X(93)90396-C