$Ba(Zr_{0.85}Y_{0.15})O_{3-\delta}$-NI Composite Membrane for Hydrogen Separation by Aerosol Deposition Method

에어로졸 증착법(Aerosol Depostion method)에 의한 $Ba(Zr_{0.85}Y_{0.15})O_{3-\delta}$-NI 수소분리막 제조

  • Park, Young-Soo (Korea Institute of Ceramic Engineering & Technology) ;
  • Choi, Jin-Sub (Nanostructured materials research lab, Chemical Engineering and Biotechnology, Inha University) ;
  • Byoun, Myoung-Sub (Korea Institute of Ceramic Engineering & Technology) ;
  • Kim, Jin-Ho (Korea Institute of Ceramic Engineering & Technology) ;
  • Hwang, Kwang-Taek (Korea Institute of Ceramic Engineering & Technology)
  • 박영수 (한국세라믹기술원 이천분원) ;
  • 최진섭 (인하대학교 생명화학공학부 나노구조 소재 연구실) ;
  • 변명섭 (한국세라믹기술원 이천분원) ;
  • 김진호 (한국세라믹기술원 이천분원) ;
  • 황광택 (한국세라믹기술원 이천분원)
  • Received : 2010.07.29
  • Accepted : 2010.08.20
  • Published : 2010.08.31

Abstract

$(Ba(Zr_{0.85}Y_{0.15})O_{3-\delta})$ oxide, showing high protonic conductivity at high temperatures and good chemical stability with $CO_2$ are referred to as hydrogen separation membrane. For high efficiency of hydrogen separation ($H_2$ flux and selectivity) and low fabrication cost, ultimate thin and dense BZY-Ni layer has to be coated on a porous substrate such as $ZrO_2$. Aerosol depostion (AD) process is a novel technique to grow ceramic film with high density and nano-crystal structure at room-temperature, and may be applicable to the fabrication process of AD integration ceramic layer effectively. XRD, SEM, X-ray mapping measurements were conducted in order to analyze the characteristics of BZY-Ni membrane fabricated by AD process. it is observed that it is homogeneous distribution for BZY-Ni. The result of $H_2$ permeation rate suggests that BZY-Ni composite is higher than BZY.

Keywords

References

  1. K. T. Hwang, Ho Cheong, "Filtering characterization of dense ceramic membrane for hydrogen separation", New & Renewable Energy, 2005, pp. 19-24.
  2. H. S. JE, K. S. CHA, H. S. KIM, Y. S. LEE, C. S. PARK, Y. H. KIM, "Stepwise Production of Syngas and Hydrogen from Methane on Ferrite Based Media Added with YSZ", Transactions of the korean hydrogen and new energy society, 2010.02, pp. 50-57.
  3. T. Hibino, K Mizutani, T. Yajima and H. iwahara, "Evaluation of proton conductivity in $SrCeO_3$ $BaCeO_3$,$ CaZrO_3 $ and $SrZrO_3$ by temperature programmed desorption method", Solid State Ionics 57 (3-4), 1992, pp. 303-306. https://doi.org/10.1016/0167-2738(92)90162-I
  4. D. S. Park, B. D. Han, J. J Choi, U. H. Yun, J. H. RUI, "Nano structure ceramics coating process by aerosol deposition", Journal of The Korea Ceramic Society, 2007, pp. 7-21.
  5. J. Akedo, M. Lebedev, A. Iwata, H. Ogiso, and S. Nakano, "Aerosol deposition method (ADM) for nano-crystal ceramics coating without firing", Mater. Res. Soc. Symp. Proc., 2003, pp. 778, 289-299.
  6. S. Kasahara, G. J. Hwang, H. Nakajima, H. S. Choi, K. Onuki, and M. Nomura, "Effects of the process parameters of the IS process on total thermal efficiency to produce hydrogen from water", J. Chem. Eng. Jpn., Vol. 36, No. 7, 2003, p. 887. https://doi.org/10.1252/jcej.36.887
  7. K. D. Kreuer, "On the development of proton conducting materials for technological applications", solid state ionics, 97, 1 1997.
  8. M. Lebedev, J. Akedo, T. Ito, "Substrate heating effects on hardness of an $\alpha$-$Al_2O_3$ thick film formed by aerosol deposition method", Journal of Crystal Growth 275, 2005, pp. 1301-1306. https://doi.org/10.1016/j.jcrysgro.2004.11.109
  9. J. Akedo, M. Lebedev, Jpn. J. Appl. Phys., "Microstructure and electrical properties of lead zirconate titanate (Pb($Zr_{52}/Ti_{48})O_3$) thick films deposited by aerosol deposition method", Japanese Journal of Applied Physics, part1, 1999, pp. 5397-5401.
  10. J. Akedo, "Aerosol deposition of ceramic thick films at room temperature", densification mechanism of ceramic layers. J. Am. Ceram. Soc. 2006, pp. 1834-1839.
  11. M. Lebedev, J. Akedo, T. Ito, "Substrate heating effects on hardness of an$\alpha$-$Al_2O_3$ thick film formed by aerosol deposition method", Journal of Crystal Growth 275, 2005, pp. 1301-1306. https://doi.org/10.1016/j.jcrysgro.2004.11.109
  12. J. Akedo, M. Lebedev, A. Iwata, S. Nakano, and H. Ogiso, "Aerosol deposition for nanocomposite materials synthesis-a novel method of ceramics processing without firing", Ceram. Eng. Sci. Proc., 2003, pp. 9-14.