DOI QR코드

DOI QR Code

간섭계를 이용한 차량 기반 에어로졸 광흡수 측정 연구

Study of Aerosol Light Absorption Measurement Operated in a Vehicle Using an Interferometer

  • 이정훈 (한국기술교육대학교 기계정보공학부)
  • Lee, Jeong-Hoon (School of Mechanical Engineering, Korea Univ. of Tech. & Edu.)
  • 투고 : 2011.06.27
  • 심사 : 2011.08.22
  • 발행 : 2011.12.01

초록

대기중에 부유하고 있는 입자들의 광흡수량을 측정할 수 있는 기법을 소개한다. 본 연구에서 사용된 기법은 광열분광법이다. 광흡수 측정에 있어서 광열 기법의 장점은 광산란에 둔감할 뿐만 아니라 광산란 계수의 영향을 받지 않고 광흡수 계수를 직접적으로 측정할 수 있다는 것이다. 공기중 부유물질의 흡수 계수 측정의 시간 상수는 10 초이며, 실시간으로 고속도로 주변에서 흡수 계수를 측정하였다. 자동차 경주용 트랙, 공항, 또는 연구소 정문 등 차량 통행량이 많은 지역에서의 흡수 계수가 높게 측정되었는데, 이는 카본 부유물 입자에 의한 영향이라고 판단된다.

We propose a method operated in a vehicle to measure light absorption of particles in atmosphere. The advantage of this method is that it is insensitive to light scattering and hence can be used for the direct measurement of the light absorption coefficient without suffering from light scattering. With this method atmospheric light absorption can be measured at a time constant of 10 s. Further, our method allows for the real-time measurement of light absorption near a highway. The light absorption coefficients were high near a race track, an airport and the main gate where vehicles emitted carbonaceous particles.

키워드

참고문헌

  1. Solomon, S. E. et. al., 2007, Technical Summary: Climate Change 2007: The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change, Cambridge University Press, Cambridge, United Kingdom and New York, USA.
  2. Moss, R. H., Edmonds, J. A., Hibbard, K. A., Manning, M. R., Rose, S. K., van Vuuren, D. P., Carter, T. R., Emori, S., Kainuma, M., Kram, T., Meehl, G. A., Mitchell, J. F. B., Nakicenovic, N., Riahi, K., Smith, S. J., Stouffer, R. J., Thomson, A. M., Weyant, J. P. and Wilbanks, T. J., 2010, "The Next Generation of Scenarios for Climate Change Research and Assessment," Nature, Vol. 463, pp. 747-756. https://doi.org/10.1038/nature08823
  3. Ishii, Y., Chen, J., and Murata, K., 1987, "Digital Phase-Measuring Interferometry with A Tunable Laser Diode," Opt. Lett., 12, 233-235. https://doi.org/10.1364/OL.12.000233
  4. Stone, J. A., Stejskal, A., and Howard, L., 1999, "Diode Lasers in Length Metrology: Application to Absolute Distance Interferometry," Int. J. Metrology, Nov-Dec: pp. 1-7.
  5. Downs, M. J., 1990, "A Proposed Design for an Optical Interferometer with Sub-Nanometric Resolution," Nanotechnology, Vol. 1, pp. 27-30. https://doi.org/10.1088/0957-4484/1/1/005
  6. Abou-Zeid, A., and Wiese, P., 1998, "Interferometer with a Wavelength-Tuned Diode Laser for Surface Profilometry," Meas. Sci. Technol., Vol. 9, pp. 1105-1110. https://doi.org/10.1088/0957-0233/9/7/017
  7. Bialkowski, S. E., 1996, Photothermal Spectroscopy Methods for Chemical Analysis, Vol. 134 Chemical Analysis: A Series of Monographs on Analytical Chemistry and its Application, John Wiley and Sons Publisher, New York.
  8. Moosmüller, H., and Arnott, W. P., 1996, "Folded Jamin Interferometer: A Stable Instrument for Refractive- Index Measurements," Opt. Lett., Vol. 21, pp. 438-440. https://doi.org/10.1364/OL.21.000438
  9. Moosmüller, H., Arnott, W. P., and Roger, C. F., 1997, "Methods for Real-Time, in situ Measurement of Aerosol Light Absorption," J. Air and Waste Management Assoc., Vol. 47, pp. 157-166. https://doi.org/10.1080/10473289.1997.10464430
  10. Sedlacek, A. J., 2006, "Real-Time Detection of Ambient Aerosols Using Photothermal Interferometry: Folded Jamin Interferometer," Rev. Sci. Instrum., Vol. 77, pp. 064903. https://doi.org/10.1063/1.2205623
  11. Lin, H.-B., and Campillo, A. J., 1985, "Photothermal Aerosol Absorption Spectroscopy," Appl. Opt., Vol. 24, pp. 422-433. https://doi.org/10.1364/AO.24.000422
  12. Davis, C. C., 1980, "Trace Detection in Gases Using Phase Fluctuation Optical Heterodyne Spectroscopy," Appl. Phys. Lett., Vol. 36, pp. 515-518. https://doi.org/10.1063/1.91590
  13. Davis, C. C., and Petuchowski, S. J., 1981, "Phase Fluctuation Optical Heterodyne Spectroscopy of Gases," Appl. Opt., Vol. 20, pp. 2539-2554 and errata: Appl. Opt., Vol. 20, pp. 4151. https://doi.org/10.1364/AO.20.002539
  14. Dovichi, N. J., 1990, Laser-Based Microchemical Analysis, Rev. Sci. Instrum., Vol. 61, pp. 3653-3667. https://doi.org/10.1063/1.1141533
  15. Davis, C. C., 1996, Laser and Electro-Optics - Fundamentals and Engineering, Cambridge University Press, New York.
  16. Lack, D. A., Lovejoy, E. R., Baynard, T., Pettersson, A., and Ravishankara, A. R., 2006, "Aerosol Absorption Measurement Using Photoacoustic Spectroscopy: Sensitivity, Calibration, and Uncertainty Developments," Aerosol Sci. Tech., Vol. 40, pp. 697-708. https://doi.org/10.1080/02786820600803917
  17. Davidson, J. A., Cantrell, C. A., McDaniel, A. H., Shetter, R. E., Madronich, S., and Calvert, J. G., 1988, "Visible-Ultraviolet Absorption Cross Sections for $NO_2$ As A Function of Temperature," J. Geophys. Res., Vol. 93, pp. 7105-7112. https://doi.org/10.1029/JD093iD06p07105
  18. Vandaele, A. C., Hermans, C., Simon, P. C., Carleer, M., Colin, R., Fally, S., Mérienne, M. F., Jenouvrier, A., and Coquart, B., 1998, "Measurements of the $NO_2$ Absorption Cross-Section from 42000 $cm^{−1}$ to 10000 $cm^{−1}$(238-1000 nm) at 220 K and 294 K," J. Quant. Spectrosc. Radiat. Transf., Vol. 59, pp. 171-184. https://doi.org/10.1016/S0022-4073(97)00168-4
  19. Vandaele, A. C., Hermans, A. C., Simon, P. C., Van Roozendael, M., Guilmot, J. M., Carleer, M., and Colin, R., 1996, "Fourier Transform Measurement of NO2 Absorption Cross-Section in the Visible Range at Room Temperature," J. Atmos. Chem., Vol. 25, pp. 289-305. https://doi.org/10.1007/BF00053797
  20. Harder, J. W., Brault, J. W., Johnston, P. V., and Mount, G. H., 1997, "Temperature Dependent $NO_2$ Cross Sections at High Spectral Resolution," J. Geophys. Res., Vol. 102, pp. 3861-3879. https://doi.org/10.1029/96JD03086
  21. Owens, M. A., Davis, C. C., and Dickerson, R. R., 1999, "A Photothermal Interferometer for Gas-Phase Ammonia Detection," Anal. Chem., Vol. 71, pp. 1391-1399. https://doi.org/10.1021/ac980810h
  22. Brewer, R. J., and Bruce, C. W., 1978, "Photoacoustic Spectroscopy of $NH_3$ at the $9-{\mu}m$ and $10-{\mu}m^{12}C^{16}O_2$ Laser Wavelengths," Appl. Opt., Vol. 17, pp. 3746-3749. https://doi.org/10.1364/AO.17.003746
  23. Moosmuller H., Chakrabarty R. K., and Arnott W. P., 2009, "Aerosol Light Absorption and Its Measurement: A Review," J. Quant. Spectrosc. Radiat. Transfer, Vol. 110, pp. 844-878. https://doi.org/10.1016/j.jqsrt.2009.02.035