Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Catalytic Ozonation of Phenol in Aqueous Solution by Co3O4 Nanoparticles

  • Dong, Yuming (School of Chemical and Material Engineering, Jiangnan University) ;
  • Wang, Guangli (School of Chemical and Material Engineering, Jiangnan University) ;
  • Jiang, Pingping (School of Chemical and Material Engineering, Jiangnan University) ;
  • Zhang, Aimin (School of Chemistry and Chemical Engineering, Key Laboratory of Mesoscopic Chemistry, Nanjing University) ;
  • Yue, Lin (School of Food Science and Technology, Jiangnan University) ;
  • Zhang, Xiaoming (School of Food Science and Technology, Jiangnan University)
  • Received : 2010.06.14
  • Accepted : 2010.08.20
  • Published : 2010.10.20
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Abstract

The degradation efficiencies of phenol in aqueous solution were studied by semi-continuous experiments in the processes of ozone alone, ozone/bulky $Co_3O_4$ and ozone/$Co_3O_4$ nanoparticles. Catalyst samples (bulky $Co_3O_4$ and $Co_3O_4$ nanoparticles) were characterized by X-ray diffraction and transmission electron microscopy. The Brunauer-Emmett-Teller surface area, $pH_{pzc}$ and the density of surface hydroxyl groups of the two catalyst samples were also measured. The catalytic activity of $Co_3O_4$ nanoparticles was investigated for the removal of phenol in aqueous solutions under different reaction temperatures. Tert-butyl alcohol had little effect on the catalytic ozonation processes. Based on these results, the possible catalytic ozonation mechanism of phenol by $Co_3O_4$ nanoparticles was proposed as a reaction process between ozone molecules and pollutants.

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