DOI QR코드

DOI QR Code

Decolorization of Acid Orange II from Aqueous Solutions using Loess

황토를 이용한 Acid Orange II의 색도제거

  • Park, Jae Hong (Measure and Analysis Division, Yeongsan River Basin Environmental Office)
  • 박재홍 (영산강유역환경청 측정분석과)
  • Received : 2010.03.25
  • Accepted : 2011.02.28
  • Published : 2011.03.30

Abstract

Loess, a natural clay, was evaluated as an adsorbent for the decolorization of Acid Orange II, an azo and reactive dye, from aqueous solution. Adsorption studies were performed at $30^{\circ}C$ and the effect of reaction time, loess dosage, initial concentration, loess particle size, pH, agitation rate were investigated to determine the optimum operation conditions. The removal efficiencies of color were measured to evaluate the effectiveness of loess. From this study, it was found that optimal reaction time was 10 min. Color removal efficiencies of Acid Orange II were increased as higher loess dosage, initial concentration and agitation rate. However, color removal efficiencies decreased when pH is high and loess particle becomes large. Adsorption of Acid Orange II fitted to the pseudo-second-order rate kinetics more than first-order rate kinetics. Langmuir and Freundlich adsorption isotherm constants and correlation coefficients were calculated and compared. It was concluded that the adsorption data of Acid Orange II onto loess fitted to the Freundlich model more than Langmuir model.

Keywords

References

  1. 김상범, 이명화, 김용진, 박철환, 이종래, 김경수(2007). 음식물 쓰레기 및 황토 혼합물의 열분해를 통한 수질정화용 다공성 담체 개발. 대한환경공학회지, 29(3), pp. 289-296.
  2. 백미화, 전혜인, 이지애, 김동수(2009). 활성탄과 유리섬유를 흡착제로 이용한 아조염료 함유 폐수의 처리. 수질보전 한국물환경학회지, 25(3), pp. 370-374.
  3. 윤종섭, 김승현, 윤조희(2003). 황토살포에 의한 적조생물 제거. 대한환경공학회지, 25(3), pp. 358-363.
  4. Ahn, D. and Chang, W. (1999). Dyestuff wastewater treatment using chemical oxidation, physical adsorption and fixed bed biofilm process. Process Biochem., 34, pp. 429-439. https://doi.org/10.1016/S0032-9592(98)00111-3
  5. Akkaya, G. and Ozer, A. (2005). Biosorption of Acid Red 274 (AR 274) on Dicranella varia: determination of equilibrium and kinetic model parameters. Process Biochem., 40, pp. 3559-3568. https://doi.org/10.1016/j.procbio.2005.03.048
  6. Bai, R. S. and Abraham, T. E. (2001). Biosorption of Cr (VI) from aqueous solution by Rhizopus nigricans. Bioresour. Technol., 79, pp. 73-81. https://doi.org/10.1016/S0960-8524(00)00107-3
  7. Brown, D. and Laboureur, P. (1983). The degradation of dyestuffs: Part I Primary biodegradation under anaerobic conditions. Chemosphere, 12(3), pp. 397-404. https://doi.org/10.1016/0045-6535(83)90114-5
  8. Chung, K. T. and Cerniglia, C. E. (1992). Mutagenicity of azo dyes, structure-activity relationships. Mutat Res., 277, pp. 201-220. https://doi.org/10.1016/0165-1110(92)90044-A
  9. Couto, S. R., Dominguze, A., and Sanroman, A. (2001). Photocatalytic degradation of dyes in aqueous solution operating in a fluidizedbed reactor. Chemosphere, 46, pp. 83-86.
  10. Dhodapkar, R., Rao, N. N., Pande, S. P., and Kaul, S. N. (2006). Removal of basic dyes from aqueous medium using a novel polymer: Jalshakti. Bioresour. Technol., 97, pp. 877-885. https://doi.org/10.1016/j.biortech.2005.04.033
  11. Ergene, A., Ada, K., Tan, S., and Katırcıoğlu, H. (2009). Removal of Remazol Brilliant Blue R dye from aqueous solutions by adsorption onto immobilized Scenedesmus quadricauda: Equilibrium and kinetic modeling studies. Desalination, 249, pp. 1308-1314. https://doi.org/10.1016/j.desal.2009.06.027
  12. Gong, R., Ding, Y., Li, M., Yang, C., Liu, H., and Sun, Y. (2005). Utilization of powdered peanut hull as biosorbent for removal of anionic dyes from aqueous solution. Dye Pigments, 64, pp. 187-192. https://doi.org/10.1016/j.dyepig.2004.05.005
  13. Hameed, B. H. and Hakimi, H. (2008). Utilization of durian (Durio zibethinus Murray) peel as low cost sorbent for the removal of acid dye from aqueous solutions. Biochem. Eng. J., 39, pp. 338-343. https://doi.org/10.1016/j.bej.2007.10.005
  14. Ho, Y. S. and McKay, G. (1999). Pseudo-second order model for sorption processes. Process Biochem., 34, pp. 451-465. https://doi.org/10.1016/S0032-9592(98)00112-5
  15. Imamoglu, M. and Tekir, O. (2008). Removal of copper (II) and lead (II) ions from aqueous solutions by adsorption on activated carbon from a new precursor hazelnut husks. Desalination, 228, pp. 108-113. https://doi.org/10.1016/j.desal.2007.08.011
  16. Kamari, A., Wane Ngah, W. S., Chong, M. Y., and Cheah, M. L. (2009). Sorption of acid dyes onto GLA and $H_{2}SO_{4}$ cross-linked chitosan beads. Desalination, 249, pp. 1180-1189. https://doi.org/10.1016/j.desal.2009.04.010
  17. Kiriakidou, F., Kondarides, D. I., and Verykios, X. E. (1999). The effect of operational parameters and TiO2-doping on the photocatalytic degradation of Azo-dyes. Catalysis Today, 54, pp. 119-130. https://doi.org/10.1016/S0920-5861(99)00174-1
  18. Koumanova, B. and Peeva-Antova, P. (2002). Adsorption of p-chlorophenol from aqueous solutions on bentonite and perlite. J. Hazard. Mater., 90, pp. 229-234. https://doi.org/10.1016/S0304-3894(01)00365-X
  19. Lagergren, S. (1898). About the theory of so called adsorption of soluble substances, K. Sevenska Vetenskapsakad Handl., 24, pp. 1-6.
  20. Larous, S., Meniai, A. H., and lehocine, M. B. (2005). Experimental study of the removal of copper from aqueous solutions by adsorption using sawdust. Desalination, 185, pp. 483-490. https://doi.org/10.1016/j.desal.2005.03.090
  21. McCann, J. and Ames, B. N. (1975). Proc. Natl. Acad. Sci., U.S.A.
  22. Mohanthy, K., Naidu, J. T., Meikap, B. C., and Biswas, M. N. (2006). Removal of crystal violet from wastewater by activated carbons prepared from rise husk. Ind. Eng. Chem. Res., 45, pp. 5165-5171. https://doi.org/10.1021/ie060257r
  23. Nadaroglu, H., Kalkan, E., and Demir, N. (2010). Removal of copper from aqueous solution using red mud. Desalination, 251, pp. 90-95. https://doi.org/10.1016/j.desal.2009.09.138
  24. Ozer, A., Akkaya, G., and Turabik, M. (2006). Biosorption of Acid Blue 290 (AB 290) and Acid Blue 324 (AB 324) dyes on Spirogyra rhizopus. J. Hazard. Mater., 135, pp. 355-364. https://doi.org/10.1016/j.jhazmat.2005.11.080
  25. Pagga, U. and Brown, D. (1986). The degradation of dyestuffs: Part II Behaviour of dyestuffs in aerobic biodegradation tests. Chemosphere, 15(4), pp. 479-491. https://doi.org/10.1016/0045-6535(86)90542-4
  26. Palanisamy, P. N. and Sivakumar, P. (2009). Kinetic and isotherm studies of the adsorption of Acid Blue 92 using a low-cost non-conventional activated carbon. Desalination, 249, pp. 388-397. https://doi.org/10.1016/j.desal.2009.09.006
  27. Rauf, N. and Tahir, S. S. (2003). Themodynamic studies of Ni (II) adsorption onto bentonite from aqueous solution. J. Chem. Themodyn., 35, pp. 2003-2009. https://doi.org/10.1016/S0021-9614(03)00153-8
  28. Robinson, T., McMullan, G., Marchant, R., and Nigam, P. (2001). Remidation of dyes in textile effluent, a critical review on current treatment technologies with a proposed alternative. Bioresesour. Technol., 77, pp. 247-255. https://doi.org/10.1016/S0960-8524(00)00080-8
  29. Sag, Y. and Aktay, Y. (2000). Mass transfer and equilibrium studies for the sorption of chromium ions onto chitin. Process Biochem., 36, pp. 157-173. https://doi.org/10.1016/S0032-9592(00)00200-4
  30. Tahir, S. S. and Rauf, N. (2006). Removal of cationic dye from aqueous solutions by adsorption onto bentonite clay. Chemosphere, 63, pp. 1842-1848. https://doi.org/10.1016/j.chemosphere.2005.10.033
  31. Tsai, W. T., Chang, C. Y., Ing, C. H., and Chang, C. F. (2004). Adsorption of acid dyes from aqueous solution on activated bleaching earth. Colloid and Interface Sci., 275, pp. 72-78. https://doi.org/10.1016/j.jcis.2004.01.072
  32. Viraraghavan, T. and Kapoor, A. (1994). Adsorption id mercury from wastewater by bentonite. Appl. Clay Sci., 9, pp. 31-39. https://doi.org/10.1016/0169-1317(94)90013-2
  33. Waranusantigul, P., Pokethitiyook, P., Kruatrachue, M., and Upatham, E. S. (2003). Kinetics of basic dye (methylene blue) biosorption by giant duckweed (Spirodela polyrrhiza). Environ. Pollut., 125, pp. 385-392. https://doi.org/10.1016/S0269-7491(03)00107-6