Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis of Cobalt-Iron Prussian Blue Analogues Nanotubes by CTAB Soft-Template Method

  • Liu, Peng (Department of Chemistry, Lanzhou University) ;
  • Liang, Chuanghui (Department of Chemistry, Lanzhou University) ;
  • Xu, Jianfeng (Department of Chemistry, Lanzhou University) ;
  • Fang, Jian (Department of Chemistry, Lanzhou University) ;
  • Zhao, Jihua (Department of Chemistry, Lanzhou University) ;
  • Shen, Weiguo (Department of Chemistry, Lanzhou University)
  • Received : 2009.09.24
  • Accepted : 2010.01.23
  • Published : 2010.05.20
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Abstract

Three cobalt-iron Prussian Blue Analogues (PBAs) nanotubes contained with different alkali metal cations of K, Rb or Cs, respectively, were prepared by using cetyltrimethylammonium bromide (CTAB)/ethanol-water micelles as soft templates. The products were characterized by energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), transmission electron microscopy (TEM) and scanning electron micrograph (SEM), which confirmed the composition of the substances and their unique nanotube structures. Furthermore, the formation mechanism of the PBAs nanotubes was discussed and provided useful insight for further synthesis of nanotubes of other Prussian blue analogues.

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