Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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31P NMR and ESI-MS Study of Fenitrothion-Copper Ion Complex: Experimental and Theoretical Study

  • Choi, Ho-June (Department of Chemistry Education and Research Institute of Natural Science, Gyeongsang National University) ;
  • Yang, Ki-Yull (Department of Chemistry Education and Research Institute of Natural Science, Gyeongsang National University) ;
  • Park, Jong-Keun (Department of Chemistry Education and Research Institute of Natural Science, Gyeongsang National University) ;
  • Koo, In-Sun (Department of Chemistry Education and Research Institute of Natural Science, Gyeongsang National University)
  • Received : 2010.02.02
  • Accepted : 2010.03.18
  • Published : 2010.05.20
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Abstract

$^{31}P$ NMR and ESI-MS studies of $Cu^{2+}$ binding to Fenitrothion (FN) were performed by experimentally and theoretically. The calculated $^{31}P$ NMR chemical shifts for FN-$Cu^{2+}$ complexes are in good agreement with experimental chemical shifts in order, and the results present an important information for organophosphorus pesticide metal complexes. ESI-MS and low energy CID MS/MS experiments of FN-$Cu^{2+}$ complexes combined with accurate mass measurements give insight into the metal localization and allow unambiguous identification of fragments and hydrolysis products.

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References

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