Transactions of the Korean hydrogen and new energy society (한국수소및신에너지학회논문집)

The Korean Hydrogen and New Energy Society (한국수소및신에너지학회)
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Stepwise Production of Syngas and Hydrogen from Methane on Ferrite Based Media Added with YSZ

YSZ 첨가 페라이트 매체상에서 메탄으로부터 합성 가스 및 수소의 단계적 생산

  • Je, Han-Sol (Dept. of Fine Chemical Engineering and Applied Chemistry, Chungnam National Univ.) ;
  • Cha, Kwang-Seo (Dept. of Fine Chemical Engineering and Applied Chemistry, Chungnam National Univ.) ;
  • Kim, Hong-Soon (Dept. of Fine Chemical Engineering and Applied Chemistry, Chungnam National Univ.) ;
  • Lee, Young-Seak (Dept. of Fine Chemical Engineering and Applied Chemistry, Chungnam National Univ.) ;
  • Park, Chu-Sik (Hydrogen Energy Research Group, Korea Institute of Energy Research) ;
  • Kim, Young-Ho (Dept. of Fine Chemical Engineering and Applied Chemistry, Chungnam National Univ.)
  • 제한솔 (충남대학교 정밀응용화학과) ;
  • 차광서 (충남대학교 정밀응용화학과) ;
  • 김홍순 (충남대학교 정밀응용화학과) ;
  • 이영석 (충남대학교 정밀응용화학과) ;
  • 박주식 (한국에너지기술연구원) ;
  • 김영호 (충남대학교 정밀응용화학과)
  • Published : 2010.02.28
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Abstract

Stepwise production of syn-gas and hydrogen from methane on ferrite based media added with yttria-stabilized zirconia (YSZ) was carried out using a fixed bed infrared reactor. In this study, all M-ferrite (M=Co, Cu, Mn and Ni) media were prepared by co-precipitation method, and there the YSZ was added as a binder to improve thermal stability, reactivity, and resistance against carbon deposition. Most of the ferrite media containing YSZ showed the good redox property for temperature programmed reduction/oxidation (TPR/O) tests. Notably, the Cu-substituted ferrite medium with YSZ showed the great resistance against carbon deposition as well as the good reactivity for the stepwise production of syngas and hydrogen. Furthermore, it also showed the good durability without significant deactivation during five repeated cyclic tests.

Keywords

References

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